对位酚类衍生物作为化学发光分析的增强剂研究

在化学发光分析中，常常要用到碱性条件下鲁米诺与过氧化氢的反应系统，通过催化剂辣根过氧化物酶使反应顺利进行。如果再加入适当的增强剂，则灵敏度提高且发光时间延长，可改善测定的重现性。实验证明，对位酚类衍生物，如：对叔丁基苯酚，对甲苯酚的发光增强作用明显，其发光效率可上升几十倍，发光时间也获得有效延长。     

金属β-二酮化合物用于MOCVD法生长铁电氧化物薄膜

对用于MOCVD法生长铁电氧化物薄膜的金属β－二酮化合物的制备、结构及性质进行了评述，对它们在生长铁电薄膜中的应用现状进行了介绍，并对它们的应用前景作了展望。     

Effects of External Electric Field on Ferroelectric Superlattice with Two Alternating Layers

The effects of the external electric field on the ferroelectric superlattice with two alternating layers have been studied using the transverse Ising model based on the effective-field theory with the differential technique. The hysteresis loops and susceptibility of the system have been given. The stronger the external electric field, the smaller the susceptibility, reflecting that the polarization is weaker.     

流动注射化学发光法测定甲磺酸双氢麦角毒碱

磺酸双氢麦角毒碱(Co-dergocrine mesvlate,Hydergine)又名喜得镇、舒脑宁,我国将其列为国家基本药物.目前,测定甲磺酸双氢麦角毒碱的分析方法,主要有荧光分光光度法、可见紫外分光光度法、免疫分析法,但未见文献报道过化学发光法测定甲磺酸双氢麦角毒碱的研究.作者发现,在碱性条件下,过氧化氢直接氧化甲磺酸双氢麦角毒碱不会产生化学发光,但当高碘酸钾和甲磺酸双氢麦角毒碱混合反应后,再加过氧化氢氧化会产生较强的化学发光,且发光强度与甲磺酸双氢麦角毒碱的浓度在一定范围内有良好的线性关系,据此建立了流动注射化学发光测定甲磺酸双氢麦角毒碱的新体系.     

Spin-Polarized Tunnelling Magnetoresistance Effects in La0.833K0.167MnO3／SrTiO3 Polycrystalline Perovskite Manganites

A sample of La0.833K0.167MnO3-SrTiO3 (LKMO/STO) is fabricated by the sol-gel method. The microstructure,magnetic and transportation properties have been studied. X-ray diffraction patterns indicate that the structure of LKMO/STO is a homogeneous solid solution phase. The resistivity of LKMO/STO shows the insulator behaviour, which is different from La0.833K0.167MnO3 (LKMO) whose resistivity shows metal-insulator transition with decreasing temperature. The low-field (moH = 0.02 T) magnetoresistance decreases from 11% to 0.2% with the increasing temperature from 4 K‘to 220K for the LKMO/STO sample. The magnitude of magnetoresistance in a strong field (μoH = 5.5 T) almost increases linearly with decreasing temperature and reaches the maximum of 65% at the low temperature of 4.2K, which is much higher than that oE LKMO (40%). The enhanced low-field magnetoresistance effects are quantitatively explained by the spin-polarized tunnelling at grain boundaries.     

羰基镍分析报警仪

羰基镍分析报警仪运用化学发光原理构成，不仅适用于羰基镍生产车间现场的检测和报警，也适于实验室的研究工作。检出限达0.037mg/m^3(0.5ppb），响应时间2min。     

金钢石的制备研究

本文研究了两种不同质异构体石墨—金刚石的转化条件，以及在实验室现有条件下，利用石墨材料制备金刚石颗粒的具体方法和试验结果。     

NaNO3掺杂Y2O3材料的制备及电流变性质

利用NaCO3和Y（NO3）3做主要原料，合成了一系列用稀土氧化物（Y2O3）作为基础材料的新型电流变材料——NaNO3掺杂Y2O3材料。对于这些材料的介电性质、微观结构和电流变性能的研究结果表明，NaNO3的掺杂可以明显地提高Y2O3材料的电流变活性。材料在二甲基硅油中的悬浮液的剪切应力随NaNO3在Y2O3中的掺杂程度有明显变化，当Na／Y（物质的量的比）为0．6时材料的电流变性能最好，