Mechanical endurance of polymer electrolyte membrane and PEM fuel cell durability

The life of proton exchange membrane fuel cells (PEMFC) is currently limited by the mechanical endurance of polymer electrolyte membranes and membrane electrode assemblies (MEAs). In this paper, the authors report recent experimental and modeling work toward understanding the mechanisms of delayed mechanical failures of polymer electrolyte membranes and MEAs under relevant PEMFC operating conditions. Mechanical breach of membranes/MEAs in the form of pinholes and tears has been frequently observed after long‐term or accelerated testing of PEMFC cells/stacks. Catastrophic failure of cell/stack due to rapid gas crossover shortly follows the mechanical breach. Ex situ mechanical characterizations were performed on MEAs after being subjected to the accelerated chemical aging and relative humidity (RH) cycling tests. The results showed significant reduction of MEA ductility manifested as drastically reduced strain‐to‐failure of the chemically aged and RH‐cycled MEAs. Postmortem analysis revealed the formation and growth of mechanical defects such as cracks and crazing in the membranes and MEAs. A finite element model was used to estimate stress/strain states of an edge‐constrained MEA under rapid RH variations. Damage metrics for accelerated testing and life prediction of PEMFCs are discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2346–2357, 2006     

Representing the mean residual life in terms of the failure rate

In survival or reliability studies, the mean residual life or life expectancy is an important characteristic of the model. Whereas the failure rate can be expressed quite simply in terms of the mean residual life and its derivative, the inverse problem—namely that of expressing the mean residual life in terms of the failure rate—typically involves an integral of a complicated expression. In this paper, we obtain simple expressions for the mean residual life in terms of the failure rate for certain classes of distributions which subsume many of the standard cases. Several results in the literature can be obtained using our approach. Additionally, we develop an expansion for the mean residual life in terms of Gaussian probability functions for a broad class of ultimately increasing failure rate distributions. Some examples are provided to illustrate the procedure.     

复杂应力构件弹性失效疲劳失效新判据——动态静态八面体应力强度理论

本文,在研究现代和经典强度理论的基础之上,提出了一个在复杂应力下弹性失效与疲劳失效的总准则,即动态静态八面体应力强度理论,同时建立了并分析了一个独立的比较完整的理论体系,给出了36种材料广义失效系数,和一点复杂应力的11个状态的计算理论,导出了广义允许强度算子方程.给出了总准则能应用到静态、动态的计算方法,通过8个工程实例的计算,表明该方法有很高的精度,因而笔者建议广泛地应用到工程.     

两相同部件温贮备可修的人机系统解的性质分析

本文首先用强连续算子半群理论证明了两相同部件温贮备可修的人机系统动态非负解的存在唯一性 ,然后证明了 0是系统主算子的本征值 ,并得到 0本征值对应的本征向量是正的 ,从而系统存在稳态正解 .     

Ply-by-Ply Failure Analysis of Laminates Under Dynamic Loading

Ply-by-ply failure analysis of symmetric and anti-symmetric laminates under uniform sinusoidal transverse dynamic loading is performed for a specified duration. The study investigates the first ply failure load, followed by the detection of successive ply failures along with their failure modes using various failure theories. Some of the well-established failure theories, mostly used by the researchers, are considered for the failure prediction in laminates. The finite element computational model based on higher order shear deformation displacement field is used for the failure analysis and the complete methodology is computer coded using FORTRAN. The ply-discount stiffness reduction scheme is employed to modify the material properties of the failed lamina. The failure theories used in the analysis are compared according to their ability to predict failure load, failed ply, failure mode and progression of failure. The failure analysis is performed for both the cross-ply and angle-ply laminates with all edges simply supported and clamped. The significance of fibre orientation and stacking sequence in terms of the strength of a laminate and failure progression is also highlighted.     

How to Construct Polar Codes for Ring-LWE-Based Public Key Encryption

There exists a natural trade-off in public key encryption (PKE) schemes based on ring learning with errors (RLWE), namely: we would like a wider error distribution to increase the security, but it comes at the cost of an increased decryption failure rate (DFR). A straightforward solution to this problem is the error-correcting code, which is commonly used in communication systems and already appears in some RLWE-based proposals. However, applying error-correcting codes to those cryptographic schemes is far from simply installing an add-on. Firstly, the residue error term derived by decryption has correlated coefficients, whereas most prevalent error-correcting codes with remarkable error tolerance assume the channel noise to be independent and memoryless. This explains why only simple error-correcting methods are used in existing RLWE-based PKE schemes. Secondly, the residue error term has correlated coefficients leaving accurate DFR estimation challenging even for uncoded plaintext. It can be found in the literature that a tighter DFR estimation can effectively create a DFR margin. Thirdly, most error-correcting codes are not well designed for safety considerations, e.g., syndrome decoding has a nonconstant time nature. A code good at error correcting might be weak under a variety of attacks. In this work, we propose a polar coding scheme for RLWE-based PKE. A relaxed “independence” assumption is used to derive an uncorrelated residue noise term, and a wireless communication strategy, outage, is used to construct polar codes. Furthermore, some knowledge about the residue noise is exploited to improve the decoding performance. With the parameterization of NewHope Round 2, the proposed scheme creates a considerable DRF margin, which gives a competitive security improvement compared to state-of-the-art benchmarks. Specifically, the security is improved by 28.8%, while a DFR of 2−149 is achieved a for code rate pf 0.25, n=1024,q= 12,289, and binomial parameter k=55. Moreover, polar encoding and decoding have a quasilinear complexity O(Nlog2N) and intrinsically support constant-time implementations.     

变形镜部分驱动器断电失效对校正性能的影响

变形镜在长期工作的过程中,压电陶瓷驱动器因累积疲劳效应会导致其失效,从而导致校正性能的降低.从变形镜的影响函数出发,将失效驱动器的电压置零,采用有限元方法建立变形镜疲劳失效模型,重点分析畸变波前的形态分布、入射光束的类型和驱动器的排布方式等对校正能力的影响.实验结果表明,在部分驱动器失效的情况下,变形镜应当根据高斯型随...     

High pressure-induced structural effects in plastic packaging

Today, flexible vacuum packages are predominantly used for products to be subjected to high pressure treatment. However, tray packages with a modified atmosphere are in demand, which provide a high failure rate with respect to gas and water vapour permeability and packaging integrity. Methods to follow permeation processes under high pressure were developed and used together with optical microscopy, confocal scanning laser microscopy, Raman spectroscopy and atomic force microscopy to identify the mechanisms for changes in permeability and damage to the packaging materials. Single film samples and pouch packages filled with model products were studied. Results indicate a reversible decrease in the coefficients of diffusion and permeation under the impact of high pressure, due to the compression of the polymeric bulk. Irreversible changes in the polymeric materials are associated with gases in the packaging head space, which cause high local temperatures and create damage due to rapid deliberation upon the pressure drop at the end of the high pressure cycle.     

An Investigation into the Migration of Segments in Crosslinked Fluorinated Polyimide Adhesive

Crosslinked fluorinated polyimides (CFPI) were successfully synthesized to study and explore the effect of cross-linkage on the migration of fluorinated segments and on the adhesion strength. Characterization by dynamic thermomechanical analysis (DMA) and thermo gravimetric analysis (TGA) confirmed good thermal properties of CFPI. X-ray photoelectron spectroscopy (XPS) results showed that the ratio of fluorinated component (6FDA-ODA) concentration of the surface to the bulk decreased with the crosslink density. The water contact angle of CFPI was lower than that of non-crosslinked fluorinated polyimide, indicating that the migration of fluorinated groups to the surface was reduced by the presence of cross-linkage. Therefore, CFPI, with no fluorine segregation on the surface, exhibited excellent wetting of adherent surfaces and adhesion strength, which was proved by lap shear strength (LSS) measurements and scanning electron microscopy.     

Exponential distributions on semigroups

Three fundamental characterizations of the standard exponential distribution on [0, ) are the remaining life, memoryless and constant failure properties. Analogs of these properties are studied for distributions on a class of semigroups in which the semigroup operation replaces addition, a compatible partial order replaces the ordinary order, and a left-invariant measure replaces Lebesgue measure. Partial characterizations of exponential distributions on such semigroups are obtained and the semigroup formulation provides new characterizations of certain aging properties studied in reliability-increasing failure rate, new better than used, and increasing failure rate average.