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1.
Heng-Dao Quan Hui-E Yang Masanori Tamura Akira Sekiya 《Journal of fluorine chemistry》2007,128(3):190-195
In this report, a simple process for preparing HFC-245fa through the reaction of 1,1,1,3,3-pentachloropropane (PCP) and anhydrous HF via two-step vapor-phase catalytic fluorination is described. The antimony pentafluoride catalyst was supported on inert porous materials to improve the catalytic activity. The resulting process catalyst not only exhibited high catalytic activity and excellent thermo-stability, but also improved the performance of SbF5, in terms of hygroscopicity and corrosion. 相似文献
2.
A new molecular model for 1,1,1,2,3,3,3-heptafluoropropane (R227ea) was developed on the basis of quantum chemical calculations and optimized using experimental vapor pressure and bubble density data. In combination with an existing model for ethanol, a molecular model for the binary mixture R227ea + ethanol was defined, using the Lorentz–Berthelot combining rule. It was validated at 283.17 K, where, considering the statistical uncertainties, it agrees to the experimental vapor pressure. The vapor–liquid equilibrium, comprising both bubble line and dew line data, was predicted at 343.13 K by molecular simulation. The Peng–Robinson equation of state fails for this system. 相似文献
3.
采用沉淀法和浸渍法制备了2种铬基(Cr2O3和CrO3/Cr2O3)催化剂,用于气相氟化2-氯-1,1,1-三氟乙烷合成1,1,1,2-四氟乙烷。研究发现含有低价铬(Cr3+)物种的Cr2O3催化剂上2-氯-1,1,1-三氟乙烷的稳态转化率为18.5%,而含有高价铬(Cr6+)物种和低价铬(Cr3+)物种的CrO3/Cr2O3催化剂初始转化率达到30.6%,然而存在明显的失活。含有Cr6+物种的CrO3/Cr2O3催化剂的2-氯-1,1,1-三氟乙烷氟化反应初始TOF值为1.71×10-4 molHCFC-133a·molCr(Ⅵ)-1·s-1,高于含有Cr3+物种的Cr2O3催化剂(4.16×10-5 molHCFC-133a·molCr(Ⅲ)-1·s-1)。Cr2O3催化剂在氟化反应前后催化剂的物相结构保持不变;而含有高价铬物种的CrO3/Cr2O3催化剂经HF反应后生成了CrOxFy活性物种。然而,CrOxFy物种在反应中挥发或转化成稳定但无活性的CrF3,从而导致催化剂失活。 相似文献
4.
The continuous-wave laser properties of an efficient diode-pumped Nd:GdVO4 crystal operating at formed with a simple plane-concave cavity have been studied. With the incident pump power of 21 W, an output power of 6.9 W was obtained, giving an optical conversion efficiency of 32.8% and a slope efficiency of 35.3%. The laser characterization of two different Nd3+-doped concentration of Nd:GdVO4 crystals were studied. 相似文献
5.
In this paper, we propose a well targeted algorithm (GAS algorithm) for detecting communities in high clustered networks by presenting group action technology on community division. During the processing of this algorithm, the underlying community structure of a clustered network emerges simultaneously as the corresponding partition of orbits by the permutation groups acting on the node set are achieved. As the derivation of the orbit partition, an algebraic structure r-cycle can be considered as the origin of the community. To be a priori estimation for the community structure of the algorithm, the community separability is introduced to indicate whether a network has distinct community structure. By executing the algorithm on several typical networks and the LFR benchmark, it shows that this GAS algorithm can detect communities accurately and effectively in high clustered networks. Furthermore, we compare the GAS algorithm and the clique percolation algorithm on the LFR benchmark. It is shown that the GAS algorithm is more accurate at detecting non-overlapping communities in clustered networks. It is suggested that algebraic techniques can uncover fresh light on detecting communities in complex networks. 相似文献
6.
In this paper we study the maximal operators and the convolution operators Tδ associated with multipliers of the form
7.
The location of the membrane lipid bilayer relative to a transmembrane protein structure is important in protein engineering. Since it is not present on the determined structures, it is essential to automatically define the membrane embedded protein region in order to test mutation effects or to design potential drugs. beta-Barrel transmembrane proteins, present in nature as outer membrane proteins (OMPs), comprise one of the two transmembrane protein fold classes. Lately, the number of their determined structures has increased and this enables the implementation and evaluation of structure-based annotation methods and their more comprehensive study. In this paper, we propose two new algorithms for (i) the geometric modelling of beta-barrels and (ii) the detection of the transmembrane region of a beta-barrel transmembrane protein. The geometric modelling algorithm combines a non-linear least square minimization method and a genetic algorithm in order to find the characteristics (axis, radius) of a shape with axial symmetry which best models a beta-barrel. The transmembrane region is detected by profiling the external residues of the beta-barrel along its axis in terms of hydrophobicity and existence of aromatic and charged residues. TbB-Tool implements these algorithms and is available in . A non-redundant set of 22 OMPs is used in order to evaluate the algorithms implemented and the results are very satisfying. In addition, we quantify the abundance of all amino acids and the average hydrophobicity for external and internal beta-stranded residues along the axis of beta-barrel, thus confirming and extending other researchers' results. 相似文献
8.
Precoloring extension on unit interval graphs 总被引:1,自引:0,他引:1
Dániel Marx 《Discrete Applied Mathematics》2006,154(6):995-1002
In the precoloring extension problem a graph is given with some of the vertices having preassigned colors and it has to be decided whether this coloring can be extended to a proper k-coloring of the graph. Answering an open question of Hujter and Tuza [Precoloring extension. III. Classes of perfect graphs, Combin. Probab. Comput. 5 (1) (1996) 35-56], we show that the precoloring extension problem is NP-complete on unit interval graphs. 相似文献
9.
Tiexin Guo 《Journal of Functional Analysis》2010,258(9):3024-842
The purpose of this paper is to exhibit the relations between some basic results derived from the two kinds of topologies (namely the (ε,λ)-topology and the stronger locally L0-convex topology) for a random locally convex module. First, we give an extremely simple proof of the known Hahn-Banach extension theorem for L0-linear functions as well as its continuous variant. Then we give the relations between the hyperplane separation theorems in [D. Filipovi?, M. Kupper, N. Vogelpoth, Separation and duality in locally L0-convex modules, J. Funct. Anal. 256 (2009) 3996-4029] and a basic strict separation theorem in [T.X. Guo, H.X. Xiao, X.X. Chen, A basic strict separation theorem in random locally convex modules, Nonlinear Anal. 71 (2009) 3794-3804]: in the process we also obtain a very useful fact that a random locally convex module with the countable concatenation property must have the same completeness under the two topologies. As applications of the fact, we prove that most of the previously established principal results of random conjugate spaces of random normed modules under the (ε,λ)-topology are still valid under the locally L0-convex topology, which considerably enriches financial applications of random normed modules. 相似文献
10.
Arthur S. Finbow 《Discrete Applied Mathematics》2010,158(12):1224-368
For a positive integer k, a k-packing in a graph G is a subset A of vertices such that the distance between any two distinct vertices from A is more than k. The packing chromatic number of G is the smallest integer m such that the vertex set of G can be partitioned as V1,V2,…,Vm where Vi is an i-packing for each i. It is proved that the planar triangular lattice T and the three-dimensional integer lattice Z3 do not have finite packing chromatic numbers. 相似文献