全文获取类型
收费全文 | 933篇 |
免费 | 47篇 |
国内免费 | 106篇 |
专业分类
化学 | 633篇 |
晶体学 | 8篇 |
力学 | 35篇 |
数学 | 34篇 |
物理学 | 376篇 |
出版年
2023年 | 99篇 |
2022年 | 10篇 |
2021年 | 9篇 |
2020年 | 11篇 |
2019年 | 13篇 |
2018年 | 12篇 |
2017年 | 14篇 |
2016年 | 17篇 |
2015年 | 20篇 |
2014年 | 16篇 |
2013年 | 55篇 |
2012年 | 31篇 |
2011年 | 34篇 |
2010年 | 32篇 |
2009年 | 72篇 |
2008年 | 73篇 |
2007年 | 73篇 |
2006年 | 66篇 |
2005年 | 36篇 |
2004年 | 25篇 |
2003年 | 30篇 |
2002年 | 24篇 |
2001年 | 33篇 |
2000年 | 24篇 |
1999年 | 25篇 |
1998年 | 29篇 |
1997年 | 15篇 |
1996年 | 17篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 24篇 |
1992年 | 12篇 |
1991年 | 13篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1985年 | 11篇 |
1984年 | 5篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1978年 | 4篇 |
1977年 | 7篇 |
1973年 | 4篇 |
1972年 | 2篇 |
1971年 | 4篇 |
1970年 | 2篇 |
1969年 | 2篇 |
排序方式: 共有1086条查询结果,搜索用时 31 毫秒
1.
Jian Shen Huizhong Zeng Zhihong Wang Shengbo Lu Huidong Huang Jingsong Liu 《Applied Surface Science》2006,252(22):8018-8021
Polycrystalline Pb(Zr0.55Ti0.45)O3 thin film was deposited on Pt/Ti/SiO2/Si(1 0 0) by radio-frequency-magnetron sputtering method, and the writing of charge bits on the surface of PZT thin film was studied by Kelvin probe force microscopy. It is found that the surface potential of the negative charge bits are higher than those of the corresponding positive ones. When ferroelectric polarization switching occurs, the potential difference becomes even more remarkable. A qualitative model was proposed to explain the origin of the asymmetric charge writing. It is demonstrated that the internal field in the interface layer, which is near the ferroelectric/electrode interface in ferroelectric film, is likely to be the cause for the occurrence of this phenomenon. 相似文献
2.
H.L. Xu A. Persson S. Svanberg 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(2):233-236
New radiative lifetime measurements based on time-resolved laser-induced fluorescence techniques are reported for 18 even-parity
levels belonging to the 4f5d26p and 4f
25d
2 configurations of Ce I and 6 even-parity levels belonging to the 5d26s, 4f5d6p, and 4f6s6p configurations of Ce II. Free neutral and singly ionized cerium atoms were produced by laser ablation. The Ce I and Ce II
levels range in energy from 26 545 to 29 102 cm-1, and 42 573 to 48 152 cm-1, respectively.
Received 25 September 2002 Published online 4 March 2003 相似文献
3.
Robert H. Crabtree 《Journal of organometallic chemistry》2004,689(24):4083-4091
The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to σ bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related reactions of non-alkane substrates such as the Murai reaction are also discussed. 相似文献
4.
聚醚醚酮链结构与反应的模型化合物的量子化学研究 总被引:1,自引:1,他引:0
利用AM1方法对聚醚醚酮模型化合物全优化,结果为:芳环平均相互扭转角为33.0度,桥键角117.0-118.0度,其分子结构拓扑图形表明:所有苯环(核)为平面构型,但其内角扭曲;其氢原子对苯环构型无实质性贡献,在更长链的计算中,冻结苯核与氢原子也得出满意结果,根据Mulliken键序与电荷讨论了醚交换与磺化反应。 相似文献
5.
Enrique J. Baran 《Monatshefte für Chemie / Chemical Monthly》1991,122(6-7):479-481
Summary Mean amplitudes of vibration for OTeF
5
–
have been calculated from known spectroscopic and structural data in a wide temperature range. The results are briefly discussed in comparison with those of related species. 相似文献
6.
Push-pull dithiafulvenes with reduced bond length alternation (BLA) and high optical nonlinearities have been prepared. The interplay between the proaromaticity of the donor and the structural and optical properties of these merocyanines is discussed. The donor ability of dithiafulvenes can reach that of ferrocene or dialkylaminophenyl groups. 相似文献
7.
本文用多组态HXR自洽场方法和优化以Slater径向积分法相结计算了类锂离子(Z=13~17,19)1s~2nl~2LJ(2≤n≤5,0≤l≤4)能级之间的跃迁波长和振子强度,并和实验进行了比较。就软X射线激光跃迁4f—3d而言,本文计算的波长值比其它文献的计算值更接近于观测值。 相似文献
8.
Leyla Özdemir Güldem Ürer 《Journal of Quantitative Spectroscopy & Radiative Transfer》2007,103(2):281-301
Multiconfiguration Hartree-Fock calculations with Breit-Pauli relativistic corrections are reported for electric dipole transition (E1) energies, wavelengths, weighted oscillator strengths and transition probabilities between all of the 1s2, 1sns and 1snp (2?n?9) states for He-like silicon. The results are found to compare very well with available other results except Δn=0 due to differences in the calculated excitation energies. 相似文献
9.
10.
The behavior of three-dimensional bond fluctuation model chains tethered on an adsorbing flat surface was simulated by the Monte Carlo method. The dependence of the number of surface contacts M on the interaction strength e and the chain length N was investigated by a finite-size scaling law M = N[a0 + a1N1/vk + O((N 1/vk)2)] for e near the critical adsorption point ec, i.e., k ≡(e-ec)/ec closes to 0. The critical adsorption point was estimated to be ec = 0.93, and the exponents 61542; = 0.49 and 1/v= 0.57. 相似文献