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The Mannich-type reaction of imines with (1-methoxy-2-methylpropenyloxy)trimethylsilane and aza-Diels-Alder reaction of imines with Danishefsky's diene can be carried out in scCO2 in the presence of lithium heptadecafluorooctanesulfonate which offer a way to synthesize β-amino carbonyl compounds and nitrogen-containing six-membered ring compounds under environmentally benign conditions. 相似文献
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Standardization and certification in the area of environmentally degradable plastics 总被引:1,自引:0,他引:1
Andrej Krzan Sarunya Hemjinda Stanislav Miertus Emo Chiellini 《Polymer Degradation and Stability》2006,91(12):2819-2833
Environmentally degradable polymers and plastics (EDPs) are a group of polymeric materials experiencing a rapid growth in number as well as in their applications and quantities used. The assessment of their key characteristic - degradability, including eventually biodegradability as the ultimate stage, is scientifically and technically a challenging issue and has led to differing interpretations in the past. In order to standardize techniques and criteria a number of standards were established by different standardization bodies which are also used as a basis for certification schemes. An up-to-date inventory of the rapidly growing standardization body is presented with basic interpretation to help guide the non-expert. A basic introduction to EDPs and polymer degradation is added for clarity. 相似文献
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ZnCl2/粘土-SA01催化剂上二苯甲烷的合成 总被引:6,自引:0,他引:6
在环境友好ZnCl2/粘土-SA01催化剂上合成了二苯甲烷,较系统地考察了负载量、苯/苄基氯摩尔比、催化剂用量、反应温度、反应时间对该傅克反应的影响,并与催化剂的表面性质关联.实验结果表明,该催化剂具有良好的催化活性和稳定性并易于回收重复使用. 相似文献
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Thermoanalytical characterization of carbon/carbon hybrid material, Apple Woodceramics 总被引:3,自引:0,他引:3
Woodceramics, a carbon/carbon composite of plant-originated carbon reinforced by glassy carbon from phenolic resin, was prepared from apple pomace at carbonizing temperatures of 1073 K (AWC800) and 1473 K (AWC1200), and characterized by thermoanalytical methods and X-ray diffraction (XRD). Simultaneous differential scanning calorimetry (DSC) and thermogravimetric (TG) showed complicated overlapping reactions similar to those of coal. The initial temperature of pyrolysis was obtained by fitting logistic functions to observed TG data. The results suggested that AWC1200 contained more volatile matter than AWC800. In an inert atmosphere, complicated devolatilization takes place. In an oxidizing atmosphere, thermal change occurs roughly in four steps: desorption of physically adsorbed matter; pyrolysis into aliphatic and aromatic fragments; ignition; combustion of char. The oxidation resistance of AWC1200 was superior to AWC800. 相似文献
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A new approach to indolizines has been developed using a 5-endo-trig iodocyclization of allylic esters followed by isomerization and dehydroiodination facilitated by triethylamine at rt. This mild procedure enabled us to synthesize a number of highly substituted indolizines in good yields. 相似文献
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A simply synthesized 4-aminonaphthalimide derivative 1 expresses both polarity and viscosity sensitive fluorescence spectra, indicating its potential usage as an environmentally sensitive fluorescence probe. By comparing the fluorescence behavior of 1 with that of a known 4-aminonaphthalimide derivative 2, it was found that the substitution of the 4-amino group has profound influence on the environmentally sensitive fluorescence properties of 4-aminonaphthalimide. 相似文献
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Jyoti M. Madar Samundeeswari L. Shastri Megharaja Holiyachi Nirmala Naik Rashmi Kulkarni 《合成通讯》2018,48(4):375-386
Pursuing our recent interest regarding antimicrobial and anti-inflammatory activities of coumarin derivatives, we have synthesized a series of coumarin-linked pyridopyrimidinones by using Baylis Hillman adduct in aqueous condition with high purity. Pyrido[1,2-a]pyrimidin-2-ones are important class of heterocyclic compounds because of their use in medicinal and agro chemistry as active agents. All these newly synthesized compounds were evaluated for their antimicrobial and anti-inflammatory activity. Coumarin pyridopyrimidinones showed excellent anti-inflammatory activity against both MMP-2 and MMP-9 gelatinase zymography, whereas considerable good activity against Gram-positive and Gram-negative bacterial strains; however, antifungal activity observed in these series is more or less inactive. The active compounds of these series would be promising structural templates for the development of novel and more efficient anti-inflammatory agent. 相似文献
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Let G be a graph with vertex set V(G) and edge set E(G). A labeling f : V(G) →Z2 induces an edge labeling f*: E(G) → Z2 defined by f*(xy) = f(x) + f(y), for each edge xy ∈ E(G). For i ∈ Z2, let vf(i) = |{v ∈ V(G) : f(v) = i}| and ef(i) = |{e ∈ E(G) : f*(e) =i}|. A labeling f of a graph G is said to be friendly if |vf(0)- vf(1)| ≤ 1. The friendly index set of the graph G, denoted FI(G), is defined as {|ef(0)- ef(1)|: the vertex labeling f is friendly}. This is a generalization of graph cordiality. We investigate the friendly index sets of cyclic silicates CS(n, m). 相似文献
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A convenient,effcient and environmentally benign procedure has been developed for the synthesis of pyrano[4,3-b]pyran derivatives via a one-pot,three-component reaction of 4-hydroxy-6-methylpyran-2-one,aldehydes and malononitrile in water using H6P2W18O62á18H2O as catalyst.Reusability of the catalyst and reaction media,short reaction times and easy isolation of products are some added advantages of the present methodology. 相似文献