CPL冷凝单管融化过程的双倒易边界元分析

1引言CPL（毛细泵两相流回路）能传输较高的热负荷，而且不需要循环泵、阀门等运动部件，重量轻可靠性好；在飞行器热控制方面有很好的应用前景[1]。CPL在恶劣的空间环境中运行，需要防止工作介质出现冷冻，为此，我们已经用解析[2]和数值的方法[3]进行了初步的分析，得到了一些可供工程设计参考应用的结果。另外，在恶劣的空间环境中，如果出现冻结，需要融化起动，热管的安全设计需要研究它的融化特性，以确保热管在空间能正常运行。双倒易边界元方法用Laplace基本解[4]，通过对一类偏微分方程两侧进行转化，将它全部转化为纯边界积分…     

万用表检测电容器方法分析及改进

本文从教学实验的实践出发,对使用万用表测量电容器容量的方法进行了分析,并对电路进行了一定改进。     

Circularly Polarized Luminescence of Aluminum Complexes for Chiral Sensing of Amino Acid and Amino Alcohol

Determination of the absolute configuration (AC) of chiral molecules is a key issue in many fields related to chirality such as drug development, the asymmetric reaction screening, and the structure determination of natural compounds. Although various methods, such as X‐ray crystallography and NMR spectroscopy, are used to determine the AC, a simple and cheap alternative method is always anticipated. So far, electronic circular dichroism (ECD) spectroscopy has been widely used to ascertain the AC and enantiomeric excess (ee) values by applying appropriate organic probes. Here, circularly polarized luminescence (CPL) spectroscopy was applied to determine the AC and ee values of a series of amino acid and amino alcohol. The measurements were conducted by mixing the amino acids or amino alcohols with an achiral 1‐hydroxy‐2‐naphthaldehyde. Upon in situ formation of the Schiff base complexes, the system showed emission enhancement and CPL in the presence of Al³⁺, whose intensity and sign can be used to assign the chiral sense of the amino acids and amino alcohols. The authenticity of the method was further compared with the established CD spectroscopy, revealing that CPL spectra of formed Al³⁺ complex were effective to determine the AC of chiral species.     

喷淋蒸发翅管式冷凝器传热传质研究

采用蒸发式冷凝器可以降低制冷装置不可逆传热损失,提高机组效率。该文提出在制冷装置中采用喷淋蒸发翅管式冷凝器,分析了喷淋蒸发翅管式冷凝器的传热过程,建立其传热传质数学模型和设计计算方法,简要分析了环境温湿度、管翅结构、风速、淋水量等一些主要因素对传热传质性能的影响,为该种冷凝器的设计和应用提供理论参考。     

复杂阴极保护体系三维有限元建模研究

滨海电厂常以天然海水作冷却水,其碳钢水室和钛管凝汽器在实施阴极保护过程中,要求钢电位应低于-0.85V(vs.SCE),电位过正则碳钢保护不足,而钛的电位则须高于-0.75V(vs.SCE),电位过负则易使钛管发生氢脆损伤.研究牺牲阳极阴极保护,需先得出两种金属在阴极保护过程中的电位分布.本文在设计室建立碳钢水室钛管模型,根据该实验体系阴极保护过程的(稳态极化和恒电流极化)测定获得两种金属有效的边界条件,用有限元(FEM)计算在一个牺牲阳极阴极保护状态得到三维电位分布.计算结果和测量结果基本一致,为优化阴极保护设计提供了理论依据.     

The Effect of Pea Chloroplast Alignment and Variation of Excitation Wavelength on the Circularly Polarized Chlorophyll Luminescence

Circularly polarized luminescence (CPL) is a powerful technique to study the macroorganization of photosynthetic light-harvesting apparatus in vivo and in vitro. It is particularly useful for monitoring environmental stress induced molecular re-organization of thylakoid membranes in green leaves. The current study focuses on two questions which are important to perform and interpret such experiments: how does CPL depend on the excitation wavelength and how on the orientation of the granal thylakoids. CPL and circular dichroism (CD) of pea chloroplasts were complementarily applied when chloroplasts were either in suspension or trapped in a polyacrylamide gel (PAAG) after alignment in a magnetic field. In contrast to the CD spectrum, the CPL signal was found to be independent of the excitation wavelength in both the Soret and the Qy absorption region for chloroplasts in both suspension and PAAG. The improved resolution of luminescence measurements revealed a relatively small negative CPL band in addition to the previously described large positive band. No effect of photoselection upon excitation on the CPL spectra was detected. The CPL intensity at 690 nm at the edge of the granal thylakoids was found to be higher than at the face of the grana suggesting the CPL anisotropy.     

CPL毛细芯冷凝器的数值模拟研究

本文分析了蒸汽在具有毛细芯结构的冷凝器中的相变冷凝传热与流动特征,采用流体体积函数(VOF:Volume of Fluid)方法建立了数学模型,继而用数值模拟方法,研究了不同的壁面温度以及不同的蒸汽入口速度对冷凝相变界面的影响,文中还对产生影响的原因进行了分析.     

A [Cyclentetrakis(methylene)]tetrakis[2‐hydroxybenzamide] Ligand That Complexes and Sensitizes Lanthanide(III) Ions

The synthesis of the cyclen derivative H₄ L ¹ ?2 HBr containing four 2‐hydroxybenzamide groups is described. The spectroscopic properties of the Ln^III conplexes of L ¹ (Ln=Gd, Tb, Yb, and Eu) reveal changes of the UV/VIS‐absorption, circular‐dichroism‐absorption, luminescence, and circularly polarized luminescence spectra. It is shown that at least two metal‐complex species are present in solution, whose relative amounts are pH dependent. At pH>8.0, an intense long‐lived emission is observed (for [Tb L ¹ ] and [Yb L ¹ ]), while at pH<8.0, a weaker, shorter‐lived species predominates. Unconventional Ln^III emitters (Pr, Nd, Sm, Dy, and Tm) were sensitized in basic solution, both in the VIS and in the near‐IR, to measure the emission of these ions.     

用于太阳能光伏发电的高倍聚光系统

 研究了基于三结型（InGaP/InGaAs/Ge）高效太阳能电池的太阳能光伏发电的高倍聚光系统。该系统采用高次非球面光学玻璃卡塞格林系统,运用Zemax和Tracepro光学设计软件完成200~500倍太阳能聚光系统的设计,同时设计了单片型高倍太阳能聚能光学组件,用热压成型方法研制了太阳能聚能透镜（副镜）。采用16个性能相同的聚光光学组件和相同数量的三结型太阳能电池组成高倍聚光型太阳能光伏组件,极大地提高了聚光比,为太阳能光伏发电的高倍聚光器设计提供参考和依据。     

椭圆管矩形翅片间空气流动的扰流特征

针对椭圆管矩形翅片间的空气流动特性,将应用于直接空冷电站椭圆管矩形翅片的几何中心相对于椭圆管的几何中心偏置.针对不同偏心距离x,以及不同入口风速u,得到空气侧对流换热系数h和压差P随u的变化规律.模拟结果表明翅片的偏置会对着空气侧的流动与换热产生不同影响:翅片向前偏置,低速尾流区对翅片表面换热的影响减小,空气侧总的表面...