L-fuzzy Q-convergence structures

In this paper, we construct a topological category of pretopological L-fuzzy Q-convergence spaces, which contains the category of topological L-fuzzy Q-convergence spaces as a bireflective full subcategory. Considering the connections with L-fuzzy topology, it is proved that the category of topological L-fuzzy Q-convergence spaces is isomorphic to the category of topological L-fuzzy quasi-coincident neighborhood spaces, and the latter is isomorphic to the category of L-fuzzy topological spaces. Moreover, we find that our pretopological L-fuzzy Q-convergence spaces can be characterized as a kind of L-fuzzy quasi-coincident neighborhood spaces, which is called strong L-fuzzy quasi-coincident neighborhood space.     

Cascaded z-filters for efficient single-scan suppression of zero-quantum coherence

A simple and robust method to suppress zero-quantum coherence (ZQC) in NMR experiments, in a single scan and with very high suppression ratio, is described. It is an appreciable improvement on a previous technique by Thrippleton and Keeler [Angew. Chem. Int. Ed. 42 (2003) 3938]. The method, called a z-filter cascade, preserves longitudinal, or z-magnetization, with high efficiency. Losses depend mostly on T1 relaxation but not T2 relaxation mechanisms. At the same time, suppression of ZQC can be essentially complete in a single scan. The time duration of the z-filter cascade scales inversely to representative chemical shift differences between the coupled spins, and is typically a few tens of milliseconds. The high efficiency of the zero-quantum suppression and excellent retention of the desired z-magnetization, in a single scan without resort to phase cycling or difference spectroscopy, makes the z-filter cascade a useful new pulse sequence building block for a whole range of NMR experiments. In cases where unwanted residual ZQC may have previously contributed to baseline " t1-noise" in two-dimensional NMR spectra, the z-filter cascade can deliver a noteworthy improvement in spectral quality.     

Fractional Order Disturbance Observer for Robust Vibration Suppression

For the first time, the fractional order disturbance observer (FO-DOB) is proposed for vibration suppression applications such as hard disk drive servo control. It has been discovered in a recently published US patent application (US20010036026) that there is a tradeoff between phase margin loss and strength of the low frequency vibration suppression. Given the required cutoff frequency of the low pass filter, also known as the Q-filter, it turns out that the relative degree of the Q-filter is the major tuning knob for this tradeoff. The solution in US20010036026 was based on an integer order Q-filter with a variable relative degree. This actually motivated the use of a fractional order Q-filter. The fractional order disturbance observer is based on the fractional order Q-filter. The implementation issue is also discussed. The nice point of this paper is that the traditional DOB is extended to the fractional order DOB with the advantage that the FO-DOB design is now no longer conservative nor aggressive, i.e., given the cutoff frequency and the desired phase margin, we can uniquely determine the fractional order of the low pass filter.     

Filters and semigroup compactification properties

Stone-Čech compactifications derived from a discrete semigroup S can be considered as the spectrum of the algebra ℬ(S) or as a collection of ultrafilters on S. What is certain and indisputable is the fact that filters play an important role in the study of Stone-Čech compactifications derived from a discrete semigroup. It seems that filters can play a role in the study of general semigroup compactifications too. In the present paper, first we review the characterizations of semigroup compactifications in terms of filters and then extend some of the results in Papazyan (Semigroup Forum 41:329–338, 1990) concerning the Stone-Čech compactification to a semigroup compactification associated with a Hausdorff semitopological semigroup.     

Determination of NMR cogwheel phase cycle with XML

The selection of correct coherence transfer pathways is an essential component of an NMR pulse sequence. This article describes a new method based on the use of web tools (eXtensible Markup Language and eXtensible Stylesheet Language Transformation) to generate a cogwheel phase cycle for selecting coherence transfer pathways. We illustrate this method with the three-pulse phase-modulated shifted-echo or split-t₁ MQMAS sequences for triple-quantum spin-3/2 systems. After generalization to the different half-integer quadrupole spins, we use the SIMPSON program to confirm our results. Finally, we apply our method to the case of the z-filter 3QMAS sequence for I=3/2 systems.     

L-拓扑空间中的几乎超紧L-子集

在L-拓扑空间中定义了L-子集的几乎超紧性,讨论了几乎超紧L-子集的性质以及L-子集的几乎超紧性与超紧性、近似超紧性及几乎良紧性之间的关系,给出了几乎超紧L-子集的网式及滤子刻画并证明了L-拓扑空间的几乎超紧性是几乎紧性的“L-推广”.     

e-filters of MS-algebras

The notion of e-filters is introduced in an MS-algebra and characterized. The concept of D-filters is introduced and a set of equivalent conditions under which every D-filter is an e-filter are given. The properties of the space of all prime e-filters of an MS-algebra are observed. The concept of D-prime filters is introduced and then a set of equivalent conditions are derived for a prime e-filter to become a D-prime filter in topological terms.     

More line narrowing in TROSY by decoupling of long-range couplings: shift correlation and JNC′ coupling constant measurements

Since the introduction of RDCs in high-resolution NMR studies of macromolecules, there is a growing interest in the development of accurate, and sensitive methods for determining coupling constants. Most methods for extracting these couplings are based on the measurement of the splitting between multiplet components in J-coupled spectra. However, these methods are often unreliable since undesired multiple-bond couplings can considerably broaden the multiplet components and consequently make accurate determination of their position difficult. To demonstrate one approach to this problem, G-BIRD^(r) decoupled TROSY sequences are proposed for the measurement of ¹J_NH and ¹J_NC′ coupling constants. Resolved or unresolved splittings due to remote protons are removed by a G-BIRD^(r) module employed during t₁ and as a result, spectra with narrow, well-resolved peaks are obtained from which heteronuclear one-bond couplings can be accurately measured. Moreover, introduction of a spin-state-selective α/β-filter in the TROSY sequence allows the separation of the ¹J_NC′ doublet components into two subspectra which contain the same number of peaks as the regular TROSY spectrum. The ¹J_NC′ couplings are obtained from the displacement between the corresponding peaks in the subspectra.     

Computational aspects of continuous–discrete extended Kalman-filtering

This paper elaborates how the time update of the continuous–discrete extended Kalman-filter (EKF) can be computed in the most efficient way. The specific structure of the EKF-moment differential equations leads to a hybrid integration algorithm, featuring a new Taylor–Heun-approximation of the nonlinear vector field and a modified Gauss–Legendre-scheme, generating positive semidefinite solutions for the state error covariance. Furthermore, the order of consistency and stability behavior of the outlined procedure is investigated. The results are incorporated into an algorithm with adaptive controlled step size, assuring a fixed numerical precision with minimal computational effort.