A convenient synthesis of pyrroles catalyzed by acidic resin under solvent-free condition

<正>A convenient and effective Paal-Knorr condensations of 2,5-hexanedione with most amines have been carried out at room temperature under solvent-free condition.Macroporous strongly acidic styrol resin(D001) as a novel,efficient,cost-effective,and reusable solid acid catalyst for the synthesis of pyrroles under the same conditions.The pyrroles were obtained in high yields in short reaction times.     

2-μm emission performance of Tm~(3+)-Ho~(3+) co-doped tellurite glasses

The emission properties of 2-μm region fluorescence of Tm~(3+)-Ho~(3+) co-doped tellurite glasses are investigated. Introducing F~- ions to the composition of tellurite glasses plays a positive effect on the 2-μm emission.A maximum intensity of 2-μm emission is achieved when 1.5-mol%Tm_2O_3 and l-mol% Ho_2_O3 concentration are doped in the glasses.The emission cross section and gain coefficient of the ~5I_8→~5I_7 transition of Ho~(3+) are calculated.The emission cross section has a maximum of 1.29×10~(-2...