全文获取类型
收费全文 | 22371篇 |
免费 | 3115篇 |
国内免费 | 1825篇 |
专业分类
化学 | 9611篇 |
晶体学 | 101篇 |
力学 | 2149篇 |
综合类 | 223篇 |
数学 | 7513篇 |
物理学 | 7714篇 |
出版年
2024年 | 35篇 |
2023年 | 262篇 |
2022年 | 434篇 |
2021年 | 489篇 |
2020年 | 790篇 |
2019年 | 645篇 |
2018年 | 585篇 |
2017年 | 575篇 |
2016年 | 841篇 |
2015年 | 822篇 |
2014年 | 1096篇 |
2013年 | 1922篇 |
2012年 | 1308篇 |
2011年 | 1326篇 |
2010年 | 1002篇 |
2009年 | 1424篇 |
2008年 | 1401篇 |
2007年 | 1441篇 |
2006年 | 1317篇 |
2005年 | 1101篇 |
2004年 | 1012篇 |
2003年 | 948篇 |
2002年 | 819篇 |
2001年 | 706篇 |
2000年 | 686篇 |
1999年 | 559篇 |
1998年 | 576篇 |
1997年 | 487篇 |
1996年 | 387篇 |
1995年 | 324篇 |
1994年 | 268篇 |
1993年 | 233篇 |
1992年 | 196篇 |
1991年 | 170篇 |
1990年 | 131篇 |
1989年 | 104篇 |
1988年 | 110篇 |
1987年 | 80篇 |
1986年 | 93篇 |
1985年 | 73篇 |
1984年 | 67篇 |
1983年 | 28篇 |
1982年 | 64篇 |
1981年 | 53篇 |
1980年 | 39篇 |
1979年 | 41篇 |
1978年 | 55篇 |
1977年 | 57篇 |
1976年 | 48篇 |
1974年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
In this article, we construct and analyze a residual-based a posteriori error estimator for a quadratic finite volume method (FVM) for solving nonlinear elliptic partial differential equations with homogeneous Dirichlet boundary conditions. We shall prove that the a posteriori error estimator yields the global upper and local lower bounds for the norm error of the FVM. So that the a posteriori error estimator is equivalent to the true error in a certain sense. Numerical experiments are performed to illustrate the theoretical results. 相似文献
2.
Seema Prasad 《Molecular Crystals and Liquid Crystals》2018,665(1):52-63
Molecular structure and vibrational spectroscopic studies of higher homologous series nematogenic p-n-alkylbenzoic acids (nBAC) that have 6 (6BAC) and 7 (7BAC) carbon atoms in the alkyl chain have been investigated using the Density Functional Becke3-Lee-Yang-Parr (B3LYP) level with the basis set 6-31++G (d.p) and Hartree Fock (HF) with the same basis set. The observed vibrational spectra has been resolved and assigned in detail for comparision with both the molecules. These results indicate that DFT and HF values are slightly different at both the levels. A comparision of chemical reactivity such as HOMO (EH), LUMO (EL) energies, energy gap (Eg), ionization energy (I), electron affinity (A), electro negativity (χ), chemical hardness (η), electronic chemical potential (μ), electrophilicity index (ω), and softness (S) has been made. It has been observed that the decrement has occurred in the energy band gap value of isolated molecule with increment in alkyl chain length. This provides valuable information regarding enhancing the stability of liquid crystal materials by maintaining the conductivity. 相似文献
3.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation. 相似文献
4.
V. V. Sagaradze N. V. Kataeva V. A. Zavalishin K. A. Kozlov V. V. Makarov A. R. Kuznetsov 《哲学杂志》2020,100(14):1868-1879
ABSTRACT The authors present the results of an investigation in Fe–Ni-Cr austenitic alloys of the low-temperature deformation-induced segregations of nickel that form in the micro regions being (i) located close to grain- and subgrain boundaries and (ii) characteristic of the concentration and magnetic inhomogeneities indicated by the appearance of a dark diffraction contrast at the electron diffraction patterns taken from these regions typical (at the same time) of an enhanced value of Curie temperature. The observed effects were connected with the micro distortions caused by the local change of lattice parameter because of an increase in nickel concentration, as well as in the result of a magnetostriction dilatation. Using methods of the X-ray energy dispersive spectroscopy (XEDS) and atomic-probe body-section radiography (tomography – APT) has made it possible to determine the borders of those regions of austenite that were characteristic of an enhanced concentration of nickel in the fields of the localisation of a deformation-induced segregation of nickel in the vicinity of grain (subgrain) boundaries of austenitic alloys of the types Fe–13Cr–30Ni and Fe–37Ni–3Ti. 相似文献
5.
6.
在管式反应器中采用苯甲酸、聚乙二醇、固体古马隆树脂(S)、液体古马隆树脂(L)为添加剂来降低煤沥青中有害物质苯并芘的含量,以期使得煤沥青可绿色化应用。采用紫外-可见分光光度计分析煤沥青中苯并芘含量。考察了反应温度、反应时间、添加剂添加量、催化剂等工艺条件对添加剂脱除煤沥青中苯并芘的影响。结果表明,不同工艺条件能降低煤沥青中苯并芘的含量。在优化条件下,不同添加剂对苯并芘脱除率由高到低依次为:液体古马隆树脂、聚乙二醇、苯甲酸和固体古马隆树脂。分析其反应机理,这与催化剂的酸性相关,发生亲电取代反应。结果表明,液体古马隆树脂(L)在催化剂存在下对煤沥青中苯并芘脱除率可达73.0%,显示了良好的应用前景。 相似文献
7.
A fundamental question in random matrix theory is to quantify the optimal rate of convergence to universal laws. We take up this problem for the Laguerre β ensemble, characterized by the Dyson parameter β, and the Laguerre weight , in the hard edge limit. The latter relates to the eigenvalues in the vicinity of the origin in the scaled variable . Previous work has established the corresponding functional form of various statistical quantities—for example, the distribution of the smallest eigenvalue, provided that . We show, using the theory of multidimensional hypergeometric functions based on Jack polynomials, that with the modified hard edge scaling , the rate of convergence to the limiting distribution is , which is optimal. In the case , general the explicit functional form of the distribution of the smallest eigenvalue at this order can be computed, as it can for and general . An iterative scheme is presented to numerically approximate the functional form for general . 相似文献
8.
In this paper, we propose a sufficient and necessary condition for the boundedness of all the solutions for the equation with the critical situation that on g and p, where , is periodic and is bounded. 相似文献
9.
Prof. Dr. Frank Glorius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8047-8051
A general and efficient methodology for the direct transition metal free trifluoromethylthiolation of a broad range of biologically relevant N‐heteroarenes is reported employing abundant sodium chloride as the catalyst. This method is operationally simple, exhibits high functional group tolerance, and does not require protecting groups. 相似文献
10.
《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2020,37(2):417-456
We study the energy-critical nonlinear wave equation in the presence of an inverse-square potential in dimensions three and four. In the defocussing case, we prove that arbitrary initial data in the energy space lead to global solutions that scatter. In the focusing case, we prove scattering below the ground state threshold. 相似文献