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1.
2.
Most adhesives and binders, including bitumen for asphalt mixture production, are presently produced from petrochemicals after
the refining of crude oil. The fact that crude oil reserves are a finite resource means that in the future, it may become
necessary to produce these materials from alternative and probably renewable sources. Suitable resources of this kind may
include polysaccharides, plant oils and proteins. This paper deals with the synthesis of polymer binders from monomers that
could, in future, be derived from renewable resources. These binders consist of polyethyl acrylate (PEA) of different molecular
weight, polymethyl acrylate (PMA) and polybutyl acrylate (PBA), which were synthesised from ethyl acrylate, methyl acrylate
and butyl acrylate, respectively, by atom transfer radical polymerisation. The rheological properties of these binders were
determined by means of oscillatory testing using a dynamic shear rheometer and combinations of stress/strain, temperature
and frequency sweeps. The results indicate that PEA can be produced to have rheological properties similar to that of ‘soft’
100/150 penetration grade bitumen, PMA with similar rheological properties to that of ‘hard’ 10/20 penetration grade bitumen,
while PBA, due to its highly viscous nature and low dynamic moduli, cannot be used on its own as a binder. The synthetic polymers
were found to be thermo-rheologically simple, and the shift factors, used to produce the dynamic moduli master curves, were
found to fit an Arrhenius function. 相似文献
3.
Harro Lentz Ernst Ulrich Franck 《Angewandte Chemie (International ed. in English)》1978,17(10):728-730
Liquid or dense supercritical ammonia has been suggested as an extraction fluid. It is indeed good solvent for very different classes of compounds, as can be seen from phase diagrams. Such diagrams for binary systems of ammonia and hydrocarbons are presented and discussed on the basis of their critical curves. Apparatus and methods for the measurement of phase equilibria and equation of state data of fluid mixtures at high pressure are described. 相似文献
4.
The electronic spectrum of VCr has been studied using the complete-active-space self-consistent field complete-active-space second-order perturbation theory approach. Potential-energy curves for 12 electronic states have been computed. Transition energies, with respect to the X2 ground state, for some of the calculated electronic states are (with possible experimental values within parentheses) 0.53 eV (0.56) for A2+, 1.03 eV (1.14) for A4, 1.20 eV (1.14) for B2, 1.45 eV (1.51) for B4, 1.60 eV (1.51, 1.78) for C2, and 1.61 eV (1.63) for A4–.
AcknowledgementsThe research reported in this communication was supported by a grant from the Swedish Natural Science Research Council (NFR). S. Alex and D.G. Leopold are acknowledged for providing results from their negative ion photoelectron spectroscopy on VCr.Contribution to Björn Roos Honorary Issue 相似文献
5.
针对保参数方向构造过渡曲线曲面方法的不足, 构造了任意参数曲线曲面间既保持参数方向又具有形状可调性的C 1与C 2连续过渡曲线曲面。首先,基于2类带1个自由参数的调配函数,分别构造满足C 1与C 2连续的过渡曲线,并讨论基于能量优化模型的最佳过渡曲线构造问题;然后,将所提出的方法推广到过渡曲面的构造。 实例结果表明,2被过渡曲线曲面为任意参数曲线曲面时,利用该方法构造的过渡曲线曲面不仅与2被过渡曲线曲面的参数方向保持一致,而且可利用所带的自由参数对其形状进行调整。通过能量优化模型确定自由参数的取值,可获得尽可能光顺的过渡曲线曲面。 所提方法弥补了保参数方向构造过渡曲线曲面方法的不足,是一种实用的过渡曲线曲面构造方法。 相似文献
6.
Behavior of lysozyme adsorbed onto biological liquid crystal lipid monolayer at the air/water interface 下载免费PDF全文
The interaction between proteins and lipids is one of the basic problems of modern biochemistry and biophysics.The purpose of this study is to compare the penetration degree of lysozyme into 1,2-diapalmitoyl-sn-glycero-3-phosphocholine(DPPC) and 1,2-dipalmitoyl-sn-glycero-3-phosphoethano-lamine(DPPE) by analyzing the data of surface pressure–area(π–A) isotherms and surface pressure–time(π–T) curves.Lysozyme can penetrate into both DPPC and DPPE monolayers because of the increase of surface pressure at an initial pressure of 15 m N/m.However,the changes of DPPE are larger than DPPC,indicating stronger interaction of lysozyme with DPPE than DPPC.The reason may be due to the different head groups and phase state of DPPC and DPPE monolayers at the surface pressure of 15 m N/m.Atomic force microscopy reveals that lysozyme was absorbed by DPPC and DPPE monolayers,which leads to self-aggregation and self-assembly,forming irregular multimers and conical multimeric.Through analysis,we think that the process of polymer formation is similar to the aggregation mechanism of amyloid fibers. 相似文献
7.
Ronald F. Bruner 《International Journal of Theoretical Physics》2009,48(9):2704-2714
It is shown that if a volume element V, of space is assumed to have intrinsic energy E, then basic principles of mechanics, thermodynamics and special relativity lead to the equation of state: E=pV, where p is the pressure. When this equation of state is incorporated in the Einstein equations it leads to the prediction that the
orbital speed of matter circling a visible galaxy embedded in a spherical galactic halo should be relativistic, in disagreement
with observations. However, it also leads directly to the interesting notion that the inertial mass of such a medium can be
understood as a resistance to being compressed via Lorentz contraction. It is then shown that the mathematical structure of
thermodynamics suggests another plausible definition of pressure if we allow for the possibility that the intrinsic energy
of spacetime may not be described by the same work-energy relationship as ordinary matter. This additional possibility leads
to the equation of state: E=−pV. While both of these equations of state describe forms of energy that are quite unlike ordinary energy, neither alone is
able to account for observed rotational velocity curves of matter orbiting visible galaxies. Therefore, the possibility that
space has two distinct components of energy is investigated. This results in a plausible, two-component equation of state
in which the former equation of state is tentatively identified as the “dark matter” (DM) component, the latter as the “dark
energy” (DE) component. The effective equation of state of space, accounting for the presence of both components, may then
be written in the form: p=w
ε, where ε is the total energy density, p the total pressure, and w represents the fractional excess of DM over DE (and therefore satisfies: −1≤w≤+1). Given the wide range of possible spacetime properties implied by this equation it appears to be a viable candidate for
explaining observations presently attributed to the presence of both DM and DE. Specifically, the static, spherically symmetric
solution of Einstein’s field equations, neglecting effects of ordinary matter, predicts the inverse r
2 distribution of intrinsic space energy required to explain observed constant rotational velocity curves for matter in circular
orbits around visible galaxies embedded within spherically symmetric galactic halos. The proposed equation of state is also
capable of describing regions of space undergoing accelerated expansion as regions where DE is dominant (i.e., w<−1/3). 相似文献
8.
Theoretical study of the electronic structure of LiNa and LiNa<Superscript>+</Superscript> molecules
Neji Khelifi Riadh Dardouri Omar Marzook Al-Dossary Brahim Oujia 《Journal of Russian Laser Research》2009,30(2):172-186
Adiabatic potential energy, spectroscopic constants, dipole moments, and vibrational levels of the lowest electronic states
of the alkali dimer LiNa molecule dissociating into Na (3s, 3p, 4s, 3d, and 4p) + Li (2s, 2p, 3s, and 3p) in 1,3Σ, 1,3Π, and 1,3Δ symmetries are presented. Adiabatic results are also reported for 2Σ, 2Π, and 2Δ electronic states of the molecular ion LiNa+ dissociating into Li (2s, 2p, 3s, and 3p) + Na+ and Li+ + Na(3s, 3p, 4s, 3d, and 4p). We use an ab initio approach involving a non-empirical pseudopotential for the Li (1s2) and Na (1s22s22p6) cores and core valence correlation correction. A very good agreement is obtained for some lowest states of the LiNa and
LiNa+ molecules for spectroscopic constants with the available theoretical works. The existence of numerous avoided crossings between
electronic states of 2Σ and 2Π symmetries is related to the charge transfer process between the two ionic systems Li+Na and LiNa+. 相似文献
9.
10.
We analyze discrete symmetry groups of vertex models in lattice statistical mechanics represented as groups of birational transformations. They can be seen as generated by involutions corresponding respectively to two kinds of transformations onq×q matrices: the inversion of theq×q matrix and an (involutive) permutation of the entries of the matrix. We show that the analysis of the factorizations of the iterations of these transformations is a precious tool in the study of lattice models in statistical mechanics. This approach enables one to analyze two-dimensionalq
4-state vertex models as simply as three-dimensional vertex models, or higher-dimensional vertex models. Various examples of birational symmetries of vertex models are analyzed. A particular emphasis is devoted to a three-dimensional vertex model, the 64-state cubic vertex model, which exhibits a polynomial growth of the complexity of the calculations. A subcase of this general model is seen to yield integrable recursion relations. We also concentrate on a specific two-dimensional vertex model to see how the generic exponential growth of the calculations reduces to a polynomial growth when the model becomes Yang-Baxter integrable. It is also underlined that a polynomial growth of the complexity of these iterations can occur even for transformations yielding algebraic surfaces, or higher-dimensional algebraic varieties. 相似文献