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A slab optical waveguide (SOWG) has been used for study of adsorption of both methylene blue (MB) and new methylene blue (NMB) in liquid–solid interface. Adsorption characteristics of MB and NMB on both bare SOWG and silanized SOWG by octadecyltrichlorosilane (ODS) were compared. Effect of pH on adsorption on MB and NMB was investigated. Binding rate constant analysis showed that both MB and NMB on bare SOWG demonstrates larger association constants than those on ODS-SOWG. Interactions of MB and NMB on bare SOWG and ODS-SOWG were analyzed by molecular mechanics calculation method. The binding energy change was in the following order: ENMB–bare > EMB–bare > ENMB–ODS > EMB–ODS. 相似文献
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转移矩阵法在负折射率介质材料平板波导中的应用研究 总被引:3,自引:3,他引:0
利用严格电磁理论,推导出了适用于负折射率介质材料光波导的转移矩阵,分析讨论了转移矩阵的性质和应用.利用转移矩阵方法,推导出导波层为负折射率介质材料、覆盖层和衬底为右手材料的三层对称介质光波导的本征色散方程.用图解法研究了负折射率介质波导中TE波的异常色散特性.在负折射材料介质波导中没有零阶模,最低阶为1阶模,并且有截止频率,只有波导参量满足一定条件的时候才会存在,导模的横向波数可以为实数和纯虚数,而正折射率介质波导导模的横向波数只能为实数. 相似文献
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关于左手性介质几何光学的研究(一) 总被引:2,自引:1,他引:1
根据几何光学中的费马原理和完善成像原理研究了光线经过正负折射率界面时的传播特性,推导了单负折射率完善成像的曲面方程,讨论了单块负折射率透镜成像特性的一些缺陷及改进方案,依此指出了最短时间原理的适用范围的局限性和利用左手性介质制作光学器件的优越性,为进一步研究左手性介质的光学特性和相关光学器件设计提供了理论基础. 相似文献
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Dikshitulu K. Kalluri Joo Hwa Lee Monzurul M. Ehsan 《International Journal of Infrared and Millimeter Waves》2003,24(3):349-365
This paper deals with the Finite Difference Time Domain (FDTD) simulation of interaction of an electromagnetic wave with a switched plasma slab. In formulating the simulation the well-known concepts of (a) total-field/scattered-field formulation (b) and PML lattice truncation are adapted to suit the simulation under consideration.FDTD is particularly well suited to handle the switched (time-varying) medium (including sudden switching) since the time varying parameters of the medium can be easily interpreted in the algorithm. The technique is applied to the difficult problem of interaction of an electromagnetic pulse source wave of frequency 0 and a gaussian envelope with a newly created plasma slab of time-varying and space varying electron density profile. The creation of a pulse of Wiggler magnetic field in the slab is illustrated. 相似文献
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Self-avoiding walk models of a polymer confined between two parallel attractive walls in two and three dimensions (slits and
slabs, respectively) have recently had a revival of interest. They were first studied as simple models of steric stabilisation
and sensitised flocculation in colloids. The revival has been catalysed by new exact solution techniques, that have allowed
the solution of directed walk models in two dimensions in full generality, and by new Monte Carlo techniques that have allowed
the simulation of the full parameter space in the three-dimensional slab model. Additionally, rigorous techniques applied
to the slab problem have also yielded new results. The contributions to the study of this problem that have been recently
added include a novel phase diagram for the “infinite-slab” (when the walls are a macroscopic distance apart but both walls
may still “see” the polymer) the delineation of the repulsive and attractive regimes of the parameter space, and a conjectured
scaling theory for the problem in general dimensions. 相似文献
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Hiroki Hotta Kazuya Tatsuno Yoji Hattori Takuya Hashimoto Masayuki Uehara Kin-ichi Tsunoda 《Electrochemistry communications》2008,10(9):1351-1354
The H+ concentration change was monitored near an electrode surface through an electrolysis using a slab optical waveguide technique. Indium tin oxide transparent electrode modified by porous insulating polymer to which methyl red was covalently immobilized was used as a guiding layer, and the absorbance change of the polymer film was monitored. H+ generation at the vicinity of the electrode through the oxidation of ascorbic acid could be monitored by this technique. 相似文献
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The control of flow in a tundish is important for improving the quality of the steel. Dams, Wiers and Pouring chamber are some of the devices used for controlling the flow in the tundish. The investigation about the role of electromagnetic forces as a replacement for these devices is an objective for the present work. Thus, 3-D MHD simulation was performed to study the effect of electromagnetic forces on flow behaviour in the tundish. The MHD model developed for carrying out the simulation was validated with the analytical solution of the Hartman problem. The results obtained shows improvement in the desired characteristics for inclusion flotataion with magnetic flow modifier of optimum strength of magnetic field. 相似文献
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Li-Xian Sun A.Mahipal Reddy Akiko Takatsu Tatsuhiro Okada 《Analytica chimica acta》2003,487(1):109-116
A slab optical waveguide (SOWG) has been used for study of adsorption of both methylene blue (MB) and new methylene blue (NMB) in liquid-solid interface. Adsorption characteristics of MB and NMB on both bare SOWG and silanized SOWG by octadecyltrichlorosilane (ODS) were compared. The simultaneous determinations of both MB and NMB were explored by flow injection SOWG spectrophotometric analysis and artificial neural networks (ANNs) for the first time. Concentrations of MB and NMB were estimated simultaneously with the ANNs. Results obtained with SOWG were compared with those got by conventional UV-visible spectrophotometry. 相似文献
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David Fuks Dina Shapiro Arnold Kiv Vyacheslav Golovanov Chung‐Chiun Liu 《International journal of quantum chemistry》2011,111(9):1902-1906
A slab approach in the framework of ab initio calculations was applied to study surface electronic states in In2O3 crystal. Density functional theory (DFT) calculations were carried out employing the WIEN 2k code and using the full potential method with Augmented Plane Waves + local orbitals (APW+lo) formalism. Total and partial DOS (Density of States) were calculated for In and O atoms in two upper (110) surface layers. Comparison of total and partial DOS allowed determining a contribution of electronic states of different In and O surface atoms into formation of surface electronic spectra and corresponding chemical bonds. A dominant ionic character of chemical bonds in In2O3 is found. Calculations were performed for three slab models with different geometry parameters. It was shown that an optimal ratio between the whole vertical size of a supercell and the vertical size of atomic cluster has to be chosen. The size of vacuum region in the slab model influences significantly on the reliability of calculated characteristics of the surface electronic structure. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献