Effect of heat release distribution on combustion oscillation

This paper describes the effect of flame position and its spatial variation on prediction accuracy of combustion oscillation in a dry low emission (DLE) combustor. A one-dimensional linear model has been developed. The flame is usually treated as fixed and located at a single axial plane in conventional analysis. However, in practice, the flame position varies during operation. A new flame model considering this variation by a spatial distribution function has been developed. Variation of flame position is empirically measured by using UV images of OH radicals in the oscillating flame. A triangular distribution function is introduced into the flame model because it is similar to the experimentally obtained distribution function. A ‘top-hat’ distribution is also considered to test the influence of distribution shape on the result. Numerical results are compared with experimental data. The triangular flame model shows better prediction of the stability boundaries of combustion oscillation compared with the simple flame sheet model. The results of the top-hat flame model differ from those of the experiment. It is found that consideration of the spatial distribution yields good results for the DLE combustor.     

Comparative PL study of individual ZnO nanorods,grown by APMOCVD and CBD techniques

The photoluminescence properties of individual ZnO nanorods, grown by atmospheric pressure metalorganic chemical vapor deposition (APMOCV) and chemical bath deposition (CBD) are investigated by means of temperature dependent micro-PL. It was found that the low temperature PL spectra are driven by neutral donor bound exciton emission D⁰X, peaked at 3.359 and 3.363 eV for APMOCVD and CBD ZnO nanorods, respectively. The temperature increase causes a red energy shift of the peaks and enhancement of the free excitonic emission (FX). The FX was found to dominate after 150 K for both samples. It was observed that while APMOCVD ZnO nanorods possess a constant low signal of visible deep level emission with temperature, the ZnO nanorods grown by CBD revealed the thermal activation of deep level emission (DLE) after 130 K. The resulting room temperature DLE was a wide band located at 420–550 nm. The PL properties of individual ZnO nanorods can be of importance for their forthcoming application in future optoelectronics and photonics.