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A nanomaterials-based novel molecular beacon has attracted growing attentions in fluorescent assays as many nanomaterials possess excellent quenching efficiency. In this work, a gold-based nanobeacon probe was established to detect organophosphorus pesticides for the first time. The constructed gold-based nanobeacon acted as a signal indicator and could display the decreasing of the intensity in the presence of targets, which competitively bound to single strand DNA. To achieve a high sensitive probe, some parameters including solution pH, temperature and reaction time were investigated and optimized. The gold-based nanobeacon probe assay was proved to be rapid and sensitive to achieve a detection limit of 0.035 μM for isocarbophos, 0.134 μM for profenofos, 0.384 μM for phorate and 2.35 μM for omethoate, respectively. The prepared nanobeacon effectively reduced the background and improved the detection sensitivity and selectivity. The probe is stable, easy to operate and does not need sophisticated instruments. These features makes the probe feasible for screening trace organophosphorus pesticides in real samples. 相似文献
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热丝辅助裂解法是结合气相沉积制备聚对二甲苯薄膜和热丝化学气相沉积而形成的一种制-CH薄膜的新方法。热丝辅助裂解法的最大特点就是在保持低衬底温度情况下可以获得高沉积速率,而热丝加热电流对薄膜沉积速率和薄膜表面形貌具有重要影响。研究表明,热丝加热电流越大,薄膜沉积速率越高,在加热电流9A时,薄膜沉积速率可达0.002mm/min,同时薄膜表面粗糙度随之增加,薄膜表面也开始出现其它元素污染,因此,一般热丝加热电流选择为7A附近。 相似文献
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Positions and intensities for 453 spectral lines in 12 rovibrational bands of 12C16O2 have been determined between 3700 and 3750 cm−1. At three temperatures (294, 500, and 698 K) eight spectra have been recorded at a pressure around 5 mbar and for an absorption path of about 190 cm−1 using a Bomen DA3 Fourier transform spectrometer (4 × 10−3 cm−1 resolution). Some of the measured positions and intensities can be compared with recent experimental results that validate the experimental set-up and the data analysis procedure. The results are also compared with the values listed in the HITRAN 2000 database. If the agreement is generally good, discrepancies are observed for three hot bands. 相似文献
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YunFei Liu ShengCai Shi ShengLin Yu 《International Journal of Infrared and Millimeter Waves》2003,24(12):2069-2077
When electromagnetic waves propagate through a wire grid, there will be some evanescent space harmonics generated around the wire grid. In this paper, we mainly investigate their effects on the transmission characteristics of a Gaussian beam by cylindrical wire grids. The results are compared with those without taking account of evanescent space-harmonics. 相似文献
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To improve the understanding of the electrochemical effects observed on an original potentiometric gas sensor, interactions of oxygen with the device were investigated. This gas sensor is made of a solid electrolyte (treated Na-β-alumina) associated with two metallic electrodes (gold and platinum) located in the same gas mixture. Adsorption of charged oxygen species, considered responsible for the electrical response developed by the sensor, was investigated by work function measurements. Results showed that charged oxygen species only form on partially gold or platinum covered solid electrolyte. Comparison of these results with those obtained in a previous calorimetric study of interactions between oxygen and the same materials suggests the existence of at least two different oxygen species adsorbed on the surface of the sensitive element. The first one, located on the solid electrolyte surface, is neutral and characterized by an endothermal reaction of formation. The second one is charged and probably produced at the gas/solid electrolyte/metallic electrode interface. A mechanism based on the concept of “three phase boundary” and similar to the “reverse spillover” phenomenon is proposed to account for the adsorption of these oxygen species. 相似文献
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