限制李超代数p-理想与其Frattini p-理想紧密联系的性质

对限制李超代数的一些p-理想与Frattini p-理想紧密联系的性质进行了讨论,给出p-基本限制李超代数和E-p-限制李超代数的一些结果,证明L是E-p-限制李超代数当且仅当L/φp(L)是p-基本的,研究了p-理想Ep(L)(其中Ep(L)是含于一切满足L/A是p-基本的所有p-理想A的交),描述限制李超代数的Frattini p-理想和某些p-理想之间的关系.     

有机化合物电子光谱中的助色基及其作用机理探讨(Ⅰ)

本文就电子光谱中助色基的作用进行了讨论 ,认为不能一概地认为助色基能使与之相连的生色基最大吸收波长统统发生红移 ,而应具体问题具体分析 :对于n→π 来说 ,一方面助色基的p轨道和生色基的最低π 反键空轨道相互作用 ,使π 反键轨道能量上升 ,另一方面助色基的p轨道和生色基的n轨道正交 ,n轨道能量基本保持不变 ,因此n→π 跃迁能增加 ,吸收波长发生蓝移。对于π→π 跃迁来说 ,助色基的p轨道和生色基的最高π成键轨道相互作用生成的新的最高π成键轨道 ,能量虽然有所升高 ,但升高的程度与π 反键轨道升高的程度相比 ,在一些化合物中π轨道升高程度较大 ,因而π→π 跃迁能减小 ,吸收波长发生红移 ;在另一些化合物中π轨道升高程度较小 ,因而π→π 跃迁能增加 ,吸收波长发生蓝移。     

p-τ值对COIL的影响的实验研究

 实验研究了单重态氧发生器（SOG）的p-τ值，即初始氯气分压与停留时间的乘积，对化学氧碘激光器（COIL）的影响，并分析了诸多实验因素对SOG的p-τ值的影响。对于提高COIL的化学效率具有很重要的实际意义。     

无限维奇Hamilton模李超代数的导子

本文首先确定了无限维奇Hamilton模李超代数的生成元集,然后确定了奇Hamilton模李超代数到广义Witt模李超代数的导子空间,进而确定了无限维奇Hamilton模李超代数的导子代数.     

A New Efficient Synthesis of p-Nitrocalix[4]arene

A new efficient synthesis of p-nitrocalix[4]arene from calix[4]arene by using nitrogen dioxide is described.The compound is an useful intermediates for the introduction of other functional groups to obtain N containing substituted calix[4]arene.The reaction mechanism is briefly discussed.     

PREPARATION AND CHARACTERIZATION OF SHISH-KEBAB TYPE LIQUID CRYSTALLINE POLY（p-PHENYLENEVINYLENE）

Novel shish-kebab type liquid crystalline poly（p-phenylenevinylene） derivatives were synthesized by Stille coupling reaction from 2,5-bis[（4-n-alkoxyl）benzoyloxy]1,4-dibromobenzene （monomer l） and 1,2-bis（tributylstannyl） ethylene （monomer 2）. The polymers with alkoxy groups are soluble in common organic solvents and exhibit blue fluorescence. Both the cast film and the annealed film have large red-shifts in fluorescence spectra and show yellow fluorescence. The polymers with CN and NO2 groups show poor solubility and green fluorescence. All the polymers possess liquid crystalline smectic phases. The melting point （Tm） of the polymers decreases when the length of the alkoxy tails of the mesogenic units increases. The polymers are easily aligned under a magnetic field of 10 Tesla. It is found that the conjugated backbone and LC side chain are aligned perpendicular and parallel to the magnetic field, respectively. The polymers show optical dichroism in fluorescence spectra, suggesting that they are available for advance materials with linear optical polarization.     

VINYL MONOMERS BEARING CHROMOPHORE MOIETIES AND THEIR POLYMERS——Ⅹ.INITIATION AND PHOTOCHEMICAL PROPERTIES OF p-(N,N-DIMETHYLAMINO)STYRENE AND ITS POLYMERS*

A vinyl monomer having an electron-donating moiety, p-(N,N-dimethylamino)styrenc (DMAS),was synthesized. It was combined with benzoyl peroxide (BPO) to form a redox initiation system to initiatethe polymerization of methyl methacrylate (MMA). UV spectra measurements show that DMAS enters thePMMA chain as well. Both DMAS and its polymer P(DMAS) display strong fluorescence, and thefluorescence can be quenched by electron-deficient compounds such as methacrylonitrile, fumaronitrile andmethyl methacrylate etc. Moreover, DMAS can also form charge transfer complex (CTC) with strongelectron acceptors such as tetracyanoethylene (TCNE). The difference between the photochemical propertiesof DMAS and P(DMAS) were explained in terms of molecular structure change and polymer conformationeffect in solution. In addition, the CTC and exciplex formation of DMAS or P(DMAS) with C_(60) were alsostudied.     

Synthesis and Adsorption Property of Two Polymeric Adsorbents with Pendent Ether Bonds

Two polymeric adsorbents, poly(methyl p-vinylbenzvl ether) and oolv(ohenvl p-vinylbenzyl ether), were synthesized from chloromethylated polystyrene, Their adsorptionproperty for phenol in hexane solution was investigated. The results showed that the twoadsorbents adsorb phenol from hexane solution through hydrogen-bonding and π-π stacking interaction.     

p-超可解融合系

本文研究有限群.设p是一个素数, S是一个p-群, F为S上的饱和融合系.本文首先给出p-超可解融合系的定义.随后证明p-超可解融合系的模型是p-超可解群,并给出p-超可解融合系的正规子系和因子系的超可解性.最后给出p-超可解融合系的判定准则.