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1.
A zinc coordination polymer derived from pyridine-2,6-dicarboxylate (PDC), {[Zn2(PDC)2]}n, was successfully prepared via conventional, sonication and microwave-irradiation methods. The composition and characteristics of the obtained coordination polymers (CPs) were investigated by elemental analysis, TGA/DTA, X-ray diffraction and spectroscopic techniques. The so obtained CPs were heat-treated in the air at 600 °C for 2 h to produce ZnO of nanosized particles (NPs). It is of interest to note that the synthesis approach of the precursor greatly affects both the nanoparticle size and the structure of the resulting ZnO NPs. Moreover, the smallest particle size was associated with the sample derived from the ultrasonically prepared precursor. TEM analysis revealed that all samples have sphere-like morphologies. Structural analysis of the prepared ZnO samples was conducted and compared using Rietveld analysis of their PXRD patterns. Optical band gap calculations based on analysis of the UV–vis spectra of ZnO samples using Tauc's power law were achieved. The highest band gap of 3.63 eV was observed for ZnO sample obtained from the ultrasonically prepared precursor. Furthermore, the photocatalytic activity of ZnO NPs for the removal of Eosin Y color was monitored. The highest removal efficiency was recorded for ZnO originated from the ultrasonically synthesized precursor. Enhancement of removal efficiency that reached 98% was attained in only a period of 8 min. Its recycling test showed that it can be reused without structural changes over four cycling experiments. 相似文献
2.
A 2D HgII coordination polymer containing ligands 1,2,4‐triazole (Htrz) and thiocyanate, [Hg(μ3‐trz)(SCN)]n ( 1 ) has been synthesized and characterized by elemental analysis and IR spectroscopy. The single‐crystal X‐ray data show the coordination number of Hg atoms is four and the ligand trz? acts as a three‐fold donor. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. The composition and formation of the complex in methanol solution were found to be in support of its solid state structure. 相似文献
3.
4.
该文利用算子半群的方法给出了取值于具有左不变度量的完备可分群的齐次Levy过程是复合Poisson过程的弱极限这一结论. 相似文献
5.
Y. Abe 《The European Physical Journal A - Hadrons and Nuclei》2002,13(1-2):143-148
Based on the theory of the compound nucleus reaction, a brief review is given on the special aspects of the reaction dynamics
in the synthesis of the superheavy elements (SHE), where the fusion probability is the most unknown factor. A new viewpoint
of the fusion reaction is proposed that it consists of two processes; the first process up to the contact of two nuclei of
the incident channel and the second one of a dynamical evolution to the spherical compound nucleus from the contact configuration.
The fusion probability is, thus, given as a product of a contact probability and a formation probability. Analytic studies
of the latter probability are discussed in the one-dimensional model, where a simple expression is given to the so-called
extra-push energy in terms of the reduced friction, the curvature parameter of the conditional saddle point and the nuclear
temperature. Preliminary results of numerical analyses of the contact probability are given, using the surface friction model
(SFM). Remarks are given on the present status of our knowledge and for future developments.
Received: 1 May 2001 / Accepted: 4 December 2001 相似文献
6.
Kj?rand Iversen Per Nilsson 《International Journal of Computers for Mathematical Learning》2007,12(2):113-133
This paper focuses on the different ways in which students in lower secondary school (14–16 year olds) experience compound
random events, presented to them in the form of combined junctions. A carefully designed ICT environment was developed enabling
the students to interact with different representations of such structures. Data for the analysis was gathered from two interview
sessions. The analysis of the interaction is based on constructivist principles on learning; i.e. we adopted a student-oriented
perspective, taking into consideration the different ways students try to make sense of chance encounters.
Our results show how some students give priority to geometrical and physical concerns, and we discuss how seeking causal explanations
of random phenomena may have encouraged this. With respect to numerically oriented models a division strategy appears to stand
out as the preferred one. 相似文献
7.
The synthesis of enantiopure bis-THF is described, starting from d-mannitol. Bis-THF is used as chiral ligand for organolithium reagents in four different reactions. The enantioselectivity provided by this ligand is moderate, and the asymmetric induction is in line with the expected model. 相似文献
8.
This article describes the technique of fast atom bombardment mass spectrometry (FAB MS) and its applications to the analysis of organometallic and coordination complexes. Sections on ion generation and matrices are followed by a Periodic Group-based review of FAB MS results obtained from Transition Metal and Main Group compounds, organometallic cluster carbonyls and their derivatives, and salts of poly-oxo-anions. The literature has been surveyed from 1981 to approximately mid-1986. 相似文献
9.
We review the unusual structural, transport and magnetic properties of highly conducting polyaniline, doped with boron trifluoride.
Our studies establish the unique conducting state of this system, which is in distinct contrast with the conventional proton-doped
polyaniline samples. 相似文献
10.
Some Results behind Dividend Problems 总被引:1,自引:0,他引:1
Ming Zhou Li Wei Jun-yi Guo 《应用数学学报(英文版)》2006,22(4):681-686
We consider the basic dividend problem of the compound Poisson model with constant barrierstrategy.Some results concealed behind the dividend problem are made explicit in the present work.Differentmethods and some of which are firstly given in this paper.All these results presented certain direct relationshipbetween some important actuary variables in classical risk theory is also revealed. 相似文献