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排序方式: 共有393条查询结果,搜索用时 15 毫秒
1.
Ferhat Sametoglu 《Optical Review》2006,13(5):326-337
Traceability in illuminance measurements at the National Metrology Institute of Turkey (TüBITAK-UME) was established in 2003
with a detector-based realization. The new measurement technique was developed for the determination of illuminance responsivity
and upgrating of the illuminance scale. The unit of the illuminance responsivity, in A/lx, was measured with an expanded uncertainty
of 0.2% (k = 2) by supplying using the developed scanning technique for the calculation of color correction factor. The surface of a
radiometer was scanned using a double-monochromator facility upgraded with an x-y scanning system. The illuminance responsivity
as a function of bandpass and temperature were also investigated in this study.
To use a radiometer in the photometric applications of metrology, a light-sensitive device, a so-called trap detector, was
characterized by measuring the absolute responsivity, the non-linearity, and spatial non-uniformity. 相似文献
2.
《Magnetic resonance in chemistry : MRC》2003,41(11):949-954
We report two new asterosaponins from the Baltic starfish Asterias rubens along with their 1H and 13C NMR data. The compounds were isolated after on‐flow liquid chromatography–NMR–mass spectrometry screening indicated that they had not been identified before. The one‐ and two‐dimensional NMR experiments used to elucidate the structures were recorded using a 5 mm cryogenic probe head. The advantages of cryogenic probes for this kind of examination in comparison with conventional probe heads are discussed. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
3.
4.
Zusammenfassung Die dünnschichtchromatographische Trennung von Flechtenextrakten zur Unterstützung der Taxonomie wurde in Bezug auf die Trennleistung
und auf die Reproduzierbarkeit optimiert. Dabei wurden besonders gute Trennleistungen erhalten mit dem Flie?mittelgemisch
Benzol:Dioxa:Eisessig=90∶25∶4 bei Verwendung von Kieselgel, dessen Aktivit?t durch eine Umgebung mit relativer Feuchte von
70% festgelegt wurde, und mit Methylenchlorid als Eluiermittel bei Verwendung von mit Oxals?ure impr?gniertem Kieselgel und
antiparallelem Aktivit?tsgradienten. Eine hohe Reproduzierbarkeit der Trennungen wurde erreicht durch Verwendung der Vario-KS-Kammer
nach Geiss, die die Einstellung einer definierten Schichtaktivit?t bzw. eines definierten Aktivit?tsgradienten und eine reproduzierbare
Vorbedampfung der Schicht mit Flie?mittel erm?glicht. Es konnte gezeigt werden, da? durch unterschiedliche chromatographische
Trennungen der gleichen Extrakte und durch die Verwendung verschiedener Anf?rbereagenzien die Identifizierung und damit die
Aussagekraft für taxonomische Probleme steigt.
Standardisation of the thin-layer chromatographic separation of lichen acids for the chemotaxonomy of lichens
Summary The thin-layer chromatography of lichen extracts for taxonomic studies has been optimized in relation to separation and to reproducibility. Especially good separations were found with benzene:dioxane:acetic acid (90∶25∶4) developer and silica gel thin-layer plates, whose activity was fixed by an ambient moisture content of 70%, and with methylene chloride developer and silica gel plates impregnated with oxalic acid and antiparallel activity gradient. High reproducibility of separation was obtained using the Geiss Vario-KS tank, which allows the activity of the plates or the activity gradient to be adjusted and which also allows reproducible exposure of plates to the vapour of developing solvents. By different chromatographic separations of the same extracts and by using different colour reactions the accuracy of identification for taxonomic studies has been improved.
相似文献
5.
Magdalena Kurdziel Elżbieta Szczepaniec-Cieciak Monika Watorczyk Barbara Dabrowska 《Journal of solution chemistry》2004,33(5):453-464
The solubility of solid 2-methyl-1,3-butadiene (isoprene) in liquid argon at a temperature of 87.3 K and in liquid nitrogen at 77.4 K has been measured by the filtration method. The hydrocarbon contents in solutions were determined using gas chromatography. GC–MS was used to identify impurities in the solute. The experimental value of the mole fraction solubility of solid isoprene in liquid argon at 87.3 K is (1.41 ± 0.27) × 10–6 and (1.56 ± 0.36) × 10–7 in liquid nitrogen at 77.4 K. The Preston–Prausnitz method was used for calculation of the solubilities of solid hydrocarbon in liquid argon in the temperature range 84.0–110.0 K and in liquid nitrogen from 64.0 to 90.0 K. The solvent–solute interaction parameters l
12 were also calculated. At 90.0 K liquid argon is a better solvent for isoprene than is liquid nitrogen. The experimental values of the solubilities of isoprene in liquid argon and nitrogen were compared with results obtained for selected unsaturated and aromatic hydrocarbons. 相似文献
6.
Magdalena Kurdziel Elżbieta Szczepaniec-Cięciak Barbara Dąbrowska Wojciech Nitek Katarzyna Paliś Edyta Ślusarska 《Journal of solution chemistry》2003,32(7):601-615
The solubilities of solid 2,3-dimethylbutane and cyclopentene in liquid argon at a temperature of 87.3 K and in liquid nitrogen at 77.4 K have been measured by the filtration method. The hydrocarbon contents in solutions were determined using gas chromatography. GC–MS was used to identify impurities in solutes. The experimental value of the mole fraction solubility of solid 2,3-dimethyl-butane in liquid argon at 87.3 K is (8.26 ± 1.60) × 10–6 and (2.77 ± 0.94) × 10–8 in liquid nitrogen at 77.4 K. The experimental value of the mole fraction solubility of solid cyclopentene in liquid argon at 87.3 K is (5.11 ± 0.44) × 10–6 and (4.60 ± 0.76) × 10–8 in liquid nitrogen at 77.4 K. The Preston–Prausnitz method was used for calculation of the solubilities of solid hydrocarbons in liquid argon in the temperature range 84.0–110.0 K and in liquid nitrogen from 64.0 to 90.0 K. The solvent–solute interaction parameters l
12 were also calculated. At 90.0 K liquid argon is a better solvent for investigated solid hydrocarbons than is liquid nitrogen. 相似文献
7.
In this paper, we have investigated the motion of a heated viscoelastic fluid layer in a rectangular tank that is subjected to a horizontal periodic oscillation. The mathematical model of the current problem is communicated with the linearized Navier–Stokes equation of the viscoelastic fluid and heat equation together with the boundary conditions that are solved by means of Laplace transform. Time domain solutions are consequently computed by using Durbin's numerical inverse Laplace transform scheme. Various numerical results are provided and thereby illustrated graphically to show the effects of the physical parameters on the free-surface elevation time histories and heat distribution. The numerical applications revealed that increasing the Reynolds number as well as the relaxation time parameter leads to a wider range of variation of the free-surface elevation, especially for the short time history. 相似文献
8.
WU GuoXiong State Key Laboratory of Ocean Engineering College of Naval Architecture Ocean Civil Engineering Shanghai Jiao Tong University Shanghai China 《中国科学:物理学 力学 天文学(英文版)》2011,(1)
The sloshing of inviscid liquid of stratified density in a rectangular tank is analyzed.As the flow is no longer irrotional,the governing equation is found to be quite different from the Laplace equation used for the liquid of constant density.In particular it contains terms of mixed temporal and spatial derivatives.The problem is solved based on the variable separation method and Laplace transform for the constant Vaisala-Brunt frequency.It is found that the stratification of density may have small effects... 相似文献
9.
Aleksandr I. Chumakov Ilya Sergeev Jean‐Philippe Celse Rudolf Rüffer Marc Lesourd Lin Zhang Manuel Sánchez del Río 《Journal of synchrotron radiation》2014,21(2):315-324
The performance of a cryogenically cooled double‐crystal silicon monochromator was studied under high‐heat‐load conditions with total absorbed powers and power densities ranging from 8 to 780 W and from 8 to 240 W mm?2, respectively. When the temperature of the first crystal is maintained close to the temperature of zero thermal expansion of silicon, the monochromator shows nearly ideal performance with a thermal slope error of 0.6 µrad. By tuning the size of the first slit, the regime of the ideal performance can be maintained over a wide range of heat loads, i.e. from power densities of 110 W mm?2 (at total absorbed power of 510 W) to 240 W mm?2 (at total absorbed power of 240 W). 相似文献
10.
Gakhyun Kim Dr. Ranjan Dutta Dr. Won-Young Cha Dr. Seong-Jin Hong Dr. Juwon Oh Dr. Dikhi Firmansyah Hongil Jo Prof. Dr. Kang Min Ok Prof. Dr. Chang-Hee Lee Prof. Dr. Dongho Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16434-16440
π–π Stacking is omnipresent not only in nature but in a wide variety of practical fields applied to our lives. Because of its importance in a performance of natural and artificial systems, such as light harvesting system and working layer in device, many researchers have put intensive effort into identifying its underlying nature. However, for the case of π–π stacked systems composed of antiaromatic units, the understanding of the fundamental mechanisms is still unclear. Herein, we synthesized a new type of planar β,β’-phenylene-bridged hexaphyrin (1.0.1.0.1.0), referred as naphthorosarin which possesses the 24π-electron conjugated pathway. Especially, the corresponding antiaromatic porphyrinoid shows the unique property to form dimeric species adopting the face-to-face geometry which is unprecedented in cases of known annulated naphthorosarins. In order to elucidate the intriguing properties derived from the stacked dimer, the current study focuses on the experimental support to rationalize the observed π–π interactions between the two subunits. 相似文献