用峰鉴别技术反相高效液相色谱法测定火锅汤料中微量吗啡

本文报道了以峰鉴别技术为定性依据的测定火锅汤料中微量吗啡的反相高效液相色谱法。本法采用改良的Ｓｔａｓ－ｏｔｔｏ法分离提取复杂样品中的微量吗啡。由于采用峰鉴别技术，增加了定性参数，大大提高了定性方法的准确性。本法简便、快速。最低检出浓度为０．０４ｍｇ／Ｌ。在数十例样品分析中，与其它仪器分析结果比照，非常符合。     

茶汤及河水中铬的形态分析

本文采用７１７型强碱性阴离子交换树脂、活性炭分离富集与偶氮胂Ⅲ光度法结合，研究了铬形态的分离及测定，提出了铬的形态分析方法，有此法测定了茶汤及河水中铬的总量，悬浮态．溶解态、无机态、有机态、Ｃｒ（Ⅲ）和Ｃｒ（Ⅵ）。茶汤中铬主要以有机态存在，而河水中铬则主要以悬浮态存在。     

高效液相色谱-荧光检测法测定罂粟籽和火锅汤料中的罂粟碱

用所建立的高效液相色谱-荧光检测法测定了罂粟籽和火锅汤料中的罂粟碱。采用的色谱柱为RP-C18柱(250 mm×4.6 mm i.d.,5 μm);检测激发波长为285 nm,发射波长为355 nm;流动相为甲醇-0.02 mol/L乙酸铵(体积比为70∶30),流速0.8 mL/min。实验结果表明,罂粟碱的进样量为1×10-4~0.1 μg时其质量浓度与相应峰面积有良好的线性关系,最低检测限(以信噪比大于3计)达到0.02 ng。罂粟籽中罂粟碱的回收率为99.0%～100.8%。方法快速准确,简便灵敏,分离度高,能够满足有关食品中罂粟碱的检测要求。     

Effects of thermoultrasonic treatment on characteristics of micro-nano particles and flavor in Greenland halibut bone soup

In order to investigate the effects of thermoultrasonic treatment (TUT) on the formation of colloidal micro-nano particles (MNPs) and the quality of halibut bone soup, nutrients, particle characteristics, and flavor characteristics were analyzed. The morphology of MNPs was studied using an optical microscope. Results showed that TUT could increase the nutrient content (total sugars, 22.15 mg/100 mL; water soluble proteins, 173.24 mg/mL; fatty acids, 1779.7 mg/100 mL; solids, 3.16 g/100 mL), reduce the particle size (605.92 nm) and interfacial tension. Meanwhile, TUT make the halibut bone soup has better emulsifying characteristics and stability. The contents of flavor substances, such as esters, 5′-nucleotides, organic acids in the halibut bone soup were more abundant, while the contents of hexanal and 1-octen-3-ol and fishy off-flavor were reduced in TUT group. The overall odor and taste outline were more harmonious. Therefore, TUT can be used in the production of high quality fish bone soup, and TUT could be considered as a good deep processing technology for halibut bone and improve economic efficiency.     

Random walk loop soup

The Brownian loop soup introduced by Lawler and Werner (2004) is a Poissonian realization from a -finite measure on unrooted loops. This measure satisfies both conformal invariance and a restriction property. In this paper, we define a random walk loop soup and show that it converges to the Brownian loop soup. In fact, we give a strong approximation result making use of the strong approximation result of Komlós, Major, and Tusnády. To make the paper self-contained, we include a proof of the approximation result that we need.

     

聚变等离子体中高能量粒子驱动的鱼骨模不稳定性研究

在考虑高能量粒子密度的空间分布及箍缩角分布的条件下,建立了研究鱼骨模的色散关系,并作了数值研究。结果表明：当高能量粒子的密度高于某个阈值时,鱼骨模会在高能量粒子密度梯度最大处被激发,其频率与高能量粒子的环向进动频率一致。在高β_h 区间,高能量勉强通行粒子将驱动鱼骨模进入第二稳定区。高能量捕获粒子能激发非共振鱼骨模,与勉强通行粒子激发的鱼骨模类似,在高β_h 区存在第二稳定区。     

Sustained high βN plasmas on EAST tokamak

Sustained high normalized beta (${\beta }_N～1.9$) plasmas with an ITER-like tungsten divertor have been achieved on EAST tokamak recently. The high power NBI heating system of 4.8 MW and the 4.6 GHz lower hybrid wave of 1 MW were developed and applied to produce edge and internal transport barriers in high ${\beta }_N$ discharges. The central flat q profile with $q(\rho )～1$ at $\rho <0.3$ region and edge safety factor $q_{95}=4.7$ is identified by the multi-channel far-infrared laser polarimeter and the EFIT code. The fraction of non-inductive current is about 40%. The relation between fishbone activity and ITB formation is observed and discussed.     

玄参汤剂的荧光光谱分析

测量了相应的激发光谱以及溶液的pH值,发现同种玄参汤剂中的荧光峰值波长随着激发波长的增加而增加;冷浸玄参汤剂的荧光峰为441 nm,而沸煮玄参汤剂的为532 nm;相应激发光谱由双峰结构向单峰结构转变,并且激发峰值也有明显的红移;同时其pH值由5.5变化到4.1。结合有机物混合体系中的荧光产生机理,解释了上述现象的产生原因：玄参汤剂中的不同荧光分子之间的相互作用以及相同荧光分子内部的能量转移;加热所导致的荧光大分子含量的增加和荧光分子间氢键二聚体的形成。文章对中药玄参的药理学研究具有一定的参考价值,为玄参汤剂质量鉴定提供了一种有效的测量方法。     

汤剂中成药中微量元素的研究

采用Z－8000型偏振塞曼原子吸收分光光度仪,对心脑宁,密炼川贝枇杷膏,清热解毒口服液,保尔康糖浆等8种中成药中Cu,Mn,Zn,Na等9种元素进行分析研究,结果表明,汤剂中成药中含有多种微量元素,这些微量元素与药效有一定联系,汤剂中成药中微量元素的含量比丸剂或胶囊制剂的微量元素含量总体都较低一些。     

在星际媒介中合成H2NCH2CN分子的理论研究

在早期地球原始化学生命起源过程中, 氨基酸是重要的必需的生物化合物, 生成肽和蛋白. 为了探究一个可能的新的氨基酸起源, 采用密度泛函理论(B3LYP)在6-311++G(d, p) 基组水平上研究了在星际媒介条件下在气相中和在模拟的冰颗粒表面上的化学反应: CH2NH分子和两个异构体分子HNC/HCN通过Strecker合成生成H2NCH2CN(氨基乙氰, 一个重要的苷氨基酸前置分子). 在研究体系中, CH2NH、HCN、HNC 和H2O分子存在于星际密集分子云中, 且早于地球广泛存在. 研究证明, 这些分子之间在星际媒介条件下和在冰颗粒表面上通过Strecker合成路线很容易生成H2NCH2CN. 所以, H2NCH2CN分子在宇宙的星际密集分子云中是广泛存在的. 还讨论了H2NCH2CN分子在新的氨基酸起源中所起的作用, 以及在通过“原始汤”生命起源理论解析早期地球生命起源中可能所起的作用.