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1.
《Arabian Journal of Chemistry》2021,14(11):103421
Processing of Carapa guianensis seeds to obtain oil on an industrial scale generates a significant amount of by-product, approximately 66% w/w, which is called cake and is a potential source of biomolecules, including simple phenolic structures. For this reason, studies were carried out on the chemical profiles of hydrolyzed extract from this agro-industrial by-product through High Performance Thin-Layer Chromatography (HPTLC) and Gas Chromatography coupled to Mass Spectrometry (GC–MS). These techniques were used to detect metabolic classes and/or groups, and to identify, for the first time, thirteen simple phenolic acids in this by-product. The sample antioxidant capacity was determined by methods of 2,2-diphenyl-1-picrylhydrazyl (DPPH)and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS+) radicals direct sequestration. The hydrolyzed fraction showed a total of 63.47% in the relative abundance of the total of compounds, standing out: p-hydroxybenzoic acid (39.19%) and protocatechuic acid (3,4-dihydroxybenzoic acid) (5.62%), both from hydroxybenzoic acids and 3-(3,4-dihydroxyphenyl)lactic acid, (7.76%) hydroxycinnamic acids derivatives. In these results, the fraction rich in simple phenolic acids was obtained, attributing the prominent behavior of this matrix antioxidant activity, expressed by (IC50: of 16.42 µg/mL and 6.52 µg/mL for DPPH and ABTS+ radicals, respectively). The research demonstrated an alternative to applicability that involves sustainability from agro-industrial. These techniques were used to detect metabolic classes and/or groups, and to identify, for the first time, thirteen simple phenolic acids in this by-product, generating a process capable of converting biomass into a bioproduct, consisting of bioactive compounds, in addition to adding value to the industrial chain. 相似文献
2.
Summary Experiments and simulations prove that correlation chromatography can greatly reduce the disadvantage of a non-linear response of the chromatographic column. A factor that has been accepted as being an important source of error in correlation or multiplex chromatography, has been shown not to be. Separations affected, improve dramatically when correlation chromatography is used, and a substantial amount of correlation noise only arises when there is a large difference in separation between a conventional chromatogram and a correlogram.A model has been developed for simulating these nonlinearities. It is shown that, especially for correlation chromatography, the simulation results match the practical measurements very well. 相似文献
3.
I. L. Davies K. E. Markides M. L. Lee M. W. Raynor K. D. Bartle 《Journal of separation science》1989,12(4):193-207
Although coupled liquid chromatographygas chromatography (LC-GC) was first demonstrated ten years ago, only in the last few years has there been a sudden surge of interest in the technique. Approximately 70% of the total number of LC-GC applications have been published in the last two years (1987–88) alone. This review categorizes LC-GC publications into four main application areas: fossil fuels, foods, environmental samples, biologiical/pharmaceutical samples, and miscellaneous samples. Multidimensional separations carried out using other coupled-column chromatographic techniques (such as supercritical fluid chromatography (SFC) with GC, and on-line trace enrichment-GC) have also been included in this review. 相似文献
4.
DING Bin-Gang ZHANG Da-Li LU Ding-Hui 《理论物理通讯》2006,46(1):113-118
We calculate the binding energies of Ni, Cu, Xe, Cs, Pt, Au, Np, Pu isotope chains using two interaction parameter sets NL-3 and NL-Z, and compared the relative errors of the even-even nuclei with those of odd-even nuclei and odd-odd nuclei. We find that the errors of binding energy of odd-even and odd-odd nuclei are not bigger than the one of even-even nuclei. The result shows that comparing with even-even nuclei, there is no systematic error and approximation in the calculations of the binding energy of odd-even and odd-odd nuclei with relativistic mean-field theory. In addition, the result is explained theoretically. 相似文献
5.
GU Bai-Ping REN Zhong-Zhou 《理论物理通讯》2005,44(2):337-342
The Dirac optical potential for p-^14 Be elastic scattering is evaluated by the relativistic impulse approximation. Each of the real part and the imaginary part of the potential shows a pronounced “long tail” for the proton elastic scattering from halo nucleus ^14Be compared with the potentials for proton scattering from its adjacent nuclei ^12C and ^16O, which do not have halo structures.This kind of “long tail” phenomenon suggests another signature for halo nuclei. 相似文献
6.
Mattias Edn Jekabs Grins Zhijian Shen Zheng Weng 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,169(2):1
Using enhancement of the 27Al central-transition magnetization by applying RAPT prior to 27Al → 29Si cross-polarization, we demonstrate fast acquisition of 29Si one-dimensional MAS and two-dimensional 27Al–29Si HETCOR spectra on a new sialon phase Ba2Al3Si9N13O5. 相似文献
7.
Hongwei Hao Minsheng Wu Yifang Chen Jiaowen Tang Qingyu Wu 《Colloids and surfaces. B, Biointerfaces》2004,33(3-4):151-156
To prevent cyanobacterial bloom in eutrophic water by ultrasonic method, ultrasonic irradiations with different parameters were tested to inhibit Spirulina platensis from growth. The experimental result based on cyanobacterial growth, chlorophyll a and photosynthetic activity showed that, the ultrasonic irradiation inhibited cyanobacterial proliferation effectively, furthermore the inhibition effectiveness increased in the order: 200 kHz>1.7 MHz>20 kHz and became saturated with the increased power. The inhibition mechanism can be mainly attributed to the mechanical damage to the cell structures caused by ultrasonic cavitation, which was confirmed by light microscopy and differential interference microscopy. The optimal frequency of 200 kHz in cavition and sonochemistry was also most effective in cyanobacterial growth inhibition. The higher frequency of 1.7 MHz is weaker than 20 kHz in cavitation, but has more effective inhibition because it is nearer to the resonance frequency of gas vesicle. The inhibition saturation with ultrasonic power was due to the ultrasonic attenuation induced by the acoustic shielding of bubbles enclosing the radiate surface of transducer. 相似文献
8.
The content of residual monomers is one of the most important characteristics of polymer dispersions. As a result of the similar physicochemical parameters of ethyl acrylate and methyl methacrylate, it is very difficult to determine the residual monomers in acrylate dispersions obtained by emulsion polymerization of both monomers. Gas chromatography with capillary columns, however, permits separation of these monomers and their quantitative determination in acrylate dispersions. 相似文献
9.
A highly selective solid phase extraction sorbent for pre-concentration of sameridine made by molecular imprinting 总被引:5,自引:0,他引:5
Summary A novel approach to solid phase extraction, based on the use of a highly selective molecularly imprinted polymer, is presented.
The versatility of this type of sorbent for solid phase extraction was demonstrated in a model batch-wise pre-concentration
of sameridine prior to gas chromatography. Problems associated with leakage of remaining imprint molecules during the desorption
phase could be eliminated by the use of a close structural analogue of sameridine as the imprint species. It was found that
a major benefit of the imprinted polymer was its specificity, which lead to distinctly cleaner chromatographic traces and
ability to improve sensitivity by extracting sameridine from larger sample volumes. 相似文献
10.