全文获取类型
收费全文 | 112篇 |
免费 | 25篇 |
国内免费 | 8篇 |
专业分类
化学 | 68篇 |
综合类 | 2篇 |
数学 | 9篇 |
物理学 | 66篇 |
出版年
2023年 | 3篇 |
2022年 | 10篇 |
2021年 | 8篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 12篇 |
2013年 | 10篇 |
2012年 | 6篇 |
2011年 | 7篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 1篇 |
2006年 | 5篇 |
2004年 | 2篇 |
2003年 | 7篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1989年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有145条查询结果,搜索用时 31 毫秒
1.
电磁继电器触点参数的测试 总被引:1,自引:0,他引:1
本文介绍了电磁继电器触点电参数的测试方法,包括接触电阻、绝缘电阻参数测试。 相似文献
2.
Density functional theory calculations were carried out for the title reactions. Ethylene oxide and methylamine were adopted as reactants. Amine clusters (dimer, trimer, tetramer, and pentamer) were considered, because the combination of one oxide and one amine molecule gave a large activation energy. An amine tetramer was found to react favorably with the oxide via various zwitterionic intermediates. A back-side S(N)2 nucleophilic attack of one amine and the subsequent proton relay up to the front side provide a stabilized reaction field. The amine-alcohol mixed reactant may react readily with the oxide, because the alcoholic O-H group is in contact with the oxide oxygen with the strong hydrogen-bond stabilization. 相似文献
3.
Dr. Qianjia Yuan Prof. Matthew S. Sigman 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(46):10823-10827
In this report, a palladium-catalyzed redox-relay Heck process to access optically active alkenylated α,β-unsaturated lactams is described. Under mild reaction conditions, electron-deficient alkenyl triflates and electron-rich alkenyl iodonium salts undergo enantioselective and site-selective coupling with enelactams to deliver the products in high yields and excellent enantioselectivities. Furthermore, the products allow facile access to natural products such as (+)-calvine and (+)-2-epicalvine in addition to the bioactive molecule aza-goniothalamin. 相似文献
4.
Ben Ali K Lafon O Zimmermann H Guittet E Lesot P 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,187(2):205-215
We describe several homo- and heteronuclear 2D NMR strategies dedicated to the analysis of anisotropic (2)H spectra of a mixture of dideuterated unlike/like stereoisomers with two remote stereogenic centers, using weakly orienting chiral liquid crystals. To this end, we propose various 2D correlation experiments, denoted "D(H)(n)D" or "D(H)(n)C" (with n=1, 2), that involve two heteronuclear polarization transfers of INEPT-type with one or two proton relays. The analytical expressions of correlation signals for four pulse sequences reported here were calculated using the product-operators formalism for spin I=1 and S=1/2. The features and advantages of each scheme are presented and discussed. The efficiency of these 2D sequences is illustrated using various deuterated model molecules, dissolved in organic solutions of polypeptides made of poly-gamma-benzyl-L-glutamate (PBLG) or poly-epsilon-carbobenzyloxy-L-lysine (PCBLL) and NMR numerical simulations. 相似文献
5.
Holly E. Bonfield Dr. Damien Valette Dr. David M. Lindsay Dr. Marc Reid 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(1):158-174
Exploration of novel, three-dimensional chemical space is of growing interest in the drug discovery community and with this comes the challenge for synthetic chemists to devise new stereoselective methods to introduce chirality in a rapid and efficient manner. This Minireview provides a timely summary of the development of palladium-catalyzed asymmetric redox-relay Heck-type processes. These reactions represent an important class of transformation for the selective introduction of remote stereocenters, and have risen to prominence over the past decade. Within this Minireview, the vast scope of these transformations will be showcased, alongside applications to pharmaceutically relevant chiral building blocks and drug substances. To complement this overview, a mechanistic summary and discussion of the current limitations of the transformation are presented, followed by an outlook on future areas of investigation. 相似文献
6.
Dr. Uttam Dutta Sandip Porey Sandeep Pimparkar Astam Mandal Jagrit Grover Adithyaraj Koodan Dr. Debabrata Maiti 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21017-21022
Biaryl compounds are extremely important structural motifs in natural products, biologically active components and pharmaceuticals. Selective synthesis of biaryls by distinguishing the subtle reactivity difference of distal arene C−H bonds are significantly challenging. Herein, we describe para-selective C−H arylation, which is acheived by a unique combination of a meta-directing group and norbornene as a transient mediator. Upon direct meta-C−H palladation, one-bond relay palladation occurs in presence of norbornene and subsequently para-C−H arylation is achieved for sulfonates, phosphonates and phenols bearing 2,6-disubstitution patterns. The protocol is amenable to electron-deficient aryl iodides. Multisubstituted arenes and phenols are obtained by postsynthetic modification of the products. The protocol allows the synthesis of hexa-substituted benzene by sequential selective distal C−H functionalization. 相似文献
7.
Liejin Zhou Xingxing Wu Xing Yang Chengli Mou Runjiang Song Shuyan Yu Huifang Chai Lutai Pan Zhichao Jin Yonggui Robin Chi 《Angewandte Chemie (International ed. in English)》2020,59(4):1557-1561
The combined use of gold as transition metal catalyst and N‐heterocyclic carbene (NHC) as organic catalyst in the same solution for relay catalytic reactions was disclosed. The ynamide substrate was activated by gold catalyst to form unsaturated ketimine intermediate that subsequently reacted with the enals (via azolium enolate intermediate generated with NHC) effectively to form bicyclic lactam products with excellent diastereo‐ and enantio‐selectivities. The gold and NHC coordination and dissociation can be dynamic and tunable events, and thus allow the co‐existence of both active metal and carbene organic catalysts in appreciable concentrations, for the dual catalytic reaction to proceed. 相似文献
8.
本文介绍了一种测试继电器在动态过程中动态参数测试的方法。采用此方法能直接测量和观察继电器动态过程中的线圈电压、电流 ,同时可测出继电器的动作时间 ,还可了解其接点在接触过程是否有振动现象存在。所以 ,此方法是一种多用途的继电器动态参数测量方法 相似文献
9.
The deployment of Small Cells in fourth generation (4G) communication systems is aimed at providing significant capacity improvements and higher availabilities. However, the design of Small Cell systems in indoor environments is especially challenging due to high shadowing attenuation induced by clutter and human blockage. This paper studies node cooperation and multiple relaying and proposes novel analytical formulas for the outage probability of cooperative Small Cells suffering from shadowing. The channel fading gains are modeled as correlated lognormal random variables, in order to reflect the properties of indoor propagation environments. Various cooperative strategies are considered, taking into account the use of one or two relays and different receiver combining techniques. In addition, the relative performance of each cooperative configuration and the benefit of cooperation over non-cooperation are investigated. Finally, interesting and useful insights are produced regarding the impact of the correlated lognormal environment parameters on the configuration of cooperative Small Cells. 相似文献
10.