考虑重力因素的断溶体储层“井-洞-缝”模型试井解释方法

顺北油田属于大型断裂构造运动形成的断溶体储层，纵向裂缝系统和垂向分布的溶洞是主要的储集体空间.本文提出溶洞中的压力变化是由流动和波动共同产生的，依此把能量守恒方程与试井理论相结合，建立考虑重力因素的断溶体储层试井解释方法.定义无量纲量，并对无量纲方程进行Laplace变换，得到Laplace空间上的井底压力.由Stehfest数值反演算法得到试井分析所需的图版曲线.对重力因素进行敏感性分析表明：重力因素只影响双对数曲线的末期，当重力因素很明显时，曲线特征类似于定压边界.对新疆油田的某井进行分析，解释了曲线后期下掉原因，并给出溶洞体积以及波动相关参数等，分析结果与生产实际情况相吻合.     

An innovative SiO2-pyrazole nanocomposite for Zn(II) and Cr(III) ions effective adsorption and anti-sulfate-reducing bacteria from the produced oilfield water

Novel SiO₂-pyrazole (SiO₂-PYZ) nanocomposite was introduced for the elimination of Zn(II) and Cr(III) from oil reservoir water. Characterization analysis of prepared SiO₂-PYZ nanocomposite was investigated using SEM, FTIR, TGA, XRD, TEM, and BET. Studying the effects and optimization of the parameters such as retention time, pH, initial Cr(III) and Zn(II) ions concentrations, adsorbent dosage, and temperature were examined. For kinetics investigation, the pseudo-second-order (PSO) model matches the adsorption process effectively under different operating conditions. After applying two other isotherm models (Langmuir and Freundlich), the experimental data was adequately equipped with Langmuir, R² = 1. The thermodynamic results pointed that the adsorption of Zn(II) and Cr(III) ions was spontaneous, endothermic, and physisorption reaction. At pH 12, the influence of more than one ion, such as Ca(II) and Na(I), was checked, and the results revealed that this conjugate substance was highly selective to Cr(III). After washing with water in multiple cycles, the adsorbed material was regenerated with 0.1 M HCl and subsequently reused without deterioration in its case cavities. Interestingly, SiO₂-PYZ was highly effective against sulfate-reducing bacteria (SRB) in the petroleum field.     

离子液体处理含油污水实验研究

合成出了适合于含油污水处理的憎水性离子液体,研究了离子液体对含油污水的处理条件。当离子液体与含油污水体积比为1∶5,pH值为5,处理15min后,水中油的去除率为95.6%,COD_Cr的去除率为93.5%,表明应用离子液体可以有效地去除油田采出水中的有机物。同时考察了再生离子液体对除油效果的影响,其五次平行实验的除油率达95.4%,COD_Cr去除率为93.2%,表明离子液体可以回收利用。在此基础上,分析了离子液体对含油污水处理的作用机理。     

基于不同优先级的油田增产多目标规划

为了衡量目标优先级不同对油田增产决策的影响,建立了基于不同优先级的多目标规划模型,并对增油量和措施费用两个目标不同优先级下的模型进行了求解,结果表明,目标优先级不同,油田增产措施的配置结果不同,但主要集中在对有效增产措施的配置上,对于效果较差的增产措施并无差异;同时,目标优先级不同导致目标的最优解相差较大,反映了决策者偏好对油田中后期增产决策的重要性.     

岩心表面润湿性与化学选堵剂对油水的封堵能力

选择阳离子聚丙烯酰胺类选堵剂,进行岩心模拟实验,研究不同岩心表面润湿性与化学选堵剂封堵能力之间的关系.表面润湿性强烈影响对水的堵塞率,水润湿性越强,对水的堵塞率越高,典型的亲水表面和亲油表面对水的堵塞率相差20%左右;使用水基凝胶,水驱后的残余阻力系数(RRF)大于油驱后的RRF,水基凝胶使水相渗透率的降低比油相渗透率的降低多.对于润湿性相同,渗透率不同的天然岩心,选堵剂的堵水率大于85%,堵油率在20%左右,表现出良好的选择性.     

油田开发指标系统的概率模拟预测

基于油田开发指标系统的复杂性和其影响因素带有明显的随机特征,从理论和实用上研究了油田开发指标系统的不确定性预测方法.方法提出采用神经网络建立开发指标和影响因素的关联关系;利用微分模拟研究开发指标的影响因素的概率分布;使用蒙特卡罗方法对影响因素进行随机抽样;依据得到的关联关系和影响因素的随机样本建立油田开发指标的概率预测模型.此外,设计了概率模拟器.实例研究表明开发指标的预测值以某概率落在某个区间内,这可为决策者做出符合实际的决策和准备应急决策方案提供依据.     

残酸对原油脱水的影响及处理

酸对原油的破乳具有较大的影响,盐酸的存在使原油脱水发生困难,特别是在稠油中,脱水效率降低;土酸对原油脱水影响比盐酸更大,脱出水颜色发黑,发黄,有大量底渣存在;残酸对原油的脱水影响最大,脱水速度减慢,水色不清,过渡带加长.针对酸化后原油pH值较低的特点,选择碳酸钠作碱化剂,复配低温2#破乳剂,进行了室内实验和现场试验,结果表明:原油脱水效果明显,脱出水颜色清,油水过渡带清晰,保证返排液的pH值保持在6～8的范围内,使原油含水质量分数低于2%.     

塔河油田超埋深碳酸盐岩油藏基质的力学试验研究

碳酸盐岩油气藏在全球范围内分布广泛,其中30%以上为缝洞型碳酸盐岩油气藏。在我国缝洞型油藏占已探明的碳酸盐岩油藏储量的2/3,是今后增储的主要领域。为准确揭示碳酸盐岩油藏基质的力学特性,本文以塔河油田奥陶系油藏地层为研究背景,通过现场深孔钻井取样得到埋深达5300~6200m的碳酸盐岩油藏基质岩样,并通过力学试验首次获得超埋深碳酸盐岩油藏基质的弹模、泊松比、抗压强度、抗拉强度、粘聚力、内摩擦角等力学参数,借助电镜扫描试验揭示出超埋深碳酸盐岩的微细观破裂机制。该项研究成果可为分析碳酸盐岩油藏溶洞的垮塌破坏机理提供有效的试验参数。     

应用废弃果皮制备绿色钻井液添加剂的综合性实验

设计了应用废弃果皮制备绿色钻井液添加剂的综合性实验,评价其对钻井液性能的影响.该实验将油田化学理论基础与实验技术、现场实践相结合,能够提高学生的专业实验技能、分析和解决问题的能力,同时采用废弃果皮作为实验原料,可提高学生的环保意识,有助于将环保理念注入日后油田生产中.     

Theory and application of numerical simulation method of capillary force enhanced oil production

A kind of second-order implicit upwind fractional step finite difference methods are presented for the numerical simulation of coupled systems for enhanced(chemical)oil production with capillary force in the porous media.Some techniques,e.g.,the calculus of variations,the energy analysis method,the commutativity of the products of difference operators,the decomposition of high-order difference operators,and the theory of a priori estimate,are introduced.An optimal order error estimate in the l~2 norm is derived.The method is successfully used in the numerical simulation of the enhanced oil production in actual oilfields.The simulation results are satisfactory and interesting.