煤直接液化油中混合酚的分离研究

利用分子筛择形特点，对煤直接液化油中的混合酚实施高效分离。本研究选取间甲酚和对甲酚作为分离煤直接液化油馏分段混合酚的模型化合物，采用化学液相沉积法对HZSM-5吸附剂的孔口结构进行改变，分析分子筛硅铝比及颗粒粒径对模型化合物间甲酚和对甲酚吸附分离性能的影响，以获得高性能固相吸附剂，并将其应用于180-190℃馏分段混合酚分离。结果表明，当分子筛硅铝比为25、粒径为3-5 μm时，分子筛的孔口结构调节效果最优；当正硅酸乙酯的最小用量为0.2 mL/g时，固相吸附剂的吸附量为0.03 g/g，对甲酚选择性高于95%。由于外表面沉积物对吸附剂的孔口结构变化，导致对甲酚选择性的提高。进一步采用HZSM-5（1）吸附剂对真实煤直接液化油混合酚的分离中发现，苯酚和对甲酚的选择性均达到100%。     

基于群论的晶格扰动介质纳米孔阵列多重Fano共振机理及演变

基于全介质超构材料独特的电磁属性,提出了一种晶格扰动介质纳米孔阵列超构表面来激发近红外区域的多重Fano共振.结合群论深入探究了该超构表面在其原胞为方形晶格构型与方形晶格对称性被破坏两情况下多重Fano共振的形成机理及演变规律.研究表明,在方形晶格超构表面中,外部辐射连续体分别与由正入射平面波直接激发的双重简并模式共振干涉形成双重Fano共振,且该共振与原胞中是否含孔及孔的形状无关,在晶格扰动超构表面中,原本不耦合的非简并模式由正入射平面波激发出来并与外部辐射连续体干涉形成Q值更高的三重Fano共振.进一步探讨了正入射平面波的xy极化方向对上述五重Fano共振的影响,结果表明,双重简并模式Fano共振偏振无关,三重非简并模式Fano共振偏振依赖.本文将为利用方形晶格构型的超构表面实现多重Fano共振的激发及演变提供有效的理论参考.     

磁各向异性色散介质散射的Pad啨时域有限差分方法分析

根据矩阵Pad啨逼近理论,把磁化色散介质的相对磁导率张量表示成以jω为自变量的矩阵函数形式,用/t代替jω后过渡到时域,再引入离散时域移位算子代替时间微分算子.进而导出磁化色散介质中的磁感应强度B和磁场强度H在离散时域的色散关系,并将其具体应用于旋磁介质,得到了这种磁化色散介质的Pad啨时域有限差分方法的递推表达式.作为验证,用这种方法计算了磁化铁氧体球的后向雷达散射截面,所得结果与文献结果一致.理论推导及算例表明,该方法是正确和有效的.     

Au/SiO2纳米多层薄膜的制备及其性质表征

利用多靶磁控溅射技术制备了Au/SiO2纳米颗粒分散氧化物多层复合薄膜.研究了在保持Au单层颗粒膜沉积时间一定时薄膜厚度一定、变化SiO2的沉积时间及SiO2的沉积时间一定而改变薄膜厚度时,多层薄膜在薄膜厚度方向的微观结构对吸收光谱的影响.研究结果表明:具有纳米层状结构的Au/SiO2多层薄膜在560nm波长附近有明显的表面等离子共振吸收峰,吸收峰的强度随Au颗粒的浓度增加而增强,在Au颗粒浓度相同的情况下,复合薄膜光学吸收强度随薄膜厚度的增加而增强.但当金属颗粒的浓度增加到一定程度时,金属颗粒相互接触,没有观察到纳米层状结构,薄膜不显示共振吸收峰特征.用修正后的M-G(Maxwell-Garnett)理论对吸收光谱进行了模拟,得到了与实验一致的结果.     

A New Method for the Analysis of Relative Permeability in Porous Media

By combining three-dimensional digital microtomography techniques with the lattice Boltzmann method,a new methodology is used to analyse the relative permeability of multiphase flow in porous media.The results indicate that the two coupling coefficients K12 and K21 have the same magnitude,therefore the Onsager reciprocity still holds,the results also agree well with the results of pipe flow numerical experiments.     

激光二极管反馈干涉的实验观测

利用LabView软件虚拟示波器和信号源,观测了激光二极管反馈干涉实验现象．实验证明反馈回激光二极管的光的入射方向和入射光强以及信号处理电路的带宽,对反馈干涉信号有很大的影响．     

混合判断矩阵排序方法研究

本文介绍了混合判断矩阵及完全一致性混合判断矩阵的概念，提出了混合判断矩阵排序的一种最小偏差法，并给出了其收敛性迭代算法，最后通过算例说明了方法的可行性。     

The Analysis and Improving of the Microwave Exciter in the Lower Hybrid Wave System

When we carry out lower hybrid wave heating and current driving plasma experiment at tokamak, we need mega-watt order of microwave power. The microwave signal at frequency of 2450 MHz is generated by a microwave exciter. According to the experiment＇s demands, the microwave exciter must provide output power of 1.5～ 2. 5 W with stabilized frequency and amplitude tobe used as the klystron input. Being amplified by the klystron, the microwave signal is transmitted through the transmitting system to the antenna and is emitted into the HL-2A tokamak. So we can see that the microwave exciter＇s function is very important to the lower hybrid wave heating and current driving plasma experiment.     

Experimental Study of Effect of Medium Boundary on Light Distribution in Tissue Phantoms

An experimental method for investigating the effect of medium boundary on distributions of light in the biological tissue phantom intralipid is presented. Measurements of distributions of light in intralipid-10% suspensions at 633 nm are described, in which a narrow collimated beam is incident on the surface of the phantoms and into the different depths inside of the phantoms. The experimental results show that the effect of the boundary of the medium on the curves geometry of light distributions is trivial, but the effect on intensity of scattering light is obvious, the maximal relative change of the energy fluence reaches 53.8% and the position of the peak of the energy fluence curve has a shift of 1.1 mm in the reverse direction of incident light for the phantom with albedo a=0.998, and the effect of the boundary is decreased with the increase of the absorption coefficients of tissue phantoms. The experimental results were analysed by the diffusion theory. These studies will be helpful for further understandings of the relation between the boundary of biological tissue and the distribution of light in tissue.     

相对论重离子碰撞实验中混合事件方法的研究

把RQMD(Relativistic Quantum Molecular Dynamics)产生器产生的数据输入作为原始事例取样,讨论了在比较复杂的背景情况下,一种新的混合事件方法,用以证实在相对论重离子碰撞实验中高能量激发共振态的存在.并以共振态重子Δ⁺⁺为例演示了这一方法的应用.