全文获取类型
收费全文 | 1415篇 |
免费 | 138篇 |
国内免费 | 24篇 |
专业分类
化学 | 823篇 |
晶体学 | 5篇 |
力学 | 55篇 |
综合类 | 3篇 |
数学 | 27篇 |
物理学 | 664篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 21篇 |
2021年 | 18篇 |
2020年 | 56篇 |
2019年 | 31篇 |
2018年 | 32篇 |
2017年 | 20篇 |
2016年 | 65篇 |
2015年 | 50篇 |
2014年 | 63篇 |
2013年 | 111篇 |
2012年 | 58篇 |
2011年 | 58篇 |
2010年 | 68篇 |
2009年 | 91篇 |
2008年 | 66篇 |
2007年 | 126篇 |
2006年 | 102篇 |
2005年 | 62篇 |
2004年 | 69篇 |
2003年 | 73篇 |
2002年 | 56篇 |
2001年 | 48篇 |
2000年 | 37篇 |
1999年 | 30篇 |
1998年 | 36篇 |
1997年 | 32篇 |
1996年 | 21篇 |
1995年 | 13篇 |
1994年 | 12篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有1577条查询结果,搜索用时 15 毫秒
1.
Zi‐Niu Wu 《国际流体数值方法杂志》2005,48(5):541-564
The widely used locally adaptive Cartesian grid methods involve a series of abruptly refined interfaces. In this paper we consider the influence of the refined interfaces on the steady state errors for second‐order three‐point difference approximations of flow equations. Since the various characteristic components of the Euler equations should behave similarly on such grids with regard to refinement‐induced errors, it is sufficient enough to conduct the analysis on a scalar model problem. The error we consider is a global error, different to local truncation error, and reflects the interaction between multiple interfaces. The steady state error will be compared to the errors on smooth refinement grids and on uniform grids. The conclusion seems to support the numerical findings of Yamaleev and Carpenter (J. Comput. Phys. 2002; 181: 280–316) that refinement does not necessarily reduce the numerical error. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
2.
Yasuyuki Agari Kiyofumi Sakai Yosikazu Kano Ryoki Nomura 《Journal of Polymer Science.Polymer Physics》2007,45(21):2972-2981
We prepared biodegradable poly(ethylene oxide) (PEO)/poly(L ‐lactic acid) (PLLA) graded blends by the dissolution–diffusion process, and discussed the biodegradability and tensile strength of the graded blends by comparing isotropic blend and PLLA only. All the graded blends were degraded more largely than the PLLA only and isotropic blend (PEO: 37.5 wt %), which had the same content as the total content of those graded blends. The graded blend having most excellent wide compositional gradient was degraded most largely with the enzyme. Thus, graded structure of the blends promoted their biodegradabilities large. It was considered that the dissolution of PEO with water increased the surface area attacked by the enzyme, while PEO caught PLLA oligomers to promote the biodegradation of PLLA. Then, the biodegradabilities of the graded blends were suppressed by the increasing crystallinity of PLLA. Furthermore, the strengths of all the graded blends were larger than those of the isotropic blend. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2972–2981, 2007 相似文献
3.
Md. Nur Alam Per B. Zetterlund Masayoshi Okubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4995-5004
Bimolecular termination in nitroxide‐mediated radical polymerization in miniemulsion has been investigated through the heating of a polystyrene–2,2,6,6‐tetramethylpiperidinyl‐1‐oxy macroinitiator and its 4‐hydroxy‐2,2,6,6‐tetramethylpiperidinyl‐1‐oxy analogue in an aqueous toluene dispersion with sodium dodecyl benzenesulfonate as a surfactant at 125 °C. The level of bimolecular termination by combination, evaluated from the high‐molecular‐weight shoulder, was higher in miniemulsion than in solution and increased with decreasing particle size. Quantitative analysis revealed that these results cannot be rationalized solely by nitroxide partitioning to the aqueous phase. The results are explained by an interface effect, by which nitroxide is adsorbed or located at the aqueous–organic interface. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4995–5004, 2007 相似文献
4.
Rui M. Novais Frank Simon Petra Pötschke Tobias Villmow José A. Covas Maria C. Paiva 《Journal of polymer science. Part A, Polymer chemistry》2013,51(17):3740-3750
This work reports the study of the effect of chemical functionalization of carbon nanotubes on their dispersion in poly(lactic acid). The nanotubes were functionalized by the 1,3‐dipolar cycloaddition reaction, generating pyrrolidine groups at the nanotube surface. Further reaction of the pyrrolidine groups with poly(lactic acid) was studied in solution and in the polymer melt. The former involved refluxing the nanotubes in a dimethylformamide/polymer solution; the latter was carried out by direct melt mixing in a microcompounder. The carbon nanotubes collected after each process were characterized by thermogravimetry and by X‐ray photoelectron spectroscopy, showing evidence of polymer bonded to the nanotube surface only when the reaction was carried out in the polymer melt. The composites with polymer modified nanotubes present smaller average agglomerate area and a narrower agglomerate area distribution. In addition, they show improved tensile properties at low CNT concentration and present lower electrical resistivity. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3740–3750 相似文献
5.
6.
G. B. Parravicini A. Stella M. C. Ungureanu P. G. Merli A. Migliori P. Cheyssac R. Kofman 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):219-222
Both theoretical and experimental works give evidence that
gallium exhibits solid phases labelled , , , besides the
stable phase strongly dependent both on the size and the
confinement conditions. An experimental technique was used based
on capacitance and conductance measurements
vs. temperature in the
audiofrequency range. This technique is particularly sensitive
to the conditions of the investigated particle surface that
plays a fundamental role in the melting and more generally in
the phase transition processes. In particular the strict
relation between the derivative of the capacitance with respect
to the temperature, dC/dT, and the entropy of the system is
considered. In gallium nanoparticles 20 nm in radius, only the
phase is shown to occur. Further the transition to liquid phase
was detected. The melting process was found to start about 65 K
below the full melting temperature value. In the case of
particles 10 nm in radius, where different metastable phases may
occur, the capacitance vs.
temperature curve was found to display abrupt changes of the
slope. The singularities are associated to a well defined
transition temperature. 相似文献
7.
Pierre Devillard 《Journal of statistical physics》1991,62(1-2):443-451
We determine by Monte Carlo simulations the width of an interface between the stable phase and the metastable phase in a two-dimensional Ising model with a magnetic field, in the case of nonconversed order parameter (Glauber dynamics). At zero temperature, the width increases ast
with–1/3, as predicted by earlier theories. As temperature increases, the value of the effective exponent that we measure decreases toward the value 1/4, which is the value in the absence of magnetic field. 相似文献
8.
Kevin E. Bassler Kazuo Sasaki Robert B. Griffiths 《Journal of statistical physics》1991,62(1-2):45-88
Certain features in Frenkel-Kontorova and other models of phases with a one-dimensional modulation can be analyzed by assuming parallel interfaces separating sets of lattice planes belonging to two different phases, and treating the free energy to create interfaces, as well as the interaction of two, three, or more interfaces, as phenomenological parameters. A strategy employed by Fisher and Szpilka for interacting defects can be extended to the case of interfaces, allowing a systematic study of the phase diagram by ignoring all interface interactions, and then successively taking into account pair, triple, and higher-order terms. The possible phase diagrams which can occur near the point where =0 include: various sorts of endpoints analogous to critical endpoints, an accumulation point of first-order transitions and triple points, and a self-similar structure which we call an upsilon point, which turns out to be an accumulation point of an infinite number of segments of first-order transition lines, each of which terminates in two upsilon points. 相似文献
9.
Iulian Preda Leonardo Soriano Daniel Díaz‐Fernández Guillermo Domínguez‐Cañizares Alejandro Gutiérrez Germán R. Castro Jesús Chaboy 《Journal of synchrotron radiation》2013,20(4):635-640
This work reports an X‐ray absorption near‐edge structure (XANES) spectroscopy study at the Ni K‐edge in the early stages of growth of NiO on non‐ordered SiO2, Al2O3 and MgO thin films substrates. Two different coverages of NiO on the substrates have been studied. The analysis of the XANES region shows that for high coverages (80 Eq‐ML) the spectra are similar to that of bulk NiO, being identical for all substrates. In contrast, for low coverages (1 Eq‐ML) the spectra differ from that of large coverages indicating that the local order around Ni is limited to the first two coordination shells. In addition, the results also suggest the formation of cross‐linking bonds Ni—O—M (M = Si, Al, Mg) at the interface. 相似文献
10.
The properties of manganite/ruthenate superlattices are reviewed with a specific focus on the manganite/ruthenate interface. La0.7Sr0.3MnO3/SrRuO3 and Pr0.7Ca0.3MnO3/SrRuO3 superlattices grow with a high crystalline perfection as illustrated in the figure to the right: at the interface the individual cation species can be clearly identified, interdiffusion is marginal. The superlattices show magnetization processes with an intricate interplay between magnetocrystalline anisotropy, size of the layer magnetization, spin confinement and interfacial antiferromagnetic interlayer coupling. There is further an unprecedented Curie temperature stabilization at room temperature values of the La0.7Sr0.3MnO3 layers in the superlattices down to layer thicknesses of one unit cell. The magnetotransport properties, especially the Hall effect, indicate the existence of a quasi‐two‐dimensional hole gas at the La0.7Sr0.3MnO3/SrRuO3 interface; this is further supported by an analysis of cation displacements as determined from scanning transmission electron microscopy. The manganite/ruthenate interface might be considered as a model system for the study of interfacial reconstruction and charge transfer in a highly correlated ferromagnetic system.