Twofold Brook rearrangement-mediated tandem reactions of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with a cyanide ion

Reaction of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with KCN in the presence of chloro or cyanoformates gives highly functionalized dienol silyl ether derivatives via a twofold Brook rearrangement-induced tandem sequence.     

Determination of the average lifetime of bottom hadrons

We have determined the average lifetime of hadrons containing b quarks produced in e⁺e^? annihilation to be

$\text{τ}\text{B}\text{=}\text{1.83}\text{+0.83}\text{+0.37}\text{?}\text{?0.34}\text{×10}{}^{\mathrm{?12}}\text{s}$

. Our method uses charged decay products from both non-leptonic and semileptonic decay modes.     

Elektronenstoss-induzierter zerfall von benzol-tricarbonyl-chrom- und -wolfram-derivaten; ein vergleich

The Electron impact mass spectra of (CO)₃ MC₆H₅—X complexes (M = Cr, W; X = OCH₃, OC₄H₉, CO₂CH₃, CO₂C₄H₉) were recorded. From metastable transitions and by high-resolution measurements complete fragmentation diagrams were obtained; in some cases comparative structure determinations of fragment ions were carried out by collisional activation. The fragmentation of the tungsten complexes considerably differs from that of the chromium compounds. The differences may be attributed to the stronger-electrophilic character as well as to the more pronounced tendency of tungsten to attain higher oxidation states.     

Type II Anion Relay Chemistry: Exploiting Bifunctional Weinreb Amide Linchpins for the One‐Pot Synthesis of Differentiated 1,3‐Diketones,Pyrans, and Spiroketals

The design, synthesis, and validation of new highly effective bifunctional linchpins for type II anion relay chemistry (ARC) has been achieved. The mechanistically novel negative‐charge migration that comprises the Brook rearrangement is now initiated by a stabilized tetrahedral intermediate, which is generated by nucleophilic addition to a Weinreb amide, rather than by a simple oxyanion that is generated from an epoxide. As a result, the linchpin preserves the carbonyl functionality in the ARC adducts, thus permitting access to functionally complex systems in a single flask without the need for further chemical manipulations. This tactic was validated with the one‐pot preparation of monoprotected 1,3‐diketones as well as pyran and spiroketal scaffolds, depending on the choice of nucleophile, electrophile, and work‐up conditions.     

On the Bullwhip Avoidance Phase: The Synchronised Supply Chain

The aim of this paper is to analyse the operational response of a Synchronised Supply Chain (SSC). To do so, first a new mathematical model of a SSC is presented. An exhaustive Latin Square design of experiments is adopted in order to perform a boundary variation analysis of the main three parameters of the periodic review smoothing (S, R) order-up-to policy: i.e., lead time, demand smoothing forecasting factor, and proportional controller of the replenishment rule. The model is then evaluated under a variety of performance measures based on internal process benefits and customer benefits. The main results of the analysis are: (I) SSC responds to violent changes in demand by resolving bullwhip effect and by creating stability in inventories under different parameter settings and (II) in a SSC, long production–distribution lead times could significantly affect customer service level. Both results have important consequences for the design and operation of supply chains.     

The problem of the relation between double pomeron exchange in inclusive and exclusive experiments

The pionization region of the inclusive single-particle spectrum is accounted for by double pomeron exchange in the absorptive part of a six-point amplitude. In this paper a multiperipheral model for the six-point amplitude with double pomeron exchange is used for continuation by crossing and analyticity to the physical region of the exclusive two particle → four particle production process. The cross section for π^? p → π^?(π⁺π^?)p in the double-Regge region is then calculated and compared with the experimental analysis of Lipes, Zweig and Robertson which sets an upper bound to the strength of the double pomeron exchange coupling. This upper bound, coupled with the model for continuation to the inclusive cross section, is shown to give too small a magnitude for the double pomeron exchange in the pionization region. Further avenues for investigation are discussed.     

Off-shell NN annihilation studied in π+p interactions at 8 and 16 GeV/c

Interactions in which the baryon is emitted forwards in the c.m.s. are studied in 8 and 16 GeV/cπ⁺p collisions. These interactions are interpreted as representing baryon exchange. The properties of such off-shell $\text{N}$N annihilation events are studied. It is found that the multiplicity distribution of the multi-pion system as a function of the effective mass for events with |u_pp| < 1 GeV² is the same as for real $\text{N}\text{N}$ annihilations.     

Rapidity density distributions in antiproton-proton collisions

Data on the density of charged particles in rapidity space for annihilation and non-annihilation p?p interactions at 7.3 and 12 GeV/c are reported. It is shown that the central rapidity density for non-annihilation processes is a simple linear function of $\text{ln}\text{(}\text{s}\text{)}$ from these low energies up to p?p collider energies ($\text{s}\text{=540}\text{GeV}$). Significant differences in density distributions for p?p and e^?e⁺ annihilations at comparable energies are found.     

Partial-wave analysis of the low-mass (π+π−p) system produced in K−p interactions at 4.2 GeV/c

A partial-wave analysis of the low-mass (π⁺π^?p) system produced in the reaction K^?p → K^?(π⁺π^?p) at 4.2 GeV/c incident momentum is performed in order to study the two (π⁺π^?p) enhancements around 1500 and 1700 MeV. It is found that the low-mass (π⁺π^?p) system can be described using the spin-parity states $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{+}}\text{,}\text{3}\text{2}{}^{\mathrm{?}}$ and $\text{5}\text{2}{}^{\mathrm{+}}$ only. In the 1500 MeV region contributions are observed from the $\text{1}\text{2}{}^{\mathrm{+}}$ wave decaying into p? and the $\text{3}\text{2}{}^{\mathrm{?}}$ wave decaying into Δ⁺⁺π^?; in the 1700 MeV region contributions are found from the $\text{1}\text{2}{}^{\mathrm{+}}$ wave decaying into Δ⁺⁺π^?, the $\text{3}\text{2}{}^{\mathrm{?}}$ wave decaying into p?, and the $\text{5}\text{2}{}^{\mathrm{+}}$ wave decaying into p?.     

First direct observation of the decay of neutral charmed particles produced by neutrinos in emulsion

Three examples of the production in emulsion by neutrinos and subsequent decay of neutral short-lived particles are reported. The flight times are ≈ 10^?13s, similar in order of magnitude to those previously determined for charged charmed particles in the same experiment.