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G. G. Bandyopadhyay S. S. Bhagawan K. N. Ninan Sabu Thomas 《Journal of Polymer Science.Polymer Physics》2004,42(8):1417-1432
The viscoelastic properties of binary blends of nitrile rubber (NBR) and isotactic polypropylene (PP) of different compositions have been calculated with mean‐field theories developed by Kerner. The phase morphology and geometry have been assumed, and experimental data for the component polymers over a wide temperature range have been used. Hashin's elastic–viscoelastic analogy principle is used in applying Kerner's theory of elastic systems for viscoelastic materials, namely, polymer blends. The two theoretical models used are the discrete particle model (which assumes one component as dispersed inclusions in the matrix of the other) and the polyaggregate model (in which no matrix phase but a cocontinuous structure of the two is postulated). A solution method for the coupled equations of the polyaggregate model, considering Poisson's ratio as a complex parameter, is deduced. The viscoelastic properties are determined in terms of the small‐strain dynamic storage modulus and loss tangent with a Rheovibron DDV viscoelastometer for the blends and the component polymers. Theoretical calculations are compared with the experimental small‐strain dynamic mechanical properties of the blends and their morphological characterizations. Predictions are also compared with the experimental mechanical properties of compatibilized and dynamically cured 70/30 PP/NBR blends. The results computed with the discrete particle model with PP as the matrix compare well with the experimental results for 30/70, 70/30, and 50/50 PP/NBR blends. For 70/30 and 50/50 blends, these predictions are supported by scanning electron microscopy (SEM) investigations. However, for 30/70 blends, the predictions are not in agreement with SEM results, which reveal a cocontinuous blend of the two. Predictions of the discrete particle model are poor with NBR as the matrix for all three volume fractions. A closer agreement of the predicted results for a 70/30 PP/NBR blend and the properties of a 1% maleic anhydride modified PP or 3% phenolic‐modified PP compatibilized 70/30 PP/NBR blend in the lower temperature zone has been observed. This may be explained by improved interfacial adhesion and stable phase morphology. A mixed‐cure dynamically vulcanized system gave a better agreement with the predictions with PP as the matrix than the peroxide, sulfur, and unvulcanized systems. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1417–1432, 2004 相似文献
5.
Polypropylene (PP) was modified with elastomer or CaCO3 particles of two different sizes (1 μm and 50 nm) in various volume fractions. The dispersion morphology and mechanical properties of the two systems were investigated as functions of the particle size and volume fraction of the modifier. The brittle‐to‐tough transition occurred when the matrix ligament thickness was less than the critical ligament thickness, which was about 0.1 μm for the PP used here, being independent of the type of modifier. At the same matrix ligament thickness, the improvement of the toughness was obviously higher with the elastomer rather than with CaCO3, but adding CaCO3 increased the modulus of PP. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1656–1662, 2004 相似文献
6.
We construct a new family of cyclic difference sets with parameters ((3
d
– 1)/2, (3
d – 1 – 1)/2, (3
d – 2 – 1)/2) for each odd d. The difference sets are constructed with certain maps that form Jacobi sums. These new difference sets are similar to Maschietti's hyperoval difference sets, of the Segre type, in characteristic two. We conclude by calculating the 3-ranks of the new difference sets. 相似文献
7.
The periodic precipitation pattern formation in gelatinous media is interpreted as a moving boundary problem. The time law,
spacing law and width law are revisited on the basis of the new scenario. The explicit dependence of the geometric structure
on the initial concentrations of the reactants is derived. Matalon—Packter law, which relates the spacing coefficient with
the initial concentrations is reformulated removing many ambiguities and impractical parameters. Experimental results are
discussed to establish the significance of moving boundary concept in the diffusion controlled pattern forming systems 相似文献
8.
Weimin Xue 《中国科学A辑(英文版)》1997,40(7):673-679
A ringR is left co-semihereditary (strongly left co-semihereditary) if every finitely cogenerated factor of a finitely cogenerated
(arbitrary) injective leftR-module is injective. A left co-semihereditary ring, which is not strongly left co-semihereditary, is given to answer a question
of Miller and Tumidge in the negative. If
R
U
S
defines a Morita duality,R is proved to be left co-semihereditary (left semihereditmy) if and only ifS is right semihereditary (right co-semihereditary). Assuming thatS⩾R is an almost excellent extension,S is shown to be (strongly) right co-semihereditary if and only ifR is (strongly) right co-semihereditary.
Project supported by the National Natural Science Foundation of China. 相似文献
9.
本文给出Om×GLn作用于Cm,n上的复多项式环上的最高权向量环的Krull维数公式,从而改正了Aslaksen,Tan及Zhu的一个错误. 相似文献
10.
The FRS-ESR facility at GSI provides one of the most efficient methods for direct mass measurements. In the present experiment,
exotic nuclei were produced via fragmentation of 152Sm projectiles in a thick beryllium target at 500-600 MeV/u, separated in-flight with the fragment separator FRS, and injected
into the storage-cooler ring ESR. Time-resolved Schottky Mass Spectrometry was applied for mass measurements of stored and
electron-cooled bare and few-electron ions. 373 different nuclides were identified by means of the spectra of their revolution
frequencies. Masses for 18 nuclides (84Zr, 92Ru, 94Rh, 107,108,110Sb, 111,112,114I, 118Ba, 122,123La, 124Ce, 127Pr, 129Nd, 132Pm, 134Sm, 137Eu) have been determined for the first time. Masses for 111,112I and 113Xe have been obtained via known α-decay energies. The experiment and first results will be presented. 相似文献