全文获取类型
收费全文 | 2670篇 |
免费 | 271篇 |
国内免费 | 269篇 |
专业分类
化学 | 998篇 |
晶体学 | 21篇 |
力学 | 196篇 |
综合类 | 43篇 |
数学 | 1475篇 |
物理学 | 477篇 |
出版年
2024年 | 5篇 |
2023年 | 34篇 |
2022年 | 73篇 |
2021年 | 69篇 |
2020年 | 101篇 |
2019年 | 93篇 |
2018年 | 92篇 |
2017年 | 100篇 |
2016年 | 110篇 |
2015年 | 104篇 |
2014年 | 147篇 |
2013年 | 246篇 |
2012年 | 141篇 |
2011年 | 158篇 |
2010年 | 136篇 |
2009年 | 161篇 |
2008年 | 176篇 |
2007年 | 159篇 |
2006年 | 150篇 |
2005年 | 145篇 |
2004年 | 107篇 |
2003年 | 99篇 |
2002年 | 88篇 |
2001年 | 79篇 |
2000年 | 73篇 |
1999年 | 58篇 |
1998年 | 63篇 |
1997年 | 42篇 |
1996年 | 26篇 |
1995年 | 25篇 |
1994年 | 22篇 |
1993年 | 22篇 |
1992年 | 12篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 6篇 |
1984年 | 11篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有3210条查询结果,搜索用时 15 毫秒
1.
不完全信息群体决策专家权重的集结 总被引:8,自引:5,他引:3
本文对于属性权重信息和属性效用信息都不完全的群体多属性决策问题,通过构造属性值区间和运用系统聚类分析法,对群体决策中的专家进行分类,并确定每位专家的权重. 相似文献
2.
《Magnetic resonance in chemistry : MRC》2003,41(6):417-430
A systematic study of the one‐bond and long‐range J(C,C), J(C,H) and J(H,H) in the series of nine bicycloalkanes was performed at the SOPPA level with special emphasis on the coupling transmission mechanisms at bridgeheads. Many unknown couplings were predicted with high reliability. Further refinement of SOPPA computational scheme adjusted for better performance was carried out using bicyclo[1.1.1]pentane as a benchmark to investigate the influence of geometry, basis set and electronic correlation. The calculations performed demonstrated that classical ab initio SOPPA applied with the locally dense Dunning's sets augmented with inner core s‐functions used for coupled carbons and Sauer's sets augmented with tight s‐functions used for coupled hydrogens performs perfectly well in reproducing experimental values of different types of coupling constants (the estimated reliability is ca 1–2 Hz) in relatively large organic molecules of up to 11 carbon atoms. Additive coupling increments were derived for J(C,C), J(C,H) and J(H,H) based on the calculated values of coupling constants within SOPPA in the model bicycloalkanes, in reasonably good agreement with the known values obtained earlier on pure empirical grounds. Most of the bridgehead couplings in all but one bicycloalkane appeared to be essentially additive within ca 2–3 Hz while bicyclo[1.1.1]pentane demonstrated dramatic non‐additivity of ?14.5 Hz for J(C,C), +16.6 Hz for J(H,H) and ?5.5 Hz for J(C,H), in line with previous findings. Non‐additivity effects in the latter compound established at the SOPPA level should be attributed to the through‐space non‐bonded interactions at bridgeheads due to the essential overlapping of the bridgehead rear lobes which provides an additional and effective non‐bonding coupling path for the bridgehead carbons and their protons in the bicyclopentane framework. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
3.
Deborah M. Greaves 《国际流体数值方法杂志》2006,50(6):693-711
An adaptive hierarchical grid‐based method for predicting complex free surface flows is used to simulate collapse of a water column. Adapting quadtree grids are combined with a high‐resolution interface‐capturing approach and pressure‐based coupling of the Navier–Stokes equations. The Navier–Stokes flow solution scheme is verified for simulation of flow in a lid‐driven cavity at Re=1000. Two approaches to the coupling of the Navier–Stokes equations are investigated as are alternative face velocity and hanging node interpolations. Collapse of a water column as well as collapse of a water column and its subsequent interaction with an obstacle are simulated. The calculations are made on uniform and adapting quadtree grids, and the accuracy of the quadtree calculations is shown to be the same as those made on the equivalent uniform grids. Results are in excellent agreement with experimental and other numerical data. A sharp interface is maintained at the free surface. The new adapting quadtree‐based method achieves a considerable saving in the size of the computational grid and CPU time in comparison with calculations made on equivalent uniform grids. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
4.
Stefan Weigert 《Czechoslovak Journal of Physics》2004,54(1):147-149
The eigenstates of a diagonalizable PT-symmetric Hamiltonian satisfy unconventional completeness and orthonormality relations. These relations reflect the properties of a pair of bi-orthonormal bases associated with non-hermitean diagonalizable operators. In a similar vein, such a dual pair of bases is shown to possess, in the presence of PT symmetry, a Gram matrix of a particular structure: its inverse is obtained by simply swapping the signs of some its matrix elements. 相似文献
5.
Katsunari Inoue Kazuaki Kato Norimitsu Tohnai Mikiji Miyata 《Journal of polymer science. Part A, Polymer chemistry》2004,42(18):4648-4655
We studied simulations by computer graphics to estimate the steric mechanism of the asymmetric polymerization of prochiral diene monomers in channels of inclusion compounds of steroidal bile acids, such as deoxycholic acid (DCA) and cholic acid. We applied a hierarchization method to interpret the crystal structures of bile acids, clarifying that the chiral host molecules associated to form characteristic 21-helical assemblies with uneven surfaces. A detailed analysis of the uneven channels in a close-packing state indicated that there were many possible arrangements of the monomers in the channels. The plausible arrangements in the channel could explain a previous study, which showed that the polymerization in the DCA channel yielded chiral polymers with a predominant configuration from prochiral diene monomers, such as 2-methyl-trans-1,3-pentadiene. On the basis of such simulation studies of the arrangements of guest monomers in the channel, we examined a plausible steric mechanism for asymmetric inclusion polymerization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4648–4655, 2004 相似文献
6.
多小波子空间上的单小波表示 总被引:1,自引:0,他引:1
本文在较弱的条件下,建立了2重多小波子空间与单小波子空间的关系.即由2重多小波构造出单小波.一方面,这种单小波的平移伸缩与2重多小波的平移伸缩生成的子空间是完全相同的;另一方面,它具有插值性.因此通过构造出的单小波建立了多小波子空间上的Shannon型采样定理. 相似文献
7.
Banach空间上的框架与Riesz基 总被引:5,自引:0,他引:5
本文讨论Banach空间上框架、无冗框架与Riesz基之间的关系及它们的稳定性. 相似文献
8.
9.
Steen Ryom-Hansen 《Journal of Algebraic Combinatorics》2006,23(1):5-20
We generalize Soergel's tilting algorithm to singular weights and deduce from this the validity of the Lascoux-Leclerc-Thibon
conjecture on the connection between the canonical basis of the basic submodule of the Fock module and the representation
theory of the Hecke-algebras at root of unity.
Supported in part by Programa Reticulados y Ecuaciones and by FONDECYT grant 1051024. 相似文献
10.
J. J. EGOZCUE J. L. DIAZ-BARRERO V. PAWLOWSKY-GLAHN 《数学学报(英文版)》2006,22(4):1175-1182
The set of probability functions is a convex subset of L1 and it does not have a linear space structure when using ordinary sum and multiplication by real constants. Moreover, difficulties arise when dealing with distances between densities. The crucial point is that usual distances are not invariant under relevant transformations of densities. To overcome these limitations, Aitchison's ideas on compositional data analysis are used, generalizing perturbation and power transformation, as well as the Aitchison inner product, to operations on probability density functions with support on a finite interval. With these operations at hand, it is shown that the set of bounded probability density functions on finite intervals is a pre-Hilbert space. A Hilbert space of densities, whose logarithm is square-integrable, is obtained as the natural completion of the pre-Hilbert space. 相似文献