全文获取类型
收费全文 | 489篇 |
免费 | 42篇 |
国内免费 | 6篇 |
专业分类
化学 | 111篇 |
力学 | 11篇 |
综合类 | 1篇 |
数学 | 245篇 |
物理学 | 169篇 |
出版年
2023年 | 17篇 |
2022年 | 12篇 |
2021年 | 5篇 |
2020年 | 11篇 |
2019年 | 9篇 |
2018年 | 8篇 |
2017年 | 9篇 |
2016年 | 16篇 |
2015年 | 10篇 |
2014年 | 37篇 |
2013年 | 59篇 |
2012年 | 36篇 |
2011年 | 43篇 |
2010年 | 41篇 |
2009年 | 41篇 |
2008年 | 20篇 |
2007年 | 34篇 |
2006年 | 23篇 |
2005年 | 7篇 |
2004年 | 13篇 |
2003年 | 13篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 9篇 |
1982年 | 7篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有537条查询结果,搜索用时 15 毫秒
1.
In this paper, we apply a three-stage-DEA model to the Spanish Professional Football League, which means separating the teams’
economic behaviour into three components: operating efficiency—of the offence and defence—athletic or operating effectiveness,
and social effectiveness. The results showed that the technical inefficiency of the defence is greater than that of the offence,
both being caused by aspects linked to the poor management of players’ abilities and by the football team’s size. Teams showed
a favourable evolution of their offensive and defensive efficiency during the 2004/2005 season and to a lesser extent in the
season before. The point system assigned by the professional football league regulations evaluates the teams’ athletic effectiveness,
but we detected that the teams with the most experience perform athletically in a more effective manner. Their social effectiveness
is strongly related to the level of play in itself and to factors linked to their PFL ranking: participation in international
competitions for important football teams; or the struggle of minor football teams to stay in the first division. 相似文献
2.
Efficiencies of the maximum pseudolikelihood estimator and a number of related estimators for the case-cohort sampling design in the proportional hazards regression model are studied. The asymptotic information and lower bound for estimating the parametric regression parameter are calculated based on the effective score, which is obtained by determining the component of the parametric score orthogonal to the space generated by the infinite-dimensional nuisance parameter. The asymptotic distributions of the maximum pseudolikelihood and related estimators in an i.i.d. setting show that these estimators do not achieve the computed asymptotic lower bound. Simple guidelines are provided to determine in which instances such estimators are close enough to efficient for practical purposes. 相似文献
3.
基于错误概率达到最小的原则,该文在罐子模型序贯试验中构造了一种渐近最优设计。在这种设计下,不仅能使病员以较多机会分配到较好的处理,而且能使估计量的统计效率在一定意义下达到最优。 相似文献
4.
Hans-Gerd Janssen Henri M. J. Snijders Jacques A. Rijks Carel A. Crarners Peter J. Schoenmakers 《Journal of separation science》1991,14(7):438-445
The effects of the pressure drop across the column on retention and efficiency in SFC have been studied. Numerical methods are described which enable the prediction of hold-up time and pressure drop in both packed and open tubular columns. Predictions of both hold-up time and pressure drop are in good agreement with experimental data. The density gradient along the column can be calculated using the numerical methods and a procedure is described which enables the calculation of the overall capacity factors of the solutes from the density profile in the column. Significant variations of the capacity factor are observed along the column. The effect of the density gradient along the column on local diffusivity and dispersion is studied. The column efficiency in systems with significant pressure drops is affected by changes in: the linear velocity of the mobile phase; the diffusion coefficients; and the capacity factors of the solutes along the column. The overall efficiency of the chromatographic system can be calculated if, as is the case for open tubular columns, adequate plate height equations are available. 相似文献
5.
Summary A program is described which calculates the number of effective plates and the coating efficiency over the entire range of a test chromatogram. The peak widths at half height are derived by assuming a Gaussian peak shape. The interpolated peak width at k=4 is used for computing a standardized number of effective plates. Plate height, column permeability, overall performance and a novel parameter called sampling efficiency are calculated from 5 other figures — i. e. carrier gas code, pressure drop, column length, column temperature and particle size.Dedicated to Dr. Leslie S. Ettre for his 60th birthday. 相似文献
6.
Leonid M. Blumberg 《Journal of separation science》1993,16(1):31-38
In linear chromatography (i.e. chromatography performed in the absence of sample overloading), when the plate height of a column is roughly uniform along its length, variations in the velocities of solutes are the only possible causes of erosion of efficiency. The sources of these variations (variations in capacity ratio and in the density of the mobile phase, etc.) play no direct role in the erosion of efficiency except through their effect on solute velocities. In other words, what eventually causes the erosion of efficiency is merely variation in the time required for solutes to traverse equally small segments of a column. Significant erosion can only arise from abrupt and deep deceleration of solutes in one or several relatively small segments of a column. If erosion of efficiency caused by pressure gradients in linear SFC is to be large, the depth and the sharpness of the deceleration of a solute must go beyond that hitherto confirmed experimentally. Many relevant examples are analyzed graphically. 相似文献
7.
<正> 光敏氧化效率是由敏化剂分子吸收光量子数及其产生单重态氧的量子产率决定的,这要求敏化剂的吸收光谱同光源的发射光谱很好地匹配。本文报道竹红菌甲素匹配高压钠灯有效地产生单重态氧,高效光敏氧化一系列具有不同反应活性的底物,成为单重态氧化学中一个新的光敏氧化体系。 相似文献
8.
Using statistically designed experiments, 12,500 observations are generated from a 4-pieced Cobb-Douglas function exhibiting increasing and decreasing returns to scale in its different pieces. Performances of DEA and frontier regressions represented by COLS (Corrected Ordinary Least Squares) are compared at sample sizes ofn=50, 100, 150 and 200. Statistical consistency is exhibited, with performances improving as sample sizes increase. Both DEA and COLS generally give good results at all sample sizes. In evaluating efficiency, DEA generally shows superior performance, with BCC models being best (except at corner points), followed by the CCR model and then by COLS, with log-linear regressions performing better than their translog counterparts at almost all sample sizes. Because of the need to consider locally varying behavior, only the CCR and translog models are used for returns to scale, with CCR being the better performer. An additional set of 7,500 observations were generated under conditions that made it possible to compare efficiency evaluations in the presence of collinearity and with model misspecification in the form of added and omitted variables. Results were similar to the larger experiment: the BCC model is the best performer. However, COLS exhibited surprisingly good performances — which suggests that COLS may have previously unidentified robustness properties — while the CCR model is the poorest performer when one of the variables used to generate the observations is omitted. 相似文献
9.
S. L. Prunty 《International Journal of Infrared and Millimeter Waves》1985,6(6):471-479
This paper presents a simple theory based on the diffraction integral approach for calculating the coupling efficiency in waveguide lasers which employ plane or spherical mirrors. The results obtained differ only slightly from a full rigorous approach, due to the fact that only less than one percent of the beam energy lies outside the waveguide aperture. The infinite aperture approximation employed here leads to an explicit compact formula for the coupling efficiency, whereas exact calculations lead to expressions requiring numerical integration for their evaluation. 相似文献
10.
The effect of injection procedures on efficiency in micellar electrokinetic capillary chromatography
Summary Micellar electrokinetic capillary chromatography (MECC) involves the application of a high voltage (10–30 KV) across a capillary
column (75μm i.d.) which is filled with a solution containing micelles. The mobile phase in this work consisted of sodium
dodecyl sulfate in an aqueous borate/phosphate buffer system. Injection parameters in MECC were investigated to minimize the
contribution to band-broadening resulting from the injection process. Efficiencies as high as 240,000 theoretical plates/meter
are reported. 相似文献