首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6856篇
  免费   977篇
  国内免费   555篇
化学   2723篇
晶体学   1153篇
力学   476篇
综合类   122篇
数学   1681篇
物理学   2233篇
  2024年   7篇
  2023年   68篇
  2022年   166篇
  2021年   205篇
  2020年   221篇
  2019年   173篇
  2018年   128篇
  2017年   196篇
  2016年   308篇
  2015年   225篇
  2014年   362篇
  2013年   492篇
  2012年   379篇
  2011年   510篇
  2010年   461篇
  2009年   457篇
  2008年   489篇
  2007年   513篇
  2006年   474篇
  2005年   385篇
  2004年   344篇
  2003年   282篇
  2002年   203篇
  2001年   172篇
  2000年   185篇
  1999年   146篇
  1998年   136篇
  1997年   135篇
  1996年   82篇
  1995年   68篇
  1994年   64篇
  1993年   51篇
  1992年   47篇
  1991年   50篇
  1990年   39篇
  1989年   27篇
  1988年   29篇
  1987年   16篇
  1986年   14篇
  1985年   16篇
  1984年   14篇
  1983年   8篇
  1982年   7篇
  1981年   7篇
  1980年   3篇
  1979年   3篇
  1978年   3篇
  1977年   4篇
  1973年   2篇
  1959年   2篇
排序方式: 共有8388条查询结果,搜索用时 15 毫秒
1.
2.
New aromatic (co)polyesters containing pendant propargyloxy groups were synthesized by phase transfer‐catalyzed interfacial polycondensation of 5‐(propargyloxy)isophthaloyl chloride (P‐IPC) and various compositions of P‐IPC and isophthaloyl chloride with bisphenol A. FTIR and NMR spectroscopic data, respectively, revealed successful incorporation of pendant propargyloxy groups into (co)polyesters and formation of (co)polyesters with desired compositions. (Co)polyesters exhibited good solubility in common organic solvents such as chloroform, dichloromethane, and tetrahydrofuran and could be cast into transparent, flexible, and tough films from chloroform solution. Inherent viscosities and number average molecular weights of (co)polyesters were in the range 0.77–1.33 dL/g and 43,600–118,000 g/mol, respectively, indicating the achievement of reasonably high‐molecular weights. The 10% weight loss temperatures of (co)polyesters were in the range 390–420 °C, demonstrating their good thermal stability. (Co)polyesters exhibited Tg in the range 146–170 °C and Tg values decreased with increase in mol % incorporation of P‐IPC. The study of non‐isothermal curing by DSC indicated thermal crosslinking of (co)polyesters via propargyloxy groups. The utility of pendant propargyloxy group was demonstrated by post‐modification of the selected copolyester with 1‐(4‐azidobutyl)pyrene, 9‐(azidomethyl)anthracene, and azido‐terminated poly(ethyleneglycol) monomethyl ether via copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition reaction. FTIR and 1H NMR spectra confirmed that click reaction was quantitative. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 588–597  相似文献   
3.
This paper reports that the growth of RuOx(110) thin layer growth on Ru(0001) has been investigated by means of scanning tunnelling microscope (STM). The STM images showed a domain structure with three rotational domains of RuOx(110) rotated by an angle of 120℃. The as-grown RuOx(110) thin layer is expanded from the bulk-truncated RuOx(110) due to the large mismatch between RuOx(110) and the Ru(0001) substrate. The results also indicate that growth of RuOx(110) thin layer on the Ru(0001) substrate by oxidation tends first to formation of the Ru-O (oxygen) chains in the [001] direction of RuOx(110).  相似文献   
4.
余军扬 《数学杂志》2002,22(1):74-78
本文给出Riccati方程及另外一类具有代表性微分方程的亚纯解(n,1)级的上界估计,在一定条件下确立了文[2]中的猜测的正确性。  相似文献   
5.
Relying on reliability growth testing to improve system designis neither usually effective nor efficient. Instead it is importantto design in reliability. This requires models to estimate reliabilitygrowth in the design that can be used to assess whether goalreliability will be achieved within the target timescale forthe design process. Many models have been developed for analysisof reliability growth on test, but there has been much lessattention given to reliability growth in design. This paperdescribes and compares two models: one motivated by the practicalengineering process; the other by extending the reasoning ofstatistical reliability growth modelling. Both models are referencedin the recently revised edition of international standard IEC61164. However, there has been no reported evaluation of theirproperties. Therefore, this paper explores the commonalitiesand differences between these models through an assessment oftheir logic and their application to an industrial example.Recommendations are given for the use of reliability growthmodels to aid management of the design process and to informproduct development.  相似文献   
6.
研究了具有开发的单种群非自治周期系统.利用非自治微分方程理论.以及变分法理论和泛函极值的Euler方程方法,得到了该开发系统的持续生存性.周期解存在性,全局渐近稳定性.研究了在开发情况下的最大收获量问题,以及取得最大经济效益下的收获问题等.  相似文献   
7.
对弱相对论性电子束驱动的回旋激射(maser)不稳定性的一般理论作了详细讨论.对在获得增长率实用表达式过程中若干解析表达式的推导与细节做了仔细的补充讨论和说明,还增加了增长率的近似表达式,并由此得到了回旋激射不稳定性主要特征的解析分析以及与精确计算的比较,使整个理论有一个完整的描述.侧重解析讨论,也提供了部分一般性的数值计算结果. 关键词: 回旋激射不稳定性 弱相对论性电子束 增长率  相似文献   
8.
9.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007  相似文献   
10.
There is a growing interest in developing numerical tools to investigate the onset of physical instabilities observed in experiments involving viscoelastic flows, which is a difficult and challenging task as the simulations are very sensitive to numerical instabilities. Following a recent linear stability analysis carried out in order to better understand qualitatively the origin of numerical instabilities occurring in the simulation of flows viscoelastic fluids, the present paper considers a possible extension for more complex flows. This promising method could be applied to track instabilities in complex (i.e. essentially non‐parallel) flows. In addition, results related to transient growth mechanism indicate that it might be responsible for the development of numerical instabilities in the simulation of viscoelastic fluids. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号