全文获取类型
收费全文 | 13984篇 |
免费 | 1273篇 |
国内免费 | 683篇 |
专业分类
化学 | 2075篇 |
晶体学 | 22篇 |
力学 | 2673篇 |
综合类 | 250篇 |
数学 | 8783篇 |
物理学 | 2137篇 |
出版年
2024年 | 21篇 |
2023年 | 90篇 |
2022年 | 227篇 |
2021年 | 270篇 |
2020年 | 329篇 |
2019年 | 279篇 |
2018年 | 303篇 |
2017年 | 380篇 |
2016年 | 427篇 |
2015年 | 346篇 |
2014年 | 573篇 |
2013年 | 869篇 |
2012年 | 769篇 |
2011年 | 649篇 |
2010年 | 610篇 |
2009年 | 762篇 |
2008年 | 782篇 |
2007年 | 852篇 |
2006年 | 702篇 |
2005年 | 624篇 |
2004年 | 524篇 |
2003年 | 536篇 |
2002年 | 471篇 |
2001年 | 424篇 |
2000年 | 444篇 |
1999年 | 380篇 |
1998年 | 333篇 |
1997年 | 298篇 |
1996年 | 329篇 |
1995年 | 293篇 |
1994年 | 220篇 |
1993年 | 213篇 |
1992年 | 208篇 |
1991年 | 177篇 |
1990年 | 153篇 |
1989年 | 105篇 |
1988年 | 135篇 |
1987年 | 94篇 |
1986年 | 103篇 |
1985年 | 133篇 |
1984年 | 94篇 |
1983年 | 26篇 |
1982年 | 71篇 |
1981年 | 51篇 |
1980年 | 39篇 |
1979年 | 30篇 |
1978年 | 55篇 |
1977年 | 47篇 |
1976年 | 30篇 |
1957年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
1.
2.
Erosion and sediments transport processes have a great impact on industrial structures and on water quality. Despite its limitations, the Saint‐Venant‐Exner system is still (and for sure for some years) widely used in industrial codes to model the bedload sediment transport. In practice, its numerical resolution is mostly handled by a splitting technique that allows a weak coupling between hydraulic and morphodynamic distinct softwares but may suffer from important stability issues. In recent works, many authors proposed alternative methods based on a strong coupling that cure this problem but are not so trivial to implement in an industrial context. In this work, we then pursue 2 objectives. First, we propose a very simple scheme based on an approximate Riemann solver, respecting the strong coupling framework, and we demonstrate its stability and accuracy through a number of numerical test cases. However, second, we reinterpret our scheme as a splitting technique and we extend the purpose to propose what should be the minimal coupling that ensures the stability of the global numerical process in industrial codes, at least, when dealing with collocated finite volume method. The resulting splitting method is, up to our knowledge, the only one for which stability properties are fully demonstrated. 相似文献
3.
The structure and rotational barrier for the mesityl-silicon bond of 2,2-dimesityl-1,1,1,3,3,3-hexamethyltrisilane have been investigated by 1H- and 13C-variable temperature nuclear magnetic resonance (NMR) as well as by density functional theory structural calculations. The calculations show that the lowest energy structure has C2 symmetry with nonequivalent ortho methyl groups, consistent with the crystal structure and solution NMR. The nonequivalent ortho methyl groups exchange through a Cs transition state with a calculated relative free energy of 11.0 kcal mol−1. The barrier for this rotation found by dynamic NMR is 13.4 ± 0.2 kcal mol−1 at 298 K. 相似文献
4.
Dr. Liat Avram Dr. Václav Havel Ronit Shusterman-Krush Dr. Mark A. Iron Dr. Moritz Zaiss Prof. Vladimír Šindelář Dr. Amnon Bar-Shir 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1687-1690
The accumulated knowledge regarding molecular architectures is based on established, reliable, and accessible analytical tools that provide robust structural and functional information on assemblies. However, both the dynamicity and low population of noncovalently interacting moieties within studied molecular systems limit the efficiency and accuracy of traditional methods. Herein, the use of a saturation transfer-based NMR approach to study the dynamic binding characteristics of an anion to a series of synthetic receptors derived from bambusuril macrocycles is demonstrated. The exchange rates of BF4− are mediated by the side chains on the receptor (100 s−1<kex<5000 s−1), which play a critical role in receptor-anion binding dynamics. The signal amplification obtained with this approach allows for the identification of different types of intermolecular interactions between the receptor and the anion, something that could not have been detected by techniques hitherto used to study molecular assemblies. These findings, which are supported by a computational molecular dynamic study, demonstrate the uniqueness and added value of this NMR method. 相似文献
5.
In this paper, we consider a viscoelastic wave equation of variable coefficients in the presence of past history with nonlinear damping and delay in the internal feedback and dynamic boundary conditions. Under suitable assumptions, we establish an explicit and general decay rate result without imposing restrictive assumption on the behavior of the relaxation function at infinity by Riemannian geometry method and Lyapunov functional method. 相似文献
6.
G. Montero L. Gonzlez E. Flrez M. D. García A. Surez 《Numerical Linear Algebra with Applications》2002,9(3):239-247
Parallel preconditioners are presented for the solution of general linear systems of equations. The computation of these preconditioners is achieved by orthogonal projections related to the Frobenius inner product. So, minM∈??∥AM?I∥ F and matrix M0∈?? corresponding to this minimum (?? being any vectorial subspace of ??n(?)) are explicitly computed using accumulative formulae in order to reduce computational cost when subspace ?? is extended to another one containing it. Every step, the computation is carried out taking advantage of the previous one, what considerably reduces the amount of work. These general results are illustrated with the subspace of matrices M such that AM is symmetric. The main application is developed for the subspace of matrices with a given sparsity pattern which may be constructed iteratively by augmenting the set of non‐zero entries in each column. Finally, the effectiveness of the sparse preconditioners is illustrated with some numerical experiments. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
7.
电路过渡过程所列方程是微分方程,本文中采用的是方框图模型分析法,即将微分方程的复杂示解分解成最基本的加(减)、乘(除)、积分(微分)、增益等运算,采用VB设计用户界面产进行计算,并给出了一算例。 相似文献
8.
In a previous paper (Ref. 1), an exact solution of the optimal planar interception with fixed end conditions was derived in closed form. The optimal control was expressed as an explicit function of the state variables and two fixed parameters, obtained by solving a set of nonlinear algebraic equations involving elliptic integrals. In order to facilitate the optimal control implementation, the present paper derives a highly accurate simplified solution assuming that the ratio of the pursuer turning radius to the initial range is small. An asymptotic expansion further reduces the computational workload. Construction of a near-optimal open-loop control, based on the approximations, completes the present paper. 相似文献
9.
V. Dzhunushaliev 《Foundations of Physics》2002,32(7):1069-1090
An approximate model of a spacetime foam is presented. It is supposed that in the spacetime foam each quantum handle is like to an electric dipole and therefore the spacetime foam is similar to a dielectric. If we neglect of linear sizes of the quantum handle then it can be described with an operator containing a Grassman number and either a scalar or a spinor field. For both fields the Lagrangian is presented. For the scalar field it is the dilaton gravity + electrodynamics and the dilaton field is a dielectric permeability. The spherically symmetric solution in this case give us the screening of a bare electric charge surrounded by a polarized spacetime foam and the energy of the electric field becomes finite one. In the case of the spinor field the spherically symmetric solution give us a ball of the polarized spacetime foam filled with the confined electric field. It is shown that the full energy of the electric field in the ball can be very big. 相似文献
10.
M. M. Kostreva 《Journal of Optimization Theory and Applications》1989,62(1):63-76
Murty's algorithm for the linear complementarity problem is generalized to solve the optimality conditions for linear and convex quadratic programming problems with both equality and inequality constraints. An implementation is suggested which provides both efficiency and tight error control. Numerical experiments as well as field tests in various applications show favorable results.The author thanks K. G. Murty for his encouragement and helpful comments. 相似文献