全文获取类型
收费全文 | 116篇 |
免费 | 21篇 |
国内免费 | 57篇 |
专业分类
化学 | 44篇 |
力学 | 2篇 |
综合类 | 2篇 |
数学 | 72篇 |
物理学 | 74篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 8篇 |
2013年 | 8篇 |
2012年 | 8篇 |
2011年 | 1篇 |
2010年 | 14篇 |
2009年 | 12篇 |
2008年 | 24篇 |
2007年 | 17篇 |
2006年 | 18篇 |
2005年 | 24篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1981年 | 1篇 |
排序方式: 共有194条查询结果,搜索用时 15 毫秒
1.
采用气相分子吸收光谱法测定地下水中的亚硝酸盐氮(NO2^-)、氨氮(NH4^+)、硝酸盐氮(NO3^-)。考察NO2^-,NH4^+和NO3^-测定时的相互干扰,并给出了相应的消除方法。研究结果表明,测定NO2^-时,NH4^+和NO3^-无干扰;NO2^-对测定NH4^+和NO3^-产生干扰,可分别采用分段法和加入2滴10%氨基磺酸溶液的方法消除干扰;对于不含NO2^-或NO2-含量不高的地下水样品,可简化操作步骤直接测定NO3^-。该方法测定结果的相对标准偏差为0.73%~2.74%(n=12),样品加标回收率为97.67%~100.28%。所用检测仪器具有流动注射、自动进样及在线绘制标准曲线的功能,简化了标准方法中的样品前处理过程,减少了样品的损失,实现了自动化分析,大幅提高了检测结果的准确度和工作效率。 相似文献
2.
Fabrication of Melamine/Tb3+-Intercalated Polydiacetylene Nanosheets and Their Thermochromic Reversibility 下载免费PDF全文
Polydiacetylene (PDA) is one kind of the conjugated polymer with layered structure, which can serve as a host to accommodate the guest components through intercalation. In these intercalated PDAs, some of them were reported to have a nearly perfect organized structure and perform completely reversible thermochromism. Till now, these reported intercalated PDAs were made by only introducing a single component for intercalation. Here, we chose 10, 12-pentacosadiynoic acid (PCDA) as the monomer, of which the carboxyl-terminal groups can interact with either Tb\begin{document}$ ^{3+} $\end{document} ions or melamines (MAs). When the feeding molar ratio of PCDA, MA, and Tb\begin{document}$ ^{3+} $\end{document} ion was 3:267:1, only Tb\begin{document}$ ^{3+} $\end{document} ions were intercalated though excess MAs existed. Such Tb\begin{document}$ ^{3+} $\end{document} -intercalated poly-PCDA exhibited completely reversible thermochromism, where almost all the carboxyl groups interacted with Tb\begin{document}$ ^{3+} $\end{document} ions to form the nearly perfect structure. When the feeding molar ratio of PCDA, MA, and Tb\begin{document}$ ^{3+} $\end{document} ion was 3:267:0.6, both Tb\begin{document}$ ^{3+} $\end{document} ions and MAs were intercalated. There existed some defects in the imperfect MA-intercalated domains and at the domain boundaries. The MA/Tb\begin{document}$ ^{3+} $\end{document} -intercalated poly-PCDA exhibits partially reversible thermochromism, where the backbones near the defects are hard to return the initial conformation, while the rest, those at nearly perfect organized domains, are still able to restore the initial conformation. 相似文献
3.
4.
5.
A. V. Arhangel'skii R. Z. Buzyakova 《Proceedings of the American Mathematical Society》1999,127(8):2449-2458
We prove that the cardinality of every first countable linearly Lindelöf Tychonoff space does not exceed , and every strongly discretely Lindelöf Tychonoff space of countable tightness is Lindelöf.
6.
H. M. Srivastava 《Proceedings of the American Mathematical Society》1999,127(2):385-396
For a natural number , the author derives several families of series representations for the Riemann Zeta function . Each of these series representing converges remarkably rapidly with its general term having the order estimate:
Relevant connections of the results presented here with many other known series representations for are also pointed out.
7.
Let be a nonempty closed convex subset of a real Banach space and be a Lipschitz pseudocontractive self-map of with . An iterative sequence is constructed for which as . If, in addition, is assumed to be bounded, this conclusion still holds without the requirement that Moreover, if, in addition, has a uniformly Gâteaux differentiable norm and is such that every closed bounded convex subset of has the fixed point property for nonexpansive self-mappings, then the sequence converges strongly to a fixed point of . Our iteration method is of independent interest.
8.
Pedro L. Q. Pergher 《Transactions of the American Mathematical Society》2001,353(1):175-189
Given a collection of real vector bundles over a closed manifold , suppose that, for some is of the form , where is the trivial one-dimensional bundle. In this paper we prove that if is the fixed data of a -action, then the same is true for the Whitney sum obtained from by replacing by . This stability property is well-known for involutions. Together with techniques previously developed, this result is used to describe, up to bordism, all possible -actions fixing the disjoint union of an even projective space and a point. 相似文献
9.
在光学势中引入色散关系, 相比于通常的耦合道光学模型, 极大地减少了光学势
参数的个数. 采用基于软旋转子模型的耦合道方法对较轻形变核28Si核的中子和质子散射实验数据进行了计算分析, 拟合得到一组色散光学势参数. 计算的中子总截面、以及中子、质子的弹性与非弹性散射微分截面与实验数据有较好的符合. 相似文献
10.
19F-NMR技术由于其化学位移范围大、不易出现峰重叠及灵敏度高等优点,自上个世纪50年代出现以来,在分析光学异构体,生命科学等研究中有其特殊意义.在体内核磁共振技术中,19F-NMR与其他方法相比,在不损伤样品的条件下,就可进行实时定量监测.近30年,引人氟代指示剂进行体内19F-NMR的研究,含氟生物活性物质以及含氟材料的研究受到很大的重视,19F-NMR技术及其应用发展起来.从近10年的情况来看,含氟生物活性物质的研究以及在医药、农药和具有优异性能的含氟材料的研究应用受到很大的重视,这是近期19F-NMR研究发展的一个主要特点. 相似文献