卵圆绒泡菌rDNA小亚基片段的克隆测序

粘菌(Myxomycetes)是真核生物中比较特殊的一个类群.但是有关其分子系统学却研究得较少,目前大多数研究仅集中在多头绒泡菌(Physarum polycephalum)等少数几个种上.本文选取卵圆绒泡菌(Physarum didermoides(Pers.)T.Macbr.)为实验材料,用引物SMNUR101和SMNUR108对其rDNA小亚基进行PCR扩增,PCR产物经Wizard(r)PCR扩增DNA纯化系统纯化后,克隆到大肠杆菌JM109中进行测序,测得的序列长度为1910bp(见图1).该序列的测得添补了我国绒泡菌分子生物学研究的空白,也为进一步研究粘菌的起源和演化提供了重要的分子生物学证据.     

一种有机电致发光共聚物的制备和性能

采用Suzuki方法合成了9，9-二辛基芴与萘并硒二唑的两种无规共聚物并研究了其紫外光谱、光致发光和电致发光性能。两种聚合物的电致发光波长为650～666nm，均为发饱和红光的LED材料，其电致发光外量子效率最高达到了1．05％。随着共聚物中萘并硒二唑含量的增加，共聚物的光致发光和电致发光的发射波长均有少量红移。证明了根据共轭高聚物链内能量转移原理，在聚芴链中引入不同含量的窄带隙杂环单元可实现对聚芴发光颜色的调节。     

调节层状分子基磁体[NO2BzQ1][FeRuxFe（1-x）（ox）3]的合成与磁性研究

合成了组成不同的一类新的层状分子基磁体[NO2BzQ1][FeRuxFe(1-x)(ox)3]，并测定了它们的变温磁化率，结果显示，磁体磁性随着Ru^Ⅲ／Fe^Ⅲ比例的不同而发生变化。     

Microwave Synthesis, Characterization and DNA-binding Properties of a New Cobalt（ Ⅱ ） Complex with 2,6-Bis（benzimidazol-2-yl）pyridine

A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra.     

Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes

Optically active aziridino alcohols containing ferrocenyl groups were prepared from commercially available L-threonine in excellent yields and used as catalysts to promote the asymmetric addition of diethylzinc to aryaldehydes to afford 1-arylpropanol in up to 84% enantiomeric excesses with moderate to good yields.     

Nickel Chloride Promoted Glaser Coupling Reaction in Hot Water

A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields.     

Crystal Structures of Two Potential Tumor Imaging Agents and Therapeutic Agents Copper（Ⅱ） Ternary Complexes with Salicylidene-tyrosinato Schiff Base and Nitrogen-donor Chelating Lewis Base

The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents.     

多小波子空间上的单小波表示

本文在较弱的条件下,建立了2重多小波子空间与单小波子空间的关系.即由2重多小波构造出单小波.一方面,这种单小波的平移伸缩与2重多小波的平移伸缩生成的子空间是完全相同的;另一方面,它具有插值性.因此通过构造出的单小波建立了多小波子空间上的Shannon型采样定理.