全文获取类型
收费全文 | 596篇 |
免费 | 13篇 |
国内免费 | 38篇 |
专业分类
化学 | 94篇 |
力学 | 184篇 |
综合类 | 7篇 |
数学 | 152篇 |
物理学 | 210篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 13篇 |
2019年 | 8篇 |
2018年 | 10篇 |
2017年 | 12篇 |
2016年 | 19篇 |
2015年 | 14篇 |
2014年 | 22篇 |
2013年 | 27篇 |
2012年 | 19篇 |
2011年 | 44篇 |
2010年 | 30篇 |
2009年 | 44篇 |
2008年 | 41篇 |
2007年 | 47篇 |
2006年 | 34篇 |
2005年 | 33篇 |
2004年 | 35篇 |
2003年 | 28篇 |
2002年 | 14篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 20篇 |
1998年 | 10篇 |
1997年 | 14篇 |
1996年 | 10篇 |
1995年 | 14篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 5篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 3篇 |
1979年 | 2篇 |
排序方式: 共有647条查询结果,搜索用时 390 毫秒
1.
The biodegradability of phtalic acid esters in marine and freshwater environments was characterized by their binding free energy with corresponding degrading enzymes. According to comprehensive biodegradation effects weights, the binding free energy values were converted into dimensionless efficacy coefficient using ratio normalization method. Then, considering comprehensive dual biodegradation effects value and the structural parameters of PAEs in both marine and freshwater environments, a 3D-QSAR pharmacophore model was constructed, five PAE derivatives (DBP−COOH, DBP−CHO, DBP−OH, DINP−NH2, and DINP−NO2) were screened out based on their environmental friendliness, functionality and stability. The prediction of biodegradation effects on five PAE derivatives by biodegradation models in marine and freshwater environment increased by 15.90 %, 15.84 %, 27.21 %, 12.33 %, and 8.32 %, and 21.57 %, 15.21 %, 20.99 %, 15.10 %, and 9.74 %, respectively. By simulating the photodegradation path of the PAE derivative molecular, it was found that DBP−OH can generate .OH and provides free radicals for the photodegradation of microplastics in the environment. 相似文献
2.
Paul Bankston 《Archive for Mathematical Logic》2006,45(1):97-112
The Chang-Łoś-Suszko theorem of first-order model theory characterizes universal-existential classes of models as just those
elementary classes that are closed under unions of chains. This theorem can then be used to equate two model-theoretic closure
conditions for elementary classes; namely unions of chains and existential substructures. In the present paper we prove a
topological analogue and indicate some applications. 相似文献
3.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
4.
A two-dimensional model for the simulation of a binary dendritic growth with convection has been developed in order to investigate the effects of convection on dendritic morphologies. The model is based on a cellular automaton (CA) technique for the calculation of the evolution of solid/liquid (s/l) interface. The dynamics of the interface controlled by temperature, solute diffusion and Gibbs–Thomson effects, is coupled with the continuum model for energy, solute and momentum transfer with liquid convection. The solid fraction is calculated by a governing equation, instead of some approximate methods such as lever rule method [A. Jacot, M. Rappaz, Acta Mater. 50 (2002) 1909–1926.] or interface velocity method [L. Nastac, Acta Mater. 47 (1999) 4253; L. Beltran-Sanchez, D.M. Stefanescu, Mat. and Mat. Trans. A 26 (2003) 367.]. For the dendritic growth without convection, mesh independency of simulation results is achieved. The simulated steady-state tip velocity are compared with the predicted values of LGK theory [Lipton, M.E. Glicksmanm, W. Kurz, Metall. Trans. 18(A) (1987) 341.] as a function of melt undercooling, which shows good agreement. The growth of dendrite arms in a forced convection has been investigated. It was found that the dendritic growth in the upstream direction was amplified, due to larger solute gradient in the liquid ahead of the s/l interface caused by melt convection. In the isothermal environment, the calculated results under very fine mesh are in good agreement with the Oseen–Ivanstov solution for the concentration-driven growth in a forced flow. 相似文献
5.
In this paper, the possibility of using the gradients of the temperature and of the internal parameters as additional state variables in Continuum Thermodynamics is considered. The expressions of the two principles are discussed and Clausius–Duhem inequality is derived under an appropriate statement of the internal entropy production. Several formulations are proposed and compared to existing results in the literature. To cite this article: P. Ireman, Q.S. Nguyen, C. R. Mecanique 332 (2004). 相似文献
6.
Thiw work is concerned with the formulation of constituent interactions and corresponding balance relations in classical mixture theory as based on a model for the (classical) constituent structure of such a mixture. 相似文献
7.
Average Atom Model in Hot Plasmas 总被引:4,自引:2,他引:2
Average Atom Model in Hot PlasmasAverageAtomModelinHotPlasmas¥YuanJianhui;SunYongsheng;ZhengShaotang(InstituteofAppliedPhysic... 相似文献
8.
It was argued by Schramm and Smirnov that the critical site percolation exploration path on the triangular lattice converges
in distribution to the trace of chordal SLE
6. We provide here a detailed proof, which relies on Smirnov’s theorem that crossing probabilities have a conformally invariant
scaling limit (given by Cardy’s formula). The version of convergence to SLE
6 that we prove suffices for the Smirnov–Werner derivation of certain critical percolation crossing exponents and for our analysis
of the critical percolation full scaling limit as a process of continuum nonsimple loops.
Research of Charles M.Newman was partially supported by the US NSF under grants DMS-01-04278 and DMS-06-06696. 相似文献
9.
We construct random locally compact real trees called Lévy trees that are the genealogical trees associated with continuous-state
branching processes. More precisely, we define a growing family of discrete Galton–Watson trees with i.i.d. exponential branch
lengths that is consistent under Bernoulli percolation on leaves; we define the Lévy tree as the limit of this growing family
with respect to the Gromov–Hausdorff topology on metric spaces. This elementary approach notably includes supercritical trees
and does not make use of the height process introduced by Le Gall and Le Jan to code the genealogy of (sub)critical continuous-state
branching processes. We construct the mass measure of Lévy trees and we give a decomposition along the ancestral subtree of
a Poisson sampling directed by the mass measure.
T. Duquesne is supported by NSF Grants DMS-0203066 and DMS-0405779. M. Winkel is supported by Aon and the Institute of Actuaries,
EPSRC Grant GR/T26368/01, le département de mathématique de l’Université d’Orsay and NSF Grant DMS-0405779. 相似文献
10.
线性方程组通解并行数值方法 总被引:4,自引:0,他引:4
1预备知识 线性方程组消息传递MIMD算法是20世纪90年代至今的活跃课题,但尚无此问题 的通用有效算法发表.用!.}.}表示矩阵列分块划分,记AX=b为[AI司.定理1、2是文 {l]、[s]成果综述和推广. 定理i[‘]设有线性方程组!e}己l,e〔尺”“m,d〔R”“‘,rank(e)=r.当且仅当rank(! 相似文献