Redox behavior of juglone in buffered aq.: Ethanol media

The present work reports the redox mechanism of 5-hydroxynaphthalene-1,4-dione (HND), commonly known as juglone, in buffered aqueous media having 50% of ethanol. HND followed different mechanistic routes depending upon the pH of the media and more than one pK_a were evaluated from the changes in the slope of the E_p vs. pH plot. The change of pH from acidic to neutral conditions was found to switch the mechanism from CEC to EE mechanism. Pulse techniques were utilized to determine the number of electrons involved in the oxidation and/or the reduction step and to ensure the nature of the redox process. Based upon the obtained results, an electrode reaction mechanism was proposed. Computational studies of HND supported the experimental results. UV-Visible spectroscopy was also employed for the detailed characterization of the compound in a wide range of pH and for the determination of its pK_a.     

Modified quasi-reversibility method for final value problems in Banach spaces

This paper is concerned with the final value problem associated with a linear operator A in a Banach space, where −A is the generator of a uniformly bounded analytic semigroup. Based on the deLaubenfels' functional calculus, we use new quasi-reversibility method, introduced by Boussetila and Rebbani recently, to form an approximate problem. We obtain some results in a Banach space similar to those in a Hilbert space.     

A comparison of regularizations for an ill-posed problem

We consider numerical methods for a ``quasi-boundary value' regularization of the backward parabolic problem given by

where is positive self-adjoint and unbounded. The regularization, due to Clark and Oppenheimer, perturbs the final value by adding , where is a small parameter. We show how this leads very naturally to a reformulation of the problem as a second-kind Fredholm integral equation, which can be very easily approximated using methods previously developed by Ames and Epperson. Error estimates and examples are provided. We also compare the regularization used here with that from Ames and Epperson.

We consider numerical methods for a ``quasi-boundary value' regularization of the backward parabolic problem given by

where is positive self-adjoint and unbounded. The regularization, due to Clark and Oppenheimer, perturbs the final value by adding , where is a small parameter. We show how this leads very naturally to a reformulation of the problem as a second-kind Fredholm integral equation, which can be very easily approximated using methods previously developed by Ames and Epperson. Error estimates and examples are provided. We also compare the regularization used here with that from Ames and Epperson.

     

On a backward parabolic problem with local Lipschitz source

We consider the regularization of the backward in time problem for a nonlinear parabolic equation in the form _ut+Au(t)=f(u(t),t)$u_t+Au(t)=f(u(t),t)$, u(1)=φ$u(1)=\phi$, where A is a positive self-adjoint unbounded operator and f is a local Lipschitz function. As known, it is ill-posed and occurs in applied mathematics, e.g. in neurophysiological modeling of large nerve cell systems with action potential f   in mathematical biology. A new version of quasi-reversibility method is described. We show that the regularized problem (with a regularization parameter β>0$\beta >0$) is well-posed and that its solution _Uβ(t)$U_{\beta }(t)$ converges on [0,1]$[0,1]$ to the exact solution u(t)$u(t)$ as β→0⁺$\beta \to 0^{+}$. These results extend some earlier works on the nonlinear backward problem.     

Regularization for Ill-posed Cauchy problems associated with generators of analytic semigroups

This paper is concerned with the ill-posed Cauchy problem associated with a densely defined linear operator A in a Banach space. Our main result is that if −A is the generator of an analytic semigroup, then there exists a family of regularizing operators for such an ill-posed Cauchy problem by using the quasi-reversibility method, fractional powers and semigroups of linear operators. The applications to ill-posed partial differential equations are also given.     

On a quasi-reversibility regularization method for a Cauchy problem of the Helmholtz equation

In this paper, we consider the Cauchy problem for the Helmholtz equation in a rectangle, where the Cauchy data is given for y=0 and boundary data are for x=0 and x=π. The solution is sought in the interval 0<y≤1. A quasi-reversibility method is applied to formulate regularized solutions which are stably convergent to the exact one with explicit error estimates.     

On an inverse problem: Recovery of non-smooth solutions to backward heat equation

We have recently developed two quasi-reversibility techniques in combination with Euler and Crank–Nicolson schemes and applied successfully to solve for smooth solutions of backward heat equation. In this paper, we test the viability of using these techniques to recover non-smooth solutions of backward heat equation. In particular, we numerically integrate the backward heat equation with smooth initial data up to a time of singularity (corners and discontinuities) formation. Using three examples, it is shown that the numerical solutions are very good smooth approximations to these singular exact solutions. The errors are shown using pseudo-L- and U-curves and compared where available with existing works. The limitations of these methods in terms of time of simulation and accuracy with emphasis on the precise set of numerical parameters suitable for producing smooth approximations are discussed. This paper also provides an opportunity to gain some insight into developing more sophisticated filtering techniques that can produce the fine-scale features (singularities) of the final solutions. Techniques are general and can be applied to many problems of scientific and technological interests.     

Notes on a new approximate solution of 2-D heat equation backward in time

In this paper, we consider a backward heat problem that appears in many applications. This problem is ill-posed. The solution of the problem as the solution exhibits unstable dependence on the given data functions. Using a new regularization method, we regularize the problem and get some new error estimates. Some numerical tests illustrate that the proposed method is feasible and effective. This work is a generalization of many recent papers, including the earlier paper [A new regularized method for two dimensional nonhomogeneous backward heat problem, Appl. Math. Comput. 215(3) (2009) 873–880] and some other authors such as Chu-Li Fu et al. ,  and , Campbell et al. [4].