卷烟主流烟气中巴豆醛在线光谱分析方法研究

卷烟主流烟气是卷烟燃烧时被人体吸食到体内的主要气体,其减焦降害已成为全社会高度关注的问题。在各种卷烟主流烟气组分中,巴豆醛以其强烈的基因毒性,成为国家规定的卷烟中七种主要有害指标物之一。传统的巴豆醛分析方法大都采用高效液相色谱法等实验室分析方法,需繁琐的样品前处理过程,无法测量巴豆醛的实时浓度,难以准确评估巴豆醛对人体健康的影响。为了快速、准确地检测卷烟主流烟气中的巴豆醛组分,本研究搭建了一套可以直接与吸烟机耦合的傅里叶红外光谱分析系统（FTIR）,并创新性开发过采样数据驱动光谱分析方法（ODDSA）,从复杂、变动的卷烟主流烟气中准确提取巴豆醛的光谱组分信息。ODDSA方法从实验设计入手,采用随机设计的思路尽可能模拟实际卷烟样品的分布范围,以构建具备良好光谱数据结构的样品集。在此基础上,创新性地将高密度小波变换引入红外光谱数据的处理过程中,以时/频双域过采样的方式提升了光谱解析分辨率,进而降低了其他基质组分对巴豆醛光谱信息的干扰。最后,发展改良竞争自适应重加权采样方法,从多倍冗余的高密度小波系数中准确提取待测物质的最佳变量组合,由此构建高质量的巴豆醛光谱定量分析模型。为了验证ODDSA方法的有效性,实验中采集了15种典型市售卷烟品牌,每个品牌在线采集8支样品的主流烟气红外光谱,随后采用随机挑选的25个验证集样本对ODDSA方法进行验证。结果表明,检验集的线性拟合系数为0.971,相对均方根误差为5.5%,其预测精度能有效满足卷烟主流烟气中巴豆醛的在线分析需求,并可拓展到环境二手烟气中其他组分的在线监测,进而为吸烟与健康评估提供全新手段。     

Sampling and recovery of multidimensional bandlimited functions via frames

In this paper, we investigate frames for L₂d[−π,π] consisting of exponential functions in connection to oversampling and nonuniform sampling of bandlimited functions. We derive a multidimensional nonuniform oversampling formula for bandlimited functions with a fairly general frequency domain. The stability of said formula under various perturbations in the sampled data is investigated, and a computationally manageable simplification of the main oversampling theorem is given. Also, a generalization of Kadec's 1/4 theorem to higher dimensions is considered. Finally, the developed techniques are used to approximate biorthogonal functions of particular exponential Riesz bases for L₂[−π,π], and a well-known theorem of Levinson is recovered as a corollary.     

A multiscale cell boundary element method for elliptic problems

In this paper we introduce the multiscale cell boundary element method (MsCBE method). The method is obtained by applying the oversampling technique of the MsFEM by Hou and Wu [T.Y. Hou, X.H. Wu, A multiscale finite element method for elliptic problems in composite materials and porous media, J. Comput. Phys. 134 (1997) 169–189] to the newly developed numerical method, the cell boundary element(CBE) method by the author and his colleagues. The advantage of the MsCBE method is that it preserves flux exactly on arbitrary subdomain without needing the dual mesh. A complete H¹ convergence analysis and numerical examples confirming our analysis are presented.     

Generalized Shift-Invariant Systems

A countable collection $X$ of functions in $L_2(\mbox{\footnotesize\bf R})$ is said to be a Bessel system if the associated analysis operator $$ \txs{X}:L_2(\mbox{\smallbf R}^d)\to \ell_2(X) : f\mapsto (\inpro{f,x})_{x\in X} $$ is well-defined and bounded. A Bessel system is a fundamental frame if $\txs{X}$ is injective and its range is closed. This paper considers the above two properties for a generalized shift-invariant system $X$. By definition, such a system has the form $$ X=\bigcup_{j\in J} Y_j, $$ where each $Y_j$ is a shift-invariant system (i.e., is comprised of lattice translates of some function(s)) and $J$ is a countable (or finite) index set. The definition is general enough to include wavelet systems, shift-invariant systems, Gabor systems, and many variations of wavelet systems such as quasi-affine ones and nonstationary ones. The main theme of this paper is the fiberization of $\txs{X}$, which allows one to study the frame and Bessel properties of $X$ via the spectral properties of a collection of finite-order Hermitian nonnegative matrices.     

Increased torque transducer sensitivity via oversampling

The sensitivity of a commercial torque transducer under oscillatory shear conditions is extended by about a factor 3–5 into the small torque region. This increased sensitivity is a result of a straightforward data treatment in the time domain termed “on the fly oversampling”. This method is enabled by the emergence of modern ADC-cards. The underlying ideas of oversampling together with a first experimental verification of this method are described in detail. Received: 22 August 2000 Accepted: 14 November 2000     

Determining under- and oversampling of individual particle distributions in microfluidic electrophoresis with orthogonal laser-induced fluorescence detection

This report investigates the effects of sample size on the separation and analysis of individual biological particles using microfluidic devices equipped with an orthogonal LIF detector. A detection limit of 17 +/- 1 molecules of fluorophore is obtained using this orthogonal LIF detector under a constant flow of fluorescein, which is a significant improvement over epifluorescence, the most common LIF detection scheme used with microfluidic devices. Mitochondria from rat liver tissue and cultured 143B osteosarcoma cells are used as model biological particles. Quantile-quantile (q-q) plots were used to investigate changes in the distributions. When the number of detected mitochondrial events became too large (>72 for rat liver and >98 for 143B mitochondria), oversampling occurs. Statistical overlap theory is used to suggest that the cause of oversampling is that separation power of the microfluidic device presented is not enough to adequately separate large numbers of individual mitochondrial events. Fortunately, q-q plots make it possible to identify and exclude these distributions from data analysis. Additionally, when the number of detected events became too small (<55 for rat liver and <81 for 143B mitochondria) there were not enough events to obtain a statistically relevant mobility distribution, but these distributions can be combined to obtain a statistically relevant electrophoretic mobility distribution.     

New insights into churn prediction in the telecommunication sector: A profit driven data mining approach

Customer churn prediction models aim to indicate the customers with the highest propensity to attrite, allowing to improve the efficiency of customer retention campaigns and to reduce the costs associated with churn. Although cost reduction is their prime objective, churn prediction models are typically evaluated using statistically based performance measures, resulting in suboptimal model selection. Therefore, in the first part of this paper, a novel, profit centric performance measure is developed, by calculating the maximum profit that can be generated by including the optimal fraction of customers with the highest predicted probabilities to attrite in a retention campaign. The novel measure selects the optimal model and fraction of customers to include, yielding a significant increase in profits compared to statistical measures.In the second part an extensive benchmarking experiment is conducted, evaluating various classification techniques applied on eleven real-life data sets from telecom operators worldwide by using both the profit centric and statistically based performance measures. The experimental results show that a small number of variables suffices to predict churn with high accuracy, and that oversampling generally does not improve the performance significantly. Finally, a large group of classifiers is found to yield comparable performance.     

Abschätzung der Normen von Operatoren analytischer Funktionen

This article investigates the norms of certain interpolation operators of analytic functions on the unit disc. In particular, it is shown that the norms of interpolation operators being the identical operator for all n -degree polynomials have a lower bound of order ln n . This result is compared with a recent result regarding trigonometric interpolation of continuous functions on the unit circle. It is shown that opposed to the operators of analytic functions on the unit disc, the method of oversampling can be applied in order to uniformly bound the interpolation operators. Moreover, some practical implications with regard to communication engineering are discussed. It is concluded that in practice the results lead to non-linear interpolation operators.     

核磁共振谱仪数字接收机的原理与实现

核磁共振波谱仪射频系统数字化是现代核磁谱仪的发展方向,用数字检波技术代替模拟正交检波是数字接收机的一项新技术.本文在分析模拟正交检波原理与不足的基础上,介绍了数字正交检波、过采样和采用中频直接采样的原理,及在400MHz核磁谱仪上的实现方案.