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Yoshio Hoei 《Journal of Macromolecular Science: Physics》2013,52(1):190-198
A complete equation of the swelling activity parameter (S) as a function of swelling deformation (λs ) is derived by using a non-Gaussian elastic network model, including a tube concept and the Flory–Rehner model, and by following McKenna's criterion that takes into account the disparity between the Flory–Huggins interaction parameters for cross-linked and uncross-linked polymers. However, only a part of tube at the network chain size scale is extended to that for a large-scale structure according to the “gel tensile blob” model for equilibrium swollen networks. This approach is basically best for the “ideal regular network + simple structured good-solvent” binary systems due to its model character. As a result, it reproduces well the literature data of S versus λs 2 with a maximum/inflection measured for such actual systems. 相似文献
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A 3D lemniscate is an implicitly given surface which generalizes the well-known Bernoulli lemniscates curves and the Cassini ovals in 2D. It is characterized by placing a finite number of points in space (the foci) and choosing a constant (radius), its algebraic degree is twice the number of foci and it is always contained in the union of certain spheres centered at the foci. The distribution of the foci gives a rough idea of the 3D shapes that could be modeled with any of the connected components of the lemniscate. The position of the foci can be used to stretch and to produce knoblike features. Given a set of foci, for a small radius the lemniscate consists of a number of spherelike surfaces centered at the foci which do not touch each other. As the radius increases the disconnected pieces coalesce producing interesting surfaces. In order to make 3D lemniscates a potentially useful primitive for CAGD it is necessary to control the coalescing/splitting of the connected components of the lemniscate while we move the foci and change the radius, simultaneously. In this paper we offer tools towards this control. We look closely at the case of four noncoplanar foci.
AMS subject classification 65D05, 65D17, 65D18This work was partially supported by grant G97 000651 of Fonacit, Venezuela. 相似文献
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