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排序方式: 共有352条查询结果,搜索用时 15 毫秒
1.
Matt Visser Carlos Barceló Stefano Liberati 《General Relativity and Gravitation》2002,34(10):1719-1734
Condensed matter systems, such as acoustics in flowing fluids, light in moving dielectrics, or quasiparticles in a moving superfluid, can be used to mimic aspects of general relativity. More precisely these systems (and others) provide experimentally accessible models of curved-space quantum field theory. As such they mimic kinematic aspects of general relativity, though typically they do not mimic the dynamics. Although these analogue models are thereby limited in their ability to duplicate all the effects of Einstein gravity they nevertheless are extremely important—they provide black hole analogues (some of which have already been seen experimentally) and lead to tests of basic principles of curved-space quantum field theory. Currently these tests are still in the realm of gedanken-experiments, but there are plausible candidate models that should lead to laboratory experiments in the not too distant future. 相似文献
2.
Christopher J. Nichols 《Tetrahedron letters》2004,45(40):7469-7473
A number of new functionalised bridged indolocarbazole systems have been prepared by ring-opening reactions of a key cyclic sulfate intermediate, prepared from the corresponding diol by the action of sulfuryl diimidazole and DBU. The same cyclic sulfate also undergoes an unprecedented asymmetric rearrangement to a chiral ketone, on treatment with a chiral lithium amide base. 相似文献
3.
与q形变玻色算符逆算符相关的相干态及其量子统计性质 总被引:1,自引:1,他引:0
讨论了q形变玻色算符的广义逆算符作用于q-相干态所得到的两类量子态的数学及量子统计性质。结果表明,q-相干态的光子激发态不存在压缩但呈现反聚束效应,而q-相干态的光子湮灭态却存在压缩但不呈现反聚束效应。 相似文献
4.
Peptidosulfonamides are an emerging group of peptidomimetics with a variety of applications in medicinal chemistry. We present a novel approach to the synthesis of peptidosulfonamides, and apply it to a series of new potential inhibitors of the bacterial peptidoglycan biosynthesis enzymes MurD and MurE. The synthesis was conducted via N-phthalimido β-aminoethanesulfonyl chlorides, which are new building blocks for the synthesis of peptidosulfonamides. In the most crucial step, sulfonic acids or their sodium salts were converted into the corresponding sulfonyl chlorides using an excess of either SOCl2 or SOCl2/DMF, and then coupled to the C-protected amino acid. None of the compounds significantly inhibited MurD, however, some inhibited MurE; one had an IC50 below 200 μM, which constitutes a promising starting point for further development. Molecular modelling simulations were performed on two analogues to investigate the absence of inhibitory activity of the sulfonamide compounds on MurD. 相似文献
5.
Maria Carmelita Kasuya 《Journal of fluorine chemistry》2007,128(5):562-565
A series of fluorinated galactosides, dodecyl 2-deoxy-2-fluoro-β-d-galactopyranoside (2F Gal), dodecyl 4-deoxy-4-fluoro-β-d-galactopyranoside (4F Gal) and dodecyl 6-deoxy-6-fluoro-β-d-galactopyranoside (6F Gal), was chemically synthesized and introduced to B16 cells to serve as scaffolds for cellular enzyme glycosylation. Results showed that the presence of fluorine exercised significant effects on cell viability. Among the fluorinated galactosides used, 2F Gal was glycosylated to afford a GM4 analogue. 相似文献
6.
Bikshandarkoil R. Srinivasan 《Journal of Chemical Sciences》2004,116(5):251-259
The complexes [MoX4]2− (M = Mo; X = O or S) exist as the monomeric tetrahedral species in aqueous alkaline solutions. Acidification of tetraoxomolybdate
results in the condensation of the tetrahedral units via a series of polyoxomolybdates leading to the ultimate formation of
the trioxide MoO3. Heptamolybdate [Mo7O24]6− is the first major polyanion of the acidification reaction. In contrast, acidification of tetrathiomolybdates leads to the
formation of amorphous molybdenum trisulphide via a dinuclear Mo(V) complex. The formation of the dinuclear Mo(V) complex
precludes the formation of any higher nuclearity Mo(VI)-S complexes in aqueous solution. Thus it is shown that the all-sulphur
analogue of heptamolybdate [M07S24]6− does not exist in alkaline medium and also cannot be isolated from aqueous acidic medium 相似文献
7.
若干有关欧阳不等式的非线性积分不等式和离散不等式 总被引:10,自引:0,他引:10
获得几个非线性的积分不等式及离散不等式.它们和近期Pachpate[1]中欧阳亮不等式[2]的推广有关.作为特殊情形还导出了一些具有幂非线性的新不等式.为说明结果的有用性,讨论了某个非线性差分方程解的有界性. 相似文献
8.
The fourth-order ordinary differential equation that defines the self-similar solutions of the Kaup—Kupershmidt and Sawada—Kotera
equations is studied. This equation belongs to the class of fourth-order analogues of the Painlevé equations. All the power
and non-power asymptotic forms and expansions near points z = 0, z = ∞ and near an arbitrary point z = z
0 are found by means of power geometry methods. The exponential additions to the solutions of the studied equation are also
determined.
相似文献
9.
本文综述了前列环素及其类似物的合成。类似物包括有7-羰基—、10,10-二氟—、5-氯—,4-羰基—、6,9-硫—、6,9-氮—,6 a-碳—前列环素以及苯前列环素等。前列环素及其类似物是一类具有抑制血小板聚集的生物活性化合物。 相似文献
10.
In order to study the influence of the side-chain orientation on the peptide backbone conformation we have synthesised the model dipeptides t-BuCO-l-Pro-(1S,2R)-c6Phe-NHMe and t-BuCO-l-Pro-(1R,2S)-c6Phe-NHMe, incorporating each enantiomer of the trans cyclohexane analogue of phenylalanine (trans-1-amino-2-phenylcyclohexanecarboxylic acid). The orientation of the aromatic side-chain determines the β-turn type accommodated by these peptides to the point that the (1S,2R)-c6Phe derivative retains the type I β-turn in the crystalline state, in contrast to the behaviour exhibited by the natural counterpart t-BuCO-l-Pro-l-Phe-NHMe. 相似文献