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1.
The Raman spectroscopic studies of two rare earth trihydrides: Y H3, HoH3, have been performed in the pressure range from ambient up to 16 GPa and 25 GPa respectively. For the first time samples of REH3 in the form of powder have been studied by Raman spectroscopy using the Diamond Anvil Cell (DAC) technique. A rapid decrease of Raman activity has been observed for the hydrides under pressure values in the vicinity of structural phase transition. Metallization as a possible reason for the observed dramatic change of the REH3 Raman activity has been discussed. 相似文献
2.
B. Dubrulle F.-M. Bréon F. Graner A. Pocheau 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,4(1):89-94
We consider fields which take random values over several decades. Starting from physical examples, we postulate that scale is not an absolute quantity. We then establish the equivalence between two existing approaches based on scale symmetry arguments as general as possible.
This yields a classification of log-infinitely divisible laws, possibly universal. The physical significance of the parameters
entering in the classification is discussed.
Received: 7 November 1997 / Received in final form: 26 March 1998 / Accepted: 30 March 1998 相似文献
3.
Granular flows in a rotating drum: the scaling law
between velocity and thickness of the flow 总被引:1,自引:0,他引:1
The flow of dry granular material in a half-filled rotating drum is studied. The thickness of the flowing zone is measured
for several rotation speeds, drum
sizes and beads sizes (size ratio between drum and beads ranging from 47
to 7400). Varying the rotation speed, a scaling law linking
mean velocity vs. thickness of the flow, v∼hm, is deduced for each couple
(beads, drum). The
obtained exponent m is not always equal to 1, the value previously reported for a drum in litterature, but varies with the
geometry of the system.
For small size ratios, exponents higher
than 1 are obtained due to a saturation of the flowing zone thickness.
The exponent of the power law decreases with the size ratio, leading
to exponents lower than 1 for high size ratios. These exponents imply that
the velocity gradient of a dry granular flow in a rotating drum
is not constant. More fundamentally, these results show that the flow of a
granular material in a rotating drum is very sensible to the geometry, and that
the deduction of the “rheology” of a granular medium flowing in such a
geometry is not obvious. 相似文献
4.
The depolarisation ratio for the Raman-active phenyl stretching mode has been measured over the whole of the mesophase range,
and the orientational order parameters deduced, in the uniaxial nematic liquid crystal octylcyanobiphenyl (8CB). Linearly
polarised light was incident normally on a homogeneously aligned sample and a χ2 minimisation routine performed on the 360° depolarisation ratio profile. The order parameters 〈P
200〉 and 〈P
400〉 , together with the differential polarisability ratio, r , are used as fitting parameters and measured as a function of temperature. Interestingly, we show that the value for r , conventionally measured in the isotropic phase and assumed to remain constant, has a clear temperature dependence, ranging
from -0.032±0.008 in the isotropic phase through to -0.245±0.015 at the nematic-to-smectic A phase transition. The measured
order parameters 〈P
200〉 and 〈P
400〉 varied from 0.35- 0.55±0.02 and 0.180- 0.245±0.02 , respectively, across the 8 ° C wide nematic phase range. The values of both 〈P
200〉 and 〈P
400〉 are in excellent agreement with theory, but it is noteworthy that 〈P
400〉 shows a much better quantitative match than has been reported in previous work. Crucially the temperature dependence of
r is shown to be a contributing factor in the low 〈P
400〉 values that have been conventionally reported from Raman scattering measurements. The potential for fitting the entire angular
depolarisation ratio distribution in liquid crystalline systems that are described by more order parameters, specifically
biaxial materials, is discussed. 相似文献
5.
The moving behaviour of two- and three-particles in a pressure-driven flow is studied by the lattice Boltzmann simulation in two dimensions. The time-dependent values, including particles' radial positions, translational velocities, angular velocities, and the x-directional distance between the particles are analysed extensively. The effect of flow Reynolds number on particle motion is also investigated numerically. The simulation results show that the leading particle equilibrium position is closer to the channel centre while the trailing particle equilibrium position is closer to the channel wall. If Reynolds number Re is less than 85.30, the larger flow Reynolds number results in the smaller x-directional equilibrium distance, otherwise the x-directional distance increases almost linearly with the increase of time and the particles separate finally. The simulation results are helpful to understand the particle-particle interaction in suspensions with swarms of particles. 相似文献
6.
The modeling of the elastic properties of disordered or nanoscale solids requires the foundations of the theory of elasticity
to be revisited, as one explores scales at which this theory may no longer hold. The only cases for which microscopically
based derivations of elasticity are documented are (nearly) uniformly strained lattices. A microscopic approach to elasticity
is proposed. As a first step, microscopically exact expressions for the displacement, strain and stress fields are derived.
Conditions under which linear elastic constitutive relations hold are studied theoretically and numerically. It turns out
that standard continuum elasticity is not self-evident, and applies only above certain spatial scales, which depend on details
of the considered system and boundary conditions. Possible relevance to granular materials is briefly discussed.
Received 18 March 2002 and Received in final form 29 May 2002 相似文献
7.
K. Broderix M. Weigt A. Zippelius 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,29(3):441-455
We consider the gelation of particles which are permanently connected by random crosslinks, drawn from an ensemble of finite-dimensional
continuum percolation. To average over the randomness, we apply the replica trick, and interpret the replicated and crosslink-averaged
model as an effective molecular fluid. A Mayer-cluster expansion for moments of the local static density fluctuations is set
up. The simplest non-trivial contribution to this series leads back to mean-field theory. The central quantity of mean-field
theory is the distribution of localization lengths, which we compute for all connectivities. The highly crosslinked gel is
characterized by a one-to-one correspondence of connectivity and localization length. Taking into account higher contributions
in the Mayer-cluster expansion, systematic corrections to mean-field can be included. The sol-gel transition shifts to a higher
number of crosslinks per particle, as more compact structures are favored. The critical behavior of the model remains unchanged
as long as finite truncations of the cluster expansion are considered. To complete the picture, we also discuss various geometrical
properties of the crosslink network, e.g. connectivity correlations, and relate the studied crosslink ensemble to a wider class of ensembles, including the Deam-Edwards
distribution.
Received on 24 April 2002 Published online 14 October 2002
RID="a"
ID="a"deceased
RID="b"
ID="b"e-mail: weigt@theorie.physik.uni-goettingen.de 相似文献
8.
Li J Tammer M Kremer F Komp A Finkelmann H 《The European physical journal. E, Soft matter》2005,17(4):423-428
Polarized Fourier transform infrared (FTIR) spectroscopy is employed to study the segmental orientation and mobility of liquid-crystalline elastomers (LCEs) with a monodomain structure in response to external mechanical fields parallel and perpendicular to the initial nematic director. The mean orientation and the molecular order parameter of the different molecular moieties referring to the mesogen, the spacer and the network are analyzed in detail. Parallel stretch leaves the mean orientation of the different molecular moieties and its molecular order parameter nearly uninfluenced. Perpendicular stretch results in a threshold-like dependence: for elongation ratios λ ⩽ λc = 1.3 (10 mol% crosslinker density), respectively λ ⩽ λc = 1.6 (5 mol% crosslinker density) no change of the mean orientation and the molecular order parameters is observed, while for λ ≥ λc all molecular units reorient and their molecular order parameters are strongly decreased. The present studies give no indications that the reorientational dynamics of the network and the mesogens differ as long as the elongation ratio is smaller than λc. 相似文献
9.
Long-duration experiments with clouds of microparticles are planned for the ICAPS facility on board the International Space Station ISS. The scientific objectives of such experiments are widespread and are ranging from the simulation of aerosol behaviour in Earths atmosphere to the formation of planets in the early solar system. It is, however, even under microgravity conditions, impossible to sustain a cloud of free-floating, microscopic particles for an extended period of time, due to thermal diffusion and due to unavoidable external accelerations. Therefore, a trap for dust clouds is required which prevents the diffusion of the particles, which provides a source of relative velocities between the dust grains and which can also concentrate the dust to higher number densities that are otherwise not achievable. We are planning to use the photophoretic effect for such a particle trap. First short-duration microgravity experiments on the photophoretic motion of microscopic particles show that such an optical particle-cloud trap is feasible. First tests of a two-dimensional trap were performed in the Bremen drop tower. 相似文献
10.
Interference patterns generated by a regular lattice of SiO2 microspheres on a transparent support are used for the surface patterning of polyimide (PI) foils. Using 248 nm excimer-laser
radiation, thousands to millions of holes with a full width at half maximum (FWHM) of 160±40 nm can be generated with a single
laser pulse.
Received: 1 March 2002 / Accepted: 4 March 2002 / Published online: 10 September 2002
RID="*"
ID="*"Corresponding author. Fax: +43-732/2468-9242, E-mail: dieter.baeuerle@jku.at 相似文献