全文获取类型
收费全文 | 11010篇 |
免费 | 625篇 |
国内免费 | 416篇 |
专业分类
化学 | 1358篇 |
晶体学 | 15篇 |
力学 | 3522篇 |
综合类 | 56篇 |
数学 | 3811篇 |
物理学 | 3289篇 |
出版年
2023年 | 77篇 |
2022年 | 137篇 |
2021年 | 160篇 |
2020年 | 187篇 |
2019年 | 215篇 |
2018年 | 157篇 |
2017年 | 204篇 |
2016年 | 330篇 |
2015年 | 327篇 |
2014年 | 375篇 |
2013年 | 736篇 |
2012年 | 455篇 |
2011年 | 617篇 |
2010年 | 459篇 |
2009年 | 750篇 |
2008年 | 749篇 |
2007年 | 727篇 |
2006年 | 647篇 |
2005年 | 576篇 |
2004年 | 535篇 |
2003年 | 538篇 |
2002年 | 410篇 |
2001年 | 292篇 |
2000年 | 307篇 |
1999年 | 241篇 |
1998年 | 291篇 |
1997年 | 220篇 |
1996年 | 170篇 |
1995年 | 194篇 |
1994年 | 150篇 |
1993年 | 124篇 |
1992年 | 93篇 |
1991年 | 77篇 |
1990年 | 49篇 |
1989年 | 64篇 |
1988年 | 52篇 |
1987年 | 40篇 |
1986年 | 34篇 |
1985年 | 42篇 |
1984年 | 20篇 |
1983年 | 15篇 |
1982年 | 21篇 |
1981年 | 23篇 |
1980年 | 17篇 |
1979年 | 21篇 |
1978年 | 17篇 |
1977年 | 18篇 |
1976年 | 18篇 |
1973年 | 13篇 |
1971年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
Song Zhang Luke A. Galuska Xiaodan Gu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(7):1108-1129
Thin films with a nanometer-scale thickness are of great interest to both scientific and industrial communities due to their numerous applications and unique behaviors different from the bulk. However, the understanding of thin-film mechanics is still greatly hampered due to their intrinsic fragility and the lack of commercially available experimental instruments. In this review, we first discuss the progression of thin-film mechanical testing methods based on the supporting substrate: film-on-solid substrate method, film-on-water tensile tests, and water-assisted free-standing tensile tests. By comparing past studies on a model polymer, polystyrene, the effect of different substrates and confinement effect on the thin-film mechanics is evaluated. These techniques have generated fruitful scientific knowledge in the field of organic semiconductors for the understanding of structure–mechanical property relationships. We end this review by providing our perspective for their bright prospects in much broader applications and materials of interest. 相似文献
2.
《Discrete Mathematics》2022,345(10):112984
Let G be a generalized dicyclic group with identity 1. An inverse closed subset S of is called minimal if and there exists some such that . In this paper, we characterize distance-regular Cayley graphs of G under the condition that S is minimal. 相似文献
3.
In this paper, we study generalized Douglas–Weyl(α, β)-metrics. Suppose that a regular(α, β)-metric F is not of Randers type. We prove that F is a generalized Douglas–Weyl metric with vanishing S-curvature if and only if it is a Berwald metric. Moreover, by ignoring the regularity, if F is not a Berwald metric, then we find a family of almost regular Finsler metrics which is not Douglas nor Weyl. As its application, we show that generalized Douglas–Weyl square metric or Matsumoto metric with isotropic mean Berwald curvature are Berwald metrics. 相似文献
4.
Controlling effective interactions and spatial dispersion of nanoparticles in multiblock copolymer melts
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Debapriya Banerjee Kenneth S. Schweizer 《Journal of Polymer Science.Polymer Physics》2015,53(16):1098-1111
The microscopic Polymer Reference Interaction Site Model theory is employed to study, for the first time, the effective interactions, spatial organization, and miscibility of dilute spherical nanoparticles in non‐microphase separating, chemically heterogeneous, compositionally symmetric AB multiblock copolymer melts of varying monomer sequence or architecture. The dependence of nanoparticle wettability on copolymer sequence and chemistry results in interparticle potentials‐of‐mean force that are qualitatively different from homopolymers. An important prediction is the ability to improve nanoparticle dispersion via judicious choice of block length and monomer adsorption‐strengths which control both local surface segregation and chain connectivity induced packing constraints and frustration. The degree of dispersion also depends strongly on nanoparticle diameter relative to the block contour length. Small particles in copolymers with longer block lengths experience a more homopolymer‐like environment which renders them relatively insensitive to copolymer chemical heterogeneity and hinders dispersion. Larger particles (sufficiently larger than the monomer diameter) in copolymers of relatively short block lengths provide better dispersion than either a homopolymer or random copolymer. The theory also predicts a novel widening of the miscibility window for large particles upon increasing the overall molecular weight of copolymers composed of relatively long blocks. The influence of a positive chi‐parameter in the pure copolymer melt is briefly studied. Quantitative application to fullerenes in specific copolymers of experimental interest is performed, and miscibility predictions are made. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1098–1111 相似文献
5.
Inner derivations and norm equality 总被引:3,自引:0,他引:3
Mohamed Barraa Mohamed Boumazgour 《Proceedings of the American Mathematical Society》2002,130(2):471-476
We characterize when the norm of the sum of two bounded operators on a Hilbert space is equal to the sum of their norms.
6.
矩阵方程A^TXB=C的正定和半正定解 总被引:5,自引:1,他引:4
何楚宁 《高校应用数学学报(A辑)》1997,(4):475-480
给出了矩阵方程A^TXB=C在正定和半正定矩阵类中有解的充要条件及解的一般表达式。 相似文献
7.
固体力学有限元体系的结构拓扑变化理论 总被引:2,自引:1,他引:1
本文是文[1]的继续.文[1]提出了杆件系统的结构拓扑变化理论和拓扑变化法本文将这一理论和方法推进到连续体有限元体系;且在此基础上揭示出有限元体系的一个新性质,称为基本位移之梯度的正交性定理,从而给出一套设计敏度的显式表达式,可直接用于计算. 相似文献
8.
The theory of tree-growing (RECPAM approach) is developed for outcome variables which are distributed as the canonical exponential family. The general RECPAM approach (consisting of three steps: recursive partition, pruning and amalgamation), is reviewed. This is seen as constructing a partition with maximal information content about a parameter to be predicted, followed by simplification by the elimination of ‘negligible’ information. The measure of information is defined for an exponential family outcome as a deviance difference, and appropriate modifications of pruning and amalgamation rules are discussed. It is further shown how the proposed approach makes it possible to develop tree-growing for situations usually treated by generalized linear models (GLIM). In particular, Poisson and logistic regression can be tree-structured. Moreover, censored survival data can be treated, as in GLIM, by observing a formal equivalence of the likelihood under random censoring and an appropriate Poisson model. Three examples are given of application to Poisson, binary and censored survival data. 相似文献
9.
G. Dattoli 《Journal of Mathematical Analysis and Applications》2002,269(2):716-725
Bilateral generating functions are those involving products of different types of polynomials. We show that operational methods offer a powerful tool to derive these families of generating functions. We study cases relevant to products of Hermite polynomials with Laguerre, Legendre and other polynomials. We also propose further extensions of the method which we develop here. 相似文献
10.
本文在一类 Lp位势V(x)下建立了广义Schrodinger算子H=(-Δ)m+V(x)在C∞0(Rn)上的本质自伴性,给出了H的本质谱的分布. 相似文献