全文获取类型
收费全文 | 2463篇 |
免费 | 234篇 |
国内免费 | 138篇 |
专业分类
化学 | 622篇 |
晶体学 | 12篇 |
力学 | 160篇 |
综合类 | 21篇 |
数学 | 728篇 |
物理学 | 1292篇 |
出版年
2024年 | 8篇 |
2023年 | 19篇 |
2022年 | 31篇 |
2021年 | 44篇 |
2020年 | 52篇 |
2019年 | 69篇 |
2018年 | 47篇 |
2017年 | 66篇 |
2016年 | 91篇 |
2015年 | 77篇 |
2014年 | 136篇 |
2013年 | 237篇 |
2012年 | 106篇 |
2011年 | 138篇 |
2010年 | 107篇 |
2009年 | 124篇 |
2008年 | 175篇 |
2007年 | 160篇 |
2006年 | 140篇 |
2005年 | 114篇 |
2004年 | 101篇 |
2003年 | 91篇 |
2002年 | 80篇 |
2001年 | 76篇 |
2000年 | 79篇 |
1999年 | 71篇 |
1998年 | 53篇 |
1997年 | 34篇 |
1996年 | 48篇 |
1995年 | 32篇 |
1994年 | 20篇 |
1993年 | 22篇 |
1992年 | 20篇 |
1991年 | 8篇 |
1990年 | 13篇 |
1989年 | 13篇 |
1988年 | 18篇 |
1987年 | 17篇 |
1986年 | 12篇 |
1985年 | 14篇 |
1984年 | 12篇 |
1983年 | 7篇 |
1982年 | 9篇 |
1981年 | 14篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1978年 | 7篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1969年 | 2篇 |
排序方式: 共有2835条查询结果,搜索用时 0 毫秒
1.
The aim of this paper is to introduce a new functional in thestudy of swelling porous elastic soils saturated by a fluid.This new functional is a useful tool; it allows us to provethe existence of solutions in the case of a compressible fluid.We also prove the stability of solutions and the exponentialdecay in the case of an incompressible fluid. We study as wellthe continuous dependence with respect to the initial time. 相似文献
2.
In photochemical vapor deposition of aluminum film on silicon using dimethylaluminum hydride, (CH3)2AlH, a surface reaction dominated below a (CH3)2AlH pressure of 0.3 m Torr at 200°C, which was induced only with the 160 nm band emitted from a deuterium lamp. A gas-phase reaction occurred above 0.3 mTorr at 200°C, which could be induced by both 160 nm and 240 nm emission bands from the lamp. To distinguish between surface ad gas-phase reactions, a thickness profile was used. At 240°C the surface reaction could be induced even by the 240 nm band, while the deposits formed under illumination of the two bands were thinner than those obtained with only the 240 nm band, indicating occurrence of vacuum ultraviolet (VUV)-enhanced desorption. The mechanism responsible for the observed wavelength dependence in unclear. The electrical resistivity of the films deposited at 200°C was 4.5 μΩ cm, which did not change with wavelength. 相似文献
3.
Enthalpies of solution have been measured from 5 to 85°C for aqueous tetraethyl- and tetrapropylammonium bromides, and the integral heat method is employed to evaluate
for these electrolytes over a wide temperature range. Data taken from the literature have been used to evaluate
for aqueous Bu4NBr over a similar temperature range. These data, along with similar data for Me4NBr, previously reported, have been used to evaluate absolute ionic heat capacities. While the absolute values agree only qualitatively with two other methods of division, the temperature dependences of the three methods essentially agree up to 65°C. Heat capacities due to structural effects on the solvent, obtained by subtracting the inherent heat capacities of the ions, are extraordinarily positive for all four tetraalkylammonium ions and have negative temperature coefficients, indicating that all four ions, including the tetramethylammonium ion, are structure-making ions. 相似文献
4.
Summary The dependence of the chloride distribution coefficient on the co-ion of solutions of different alkali fluorides, MF, up to 11M is tested on the strongly basic anion-exchange resin AG1-X10. Under the same experimental conditions the distribution coefficient decreases in the following order for M+: Na+>K+>Rb+>Cs+. This can be explained by the different co-ion-chloride interactions. The consequence of this interaction for a chromatographic separation of chloride is shown with 5M KF and CsF solutions, used as eluants. Depending on the fluoride concentration, the distribution coefficient passes through a minimum value to increase again at higher electrolyte concentration. The non-exchange electrolyte in the resin phase is responsible for this effect. In addition, the bromide and the iodide distribution coefficients up to 10M KF solutions are determined. One results is that the selectivity coefficient between halide ions increases at higher electrolyte concentrations. 相似文献
5.
Denize C. Favaro Rubén H. Contreras Cláudio F. Tormena 《Magnetic resonance in chemistry : MRC》2013,51(6):334-338
SOPPA(CCSD) calculations show that the FC term is the most important contribution to the through‐space transmission of JFN coupling constants for the fluoroximes studied in this work. Because of the well‐known behavior of FC term, a new rationalization for the experimental TSJFN SSCC is presented. It is mainly based on the overlap matrix (Sij) between fluorine and nitrogen lone pairs obtained from NBO analyses. An expression is proposed to take into account the influence of the electronic density (Dij) between coupled nuclei as well as the s% character at the site of the coupling nuclei of bonds and non‐bonding electron pairs involved in Dij. In using this approach, a linear correlation between TSJFN versus Dij is obtained. The most important aspect of this rationalization is related to the facility for understanding the behavior of some unusual experimental coupling constants. It is shown that, at least in this case, the electronic origin of the so‐called through‐space coupling is transmitted through to the overlap of orbitals on the coupled atoms, suggesting that, at least for these compounds, instead of through‐space coupling, it should better be dubbed as ‘through overlapping orbital coupling’. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
6.
Tsutomu Sato 《Pramana》1983,21(6):375-384
The first-order Raman spectra ofE
gandA
1g
modes in MnF2 crystal were measured at temperatures from 4.2 to 563 K, and the values of the linewidths obtained. The temperature dependence
of the linewidths was analyzed by the phonon dispersion curves based on the rigid ion model, and the result showed that it
was caused approximately by the cubic anharmonic term in crystal potential energy. 相似文献
7.
Jye -Chyl Lu Gouri K. Bhattacharyya 《Annals of the Institute of Statistical Mathematics》1990,42(3):543-559
In this article, several approaches are advanced towards the construction of bivariate Weibull models from the consideration of failure behaviors of the components of a two-component system. First, a general method of construction of bivariate life models is developed in the setting of random environmental effects. Some new bivariate Weibull models are derived as special cases and added insights are provided for some of the existing ones. In the course of model formulation in terms of the dependence structure, a new bivariate family of life distributions is constructed so as to incorporate both positive and negative quadrant dependence in the same parametric setting, and a bivariate Weibull model is obtained as a special case. Finally, some distributional properties are presented for a bivariate Weibull model derived from the consideration of random hazards. 相似文献
8.
The uncertainty principle lies at the heart of quantum physics, and is widely thought of as a fundamental limit of the measurement precision of incompatible observables. Here it is shown that the traditional uncertainty relation in fact belongs to the leading order approximation of a generalized uncertainty relation. That is, the leading order linear dependence of observables gives the Heisenberg type of uncertainty relations, while higher order nonlinear dependence may reveal more different and interesting correlation properties. Applications of the generalized uncertainty relation and the high order nonlinear dependence between observables in quantum information science are also discussed. 相似文献
9.
We study two estimators of the long-range parameter of a covariance stationary linear process. We show that one of the estimators
achieve the optimal semiparametric rate of convergence, whereas the other has a rate of convergence as close as desired to
the optimal rate. Moreover, we show that the estimators are asymptotically normal with a variance, which does not depend on
any unknown parameter, smaller than others suggested in the literature. Finally, a small Monte Carlo study is included to
illustrate the finite sample relative performance of our estimators compared to other suggested semiparametric estimators.
More specifically, the Monte-Carlo experiment shows the superiority of the proposed estimators in terms of the Mean Squared
Error.
The first author research was funded by the Economic and Social Research Council (ESRC) reference number: R000238212. The
second author research was funded by the Ministry of Education, Culture, Sports and Technology of Japan, reference number:
09CE2002 and B(2)10202202. 相似文献
10.
David Eisenbud Craig Huneke Bernd Ulrich 《Proceedings of the American Mathematical Society》2003,131(3):701-708
In this paper we show that the Rees algebra can be made into a functor on modules over a ring in a way that extends its classical definition for ideals. The Rees algebra of a module may be computed in terms of a ``maximal' map from to a free module as the image of the map induced by on symmetric algebras. We show that the analytic spread and reductions of can be determined from any embedding of into a free module, and in characteristic 0--but not in positive characteristic!--the Rees algebra itself can be computed from any such embedding.