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1.
2.
熔制了掺铒碲铌玻璃样品(100-X)TeO2-XNb2O5(X=5,10,15,20mol%),测试了其密度、折射率、转变温度、析晶温度、维氏机械强度、吸收光谱、荧光光谱、荧光寿命等参量。利用Judd-Ofelt和McCumber理论分别计算了铒离子强度参量Ωt(t=2,4,6)和受激发射截面σemi的大小,研究了掺铒碲铌玻璃样品光谱参量对Nb2O5成分的依赖性,并与典型的碲锌钠玻璃(75TeO2-20ZnO-5Na2O)在热学、机械强度、光谱性质和放大品行四个方面进行了比较. 相似文献
3.
M.Yu. Tretyakov V.V. Parshin M.A. Koshelev A.P. Shkaev A.F. Krupnov 《Journal of Molecular Spectroscopy》2006,238(1):91-97
Extension of the working frequency of modern resonator spectrometers into submillimeter wave range is described. Experimental record of atmospheric absorption spectrum covering 45-370 GHz range is demonstrated for the first time, and measured water vapor J′ka′, kc′-Jka, kc = 51,5-42,2 at 325 GHz line parameters are presented. For the first time pressure lineshift for the 325-GHz water vapor line is measured. Further extension of working range is discussed. New estimations of physical limits of time needed for measurements of absorption in the whole Backward Wave Oscillator (BWO) range are given for phase continuous synthesizer regime. Basic schemes of fast broadband continuous phase synthesized sources are discussed. Verification of the previous measurements of water vapor 31,3-22,0 at 183 GHz line parameters is presented. Comparisons with ringdown resonator spectrometers are given. 相似文献
4.
This article presents the comparison of approximate and exact small-signal theories for analyzing the influence of the higher-order dispersion terms on dispersive optical communication systems operating near zero dispersion wavelength for linear single-mode fiber. For the approximate theory, the generalized conversion matrix has been reported and gives the transfer function of intensity and phase from the fiber input to fiber output for a laser source including the influence of any higher-order dispersion term. In addition, expressions for the small-signal frequency response and the relative intensity noise (RIN) response of an ultrafast laser diode including noises are derived. However, it is observed that the approximation assumed for the second-order dispersion term for the approximate analysis is not valid. From the approximate theory, the exact generalized conversion matrix and exact expressions for small-signal frequency response and relative intensity noise (RIN) are obtained. We show that for the exact theory, the second-order dispersion term has no effect on intensity and frequency response even at large modulating frequencies and large propagation distances contrary to the approximate theory as reported by other authors. But we show that third-order dispersion term certainly has some minute impact on the frequency and RIN response for long distance links at high modulating frequencies. 相似文献
5.
M. Keane 《Applied Acoustics》2007,68(10):1104-1117
A new method is presented for splitting musical notes into tonal and broadband components by removing the harmonic peaks from the spectra. This method was used to analyse the key vibrations of eight pianos (four grand and four upright). The broadband component of vibrations was found to be more intense in the upright pianos than in the grand pianos, while no such difference was found in the tonal component. As grands are considered to be superior to uprights, this suggests that it may be possible to improve upright pianos by reducing the strength of the broadband component of vibrations. 相似文献
6.
G.A. Groß 《Thermochimica Acta》2005,432(2):229-240
A silicon chip device with two types of integrated platinum thin film resistors was applied for microcaloric measurements. It was shown that the device is capable of fast characterization of liquid evaporation behaviour and allows the determination of evaporation enthalpies for pure liquids and mixtures. The applicability was demonstrated for a wide range of solvents from nonpolar aliphatic solvents over polar organics to protic solvents (e.g. iso-octane, toluene, acetone, ethanol, methanol and water). The sample volumes were in the range of about 2-5 μL. The determination of transient times, in case of constant power mode, or the power integral over time was used for the fast estimation of binary liquid mixtures. Thermo-resistive measurements of 5 μL droplets of solvent mixtures like methanol/iso-propanol, ethanol/water, iso-octane/iso-propanol and iso-octane/1,4-dioxane showed significant changes in temperature characteristics and evaporation enthalpies in dependence on composition. The applied heating power was about 1 W, which corresponds to measurement times between a few seconds and a minute. 相似文献
7.
DETERMINATION OF QUADRICEPS FORCES IN SQUAT AND ITS APPLICATION IN CONTACT PRESSURE ANALYSIS OF KNEE JOINT 总被引:1,自引:0,他引:1
While the quadriceps muscles of human body are quite important to the daily activities of knee joints,the determination of quadriceps forces poses significant challenges since it cannot be measured in ... 相似文献
8.
This work describes the dielectric properties of piezoelectric poly(vinylidene fluoride) (PVDF) thin films in the frequency and temperature ranges relevant for usual applications. We measured the isothermal dielectric relaxation spectra of commercial piezoelectric PVDF thin films between 10 Hz to 10 MHz, at several temperatures from 278 K to 308 K. Measurements were made for samples in mechanically free and clamped conditions, in the direction of the poling field (perpendicular to the film). We found that the imaginary part of the dielectric relaxation spectra of free and clamped PVDF samples is dominated by a peak, above 100 kHz, that can be characterized by a Havriliak-Negami function. The characteristic time follows an Arrhenius dependence on temperature. Moreover, the spectra of the free PVDF samples show two additional peaks at low frequencies which are associated with mechanical relaxation processes. Our results are important for the characterization of piezoelectric PVDF, particularly after the stretching and poling processes in thin films, and for the design and characterization of a broad range of ultrasonic transducers. 相似文献
9.
Kwenga Sichilongo 《International journal of environmental analytical chemistry》2013,93(13):973-984
Signal losses due to precursor ion isolation in a quadrupole-ion-trap mass spectrometer were studied using selected pesticides as model compounds. These signal losses originate from isolations of ion populations employing the broadband isolation (bbiso) waveform used in the Varian quadrupole ion-trap precursor ion isolation protocol. Signal losses were found to be ‘precursor ion structure’ dependent upon isolation using the bbiso. The effect of the bbiso waveform on the ionic structure and nature of substituents on the precursor ion was investigated. Isolation of old electron radical molecular ions of the type [M+?] showed remarkable signal losses compared with isolation of fragment ions derived from the same compounds. The impact of the bbiso waveform on the response of the instrument using mass spectrometry/mass spectrometry and the bbiso waveform was also examined. The response of the instrument as related to the calculated Instrument Detection Limits was observed to parallel ion population losses. 相似文献
10.
Emmanuel Urandu Mapesa Ludwig Popp Wycliffe Kiprop Kipnusu Martin Tress Friedrich Kremer 《Soft Materials》2014,12(4):S22-S30
Broadband Dielectric Spectroscopy (BDS) is used to probe the molecular dynamics of Type A polymer, poly(cis-1,4-isoprene), when confined in the 1-dimensional (1D) exploring space of thin layers and the 2-dimensional (2D) constraining geometry of unidirectional anodic aluminum oxide (AAO) nanopores. For both cases, it was observed that the structural relaxation remains bulk-like in its mean relaxation rate, although the distribution of its relaxation times is broadened in 2D confinement. Furthermore, the fluctuation of the end-to-end vector is interrupted, with the 1D case being relatively less pronounced. By this clear-cut comparison, it is demonstrated that the effects of confinement on molecular dynamics depend, inter alia, on the dimensionality of the restricting space. 相似文献