首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   40010篇
  免费   3465篇
  国内免费   2239篇
化学   22454篇
晶体学   221篇
力学   2149篇
综合类   309篇
数学   8831篇
物理学   11750篇
  2023年   352篇
  2022年   673篇
  2021年   844篇
  2020年   1062篇
  2019年   984篇
  2018年   873篇
  2017年   896篇
  2016年   1152篇
  2015年   1076篇
  2014年   1514篇
  2013年   2786篇
  2012年   1601篇
  2011年   1761篇
  2010年   1562篇
  2009年   2083篇
  2008年   2238篇
  2007年   2394篇
  2006年   2082篇
  2005年   1737篇
  2004年   1561篇
  2003年   1500篇
  2002年   2625篇
  2001年   1220篇
  2000年   1075篇
  1999年   970篇
  1998年   943篇
  1997年   689篇
  1996年   604篇
  1995年   590篇
  1994年   461篇
  1993年   438篇
  1992年   450篇
  1991年   341篇
  1990年   231篇
  1989年   189篇
  1988年   199篇
  1987年   198篇
  1986年   173篇
  1985年   249篇
  1984年   249篇
  1983年   188篇
  1982年   303篇
  1981年   340篇
  1980年   313篇
  1979年   319篇
  1978年   294篇
  1977年   263篇
  1976年   238篇
  1974年   205篇
  1973年   226篇
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
1.
《Mendeleev Communications》2022,32(5):597-600
Calorimetric monitoring of the autoclave reaction N2O4 + C2H4 at –85 to +10 °C under argon pressure 10–30 bar revealed that the exothermic chemical reaction started at temperatures above –52 °C at 10 bar, whereas an intensive exothermic reaction started at –85 °C and pressure of 30 bar. IR study showed that oligo/polynitroethylene was formed at 30 bar, while carbonyl and hydroxy compound as well as nitrate R–ONO2 formation occurred upon processing at 10 bar.  相似文献   
2.
《Mendeleev Communications》2022,32(5):629-631
The Michael–Mannich cascade cyclization of cyano olefins, ethyl 4,4,4-trifluoro-3-oxobutanoate, aromatic aldehydes and ammonium acetate provides convenient stereoselective formation of ethyl 5,5-dicyano-4,6-diaryl-2-hydroxy-2-(trifluoromethyl)piperidine-3-carboxylates with fourstereogenic centers and dialkyl 4,6-diaryl-5-cyano-2-hydroxy-2-(trifluoromethyl)piperidine-3,5-dicarboxylates with five stereogenic centers. Ammonium acetate plays dual role, acting as a base and as a nitrogen source.  相似文献   
3.
《Mendeleev Communications》2022,32(4):534-536
Correlation times and diffusion coefficients of water molecules were measured for the first time by 1H spin relaxation and pulsed field gradient NMR in Li+, Na+ and Cs+ ionic forms of Nafion 117 membrane. Hydration numbers of Li+, Na+ and Cs+ cations were calculated. It was shown that at high humidity macroscopic transfer is controlled by the local translational motion of water molecules.  相似文献   
4.
郑凌玲 《化学教育》2022,43(10):100-106
深挖高职院校公选课“生活中的化学”的育人元素,精心设计教学内容,运用课堂主题辩论、趣味生活实验的设计与展示、探秘生活中的化学等理论知识传授与课内外实践相结合的教学方式,实现全过程育人,充分展现了公选课在立德树人方面的价值。  相似文献   
5.
In this paper we consider minimizers of the functionalmin{λ1(Ω)++λk(Ω)+Λ|Ω|,:ΩD open} where DRd is a bounded open set and where 0<λ1(Ω)λk(Ω) are the first k eigenvalues on Ω of an operator in divergence form with Dirichlet boundary condition and with Hölder continuous coefficients. We prove that the optimal sets Ω have finite perimeter and that their free boundary ΩD is composed of a regular part, which is locally the graph of a C1,α-regular function, and a singular part, which is empty if d<d, discrete if d=d and of Hausdorff dimension at most dd if d>d, for some d{5,6,7}.  相似文献   
6.
7.
The minimum k-enclosing ball problem seeks the ball with smallest radius that contains at least k of m given points. This problem is NP-hard. We present a branch-and-bound algorithm on the tree of the subsets of k points to solve this problem. Our method is able to solve the problem exactly in a short amount of time for small and medium sized datasets.  相似文献   
8.
Far-red emitting fluorescent labels are highly desirable for spectral multiplexing and deep tissue imaging. Here, we describe the generation of frFAST (far-red Fluorescence Activating and absorption Shifting Tag), a 14-kDa monomeric protein that forms a bright far-red fluorescent assembly with (4-hydroxy-3-methoxy-phenyl)allylidene rhodanine (HPAR-3OM). As HPAR-3OM is essentially non-fluorescent in solution and in cells, frFAST can be imaged with high contrast in presence of free HPAR-3OM, which allowed the rapid and efficient imaging of frFAST fusions in live cells, zebrafish embryo/larvae, and chicken embryos. Beyond enabling the genetic encoding of far-red fluorescence, frFAST allowed the design of a far-red chemogenetic reporter of protein–protein interactions, demonstrating its great potential for the design of innovative far-red emitting biosensors.  相似文献   
9.
A new strategy for the synthesis of tetrahydroisoquinolines based on the Pd0‐catalyzed intramolecular α‐arylation of sulfones is reported. The combination of this Pd‐catalyzed reaction with intermolecular Michael and aza‐Michael reactions allows the development of two‐ and three‐step domino processes to synthesize diversely functionalized scaffolds from readily available starting materials.  相似文献   
10.
The synthesis of vinyl alcohol copolymers is limited due to the poor radical reactivity of vinyl acetate (VAc), the traditional precursor to polyvinyl alcohol (PVA). Main group monomers such as BN 2-vinylnaphthalene (BN2VN) have attracted attention as alternatives to VAc to form side chain hydroxyls via oxidation, but outstanding questions of molecular weight control remain. Herein we report systematic investigation of solvent, temperature, and initiator concentration as factors influencing BN2VN degree of polymerization. We find increased chain transfer to toluene, hypothesized to arise from differences in radical stabilization and reactivity by aromatic and BN aromatic rings. As a result of these combined efforts, high molecular weight (Mw ~ 105 g mol−1) BN2VN homopolymers and BN2VN-styrene copolymers were obtained.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号