全文获取类型
收费全文 | 743篇 |
免费 | 32篇 |
国内免费 | 52篇 |
专业分类
化学 | 268篇 |
晶体学 | 3篇 |
力学 | 35篇 |
数学 | 221篇 |
物理学 | 300篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 10篇 |
2020年 | 9篇 |
2019年 | 14篇 |
2018年 | 13篇 |
2017年 | 30篇 |
2016年 | 31篇 |
2015年 | 19篇 |
2014年 | 52篇 |
2013年 | 49篇 |
2012年 | 35篇 |
2011年 | 49篇 |
2010年 | 37篇 |
2009年 | 47篇 |
2008年 | 64篇 |
2007年 | 54篇 |
2006年 | 44篇 |
2005年 | 41篇 |
2004年 | 35篇 |
2003年 | 19篇 |
2002年 | 16篇 |
2001年 | 21篇 |
2000年 | 17篇 |
1999年 | 15篇 |
1998年 | 14篇 |
1997年 | 16篇 |
1996年 | 11篇 |
1995年 | 5篇 |
1994年 | 10篇 |
1993年 | 8篇 |
1992年 | 6篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 4篇 |
1974年 | 1篇 |
排序方式: 共有827条查询结果,搜索用时 7 毫秒
1.
An optical measurement of vortex shape at a free surface 总被引:1,自引:0,他引:1
We have proposed an optical method of vortex shape measurement based on Fourier transform profilometry (FTP) and verified it by experiment. The results of our experiment proposed in this paper show that FTP can efficiently reconstruct the vortex shape at a free surface and this method is suitable for wide use in studying such problems as liquid shear flow, wake of an object, flow behind a bluff body, and wetting angle. 相似文献
2.
Zhao Xuelei 《数学年刊B辑(英文版)》1997,18(1):47-54
GIRSANOV’STHEOREMONABSTRACTWIENERSPACESZHANGYINNANAbstractLet(E,H,μ)beanabstractWienerspaceinthesenseofL.Gros.Itisprovedth... 相似文献
3.
两步相移实现投影栅相位测量轮廓术 总被引:9,自引:2,他引:7
提出一种新的投影栅相位测量方法--两步相移法。该方法只需两幅相移条纹图,因此计算量小,速度快。给出了实验及计算结果,并同四步相移法进行了比较,证明了该方法具有较高的精度。 相似文献
4.
The object of the paper is to study the absolute matrix summability problem of Fourier series, conjugate series and some associated
series under a new set of conditions on matrix methods, generalising many known results in the literature. 相似文献
5.
B.E. Rhoades 《Journal of Mathematical Analysis and Applications》2003,277(1):375-378
We modify some of the conditions of the theorem to make it more applicable. 相似文献
6.
Jung-Hoon Oh Mun-Chual Rho Hyeong Kyu Lee Jae Nyoung Kim Sang-Hun Jung 《Tetrahedron letters》2004,45(38):7077-7079
Asymmetric synthesis of four possible stereoisomers of (9,10)-epoxyheptadecan-4,6-diyn-3-one was accomplished, and the absolute configuration of the naturally occurring (9R,10S)-epoxyheptadecan-4,6-diyn-3-one (1) was elucidated. 相似文献
7.
Starting from shikimic acid, the total synthesis of zeylenone was studied. The product was proved to be the (+)antipode of zeylenone through analysis and comparison of their respective spectra (including NMR, MS, IR and CD) and optical data. The absolute configuration of the natural product was thus determined to be (1S,2S,3R). 相似文献
8.
Arata Yajima 《Tetrahedron》2005,61(38):9164-9172
A versatile methodology for the synthesis of various terpenoids via B-alkyl Suzuki-Miyaura coupling as a key step is established. Synthesis of cordiaquinone J and K, new antifungal and larvicidal meroterpenoids, was achieved by using this methodology. The absolute configurations of cordiaquinone J and K were confirmed by the synthesis. 相似文献
9.
When a benzene ring bears two 2-methyl-1-naphthyl moieties in the para, meta or ortho positions as in 1,4-bis(2-methyl-1-naphthyl)benzene, 1, 1,3-bis(2-methyl-1-naphthyl)benzene, 2 and 1,2-bis(2-methyl-1-naphthyl)benzene 3, two rotational isomers (atropisomers) are generated, with the two naphthyl substituents in a syn or anti relationship. In the case of the para and meta derivatives (1 and 2, respectively) these atropisomers could not be separated but were detected by NMR spectroscopy, that also allowed the determination of their syn-anti interconversion barriers in solution (19.5 and 20.4 kcal mol−1, respectively) and, in the case of 2, also in the solid state (26.7 kcal mol−1). In the more hindered ortho derivative 3, the syn (meso) and anti (racemic) atropisomers interconvert in solution with a barrier (31.2 kcal mol−1) sufficiently high to allow their physical separation. The racemic form could also be separated (by enantioselective HPLC) into the PP and MM enantiomers. Analysis of the corresponding CD spectra allowed the assignment of the absolute configuration. When three such naphthyl substituents are bonded to the phenyl in a meta relationship, two atropisomers in statistical proportions were observed: the anti (Cs symmetry) and the syn (C3v symmetry) display a 3:1 ratio at the equilibrium in solution. This ratio is different in the solid state, as is the interconversion barrier (22.1 and 32.1 kcal mol−1 in solution and in the solid, respectively). 相似文献
10.