全文获取类型
收费全文 | 1822篇 |
免费 | 44篇 |
国内免费 | 96篇 |
专业分类
化学 | 783篇 |
晶体学 | 1篇 |
力学 | 142篇 |
综合类 | 7篇 |
数学 | 829篇 |
物理学 | 200篇 |
出版年
2023年 | 15篇 |
2022年 | 18篇 |
2021年 | 16篇 |
2020年 | 12篇 |
2019年 | 23篇 |
2018年 | 14篇 |
2017年 | 20篇 |
2016年 | 18篇 |
2015年 | 26篇 |
2014年 | 48篇 |
2013年 | 157篇 |
2012年 | 60篇 |
2011年 | 80篇 |
2010年 | 50篇 |
2009年 | 80篇 |
2008年 | 62篇 |
2007年 | 80篇 |
2006年 | 57篇 |
2005年 | 60篇 |
2004年 | 53篇 |
2003年 | 36篇 |
2002年 | 581篇 |
2001年 | 76篇 |
2000年 | 34篇 |
1999年 | 32篇 |
1998年 | 32篇 |
1997年 | 28篇 |
1996年 | 23篇 |
1995年 | 23篇 |
1994年 | 12篇 |
1993年 | 23篇 |
1992年 | 16篇 |
1991年 | 12篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 8篇 |
1985年 | 7篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 9篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1976年 | 6篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有1962条查询结果,搜索用时 15 毫秒
1.
Nagendranath Mahata V. Vishwanathan 《Journal of molecular catalysis. A, Chemical》1997,120(1-3):267-270
Kinetics of vapor phase hydrogenation of phenol to cyclohexanone over Pd/MgO system has been studied in a flow microreactor under normal atmospheric pressure. The reaction rate is found to be negative order with respect to the partial pressure of phenol and has increased from −0.5 to 0.5 with increasing temperature (473 to 563 K). The apparent activation energy (Ea) of the process is found to be close to 65 kJ per mol. On the basis of kinetic results a surface mechanism is proposed. 相似文献
2.
Exact closed-form solutions are exhibited for the Hopf equation for stationary incompressible 3D Navier-Stokes flow, for the cases of homogeneous forced flow (including a solution with depleted nonlinearity) and inhomogeneous flow with arbitrary boundary conditions. This provides an exact method for computing two- and higher-point moments, given the mean flow. 相似文献
3.
A graph G is N2‐locally connected if for every vertex ν in G, the edges not incident with ν but having at least one end adjacent to ν in G induce a connected graph. In 1990, Ryjá?ek conjectured that every 3‐connected N2‐locally connected claw‐free graph is Hamiltonian. This conjecture is proved in this note. © 2004 Wiley Periodicals, Inc. J Graph Theory 48: 142–146, 2005 相似文献
4.
A theorem of Birkhoff‐Frink asserts that every algebraic closure operator on an ordinary set arises, from some algebraic structure on the set, as the corresponding generated subalgebra operator. However, for many‐sorted sets, i.e., indexed families of sets, such a theorem is not longer true without qualification. We characterize the corresponding many‐sorted closure operators as precisely the uniform algebraic operators. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
5.
Juan Pablo Vielma 《Operations Research Letters》2007,35(1):29-35
Two independent proofs of the polyhedrality of the split closure of mixed integer linear program have been previously presented. Unfortunately neither of these proofs is constructive. In this paper, we present a constructive version of this proof. We also show that split cuts dominate a family of inequalities introduced by Köppe and Weismantel. 相似文献
6.
Joseph Y.-T. Leung 《Discrete Applied Mathematics》2007,155(8):945-970
We consider the problem of scheduling orders for multiple different product types in an environment with m dedicated machines in parallel. The objective is to minimize the total weighted completion time. Each product type is produced by one and only one of the m dedicated machines; that is, each machine is dedicated to a specific product type. Each order has a weight and may also have a release date. Each order asks for certain amounts of various different product types. The different products for an order can be produced concurrently. Preemptions are not allowed. Even when all orders are available at time 0, the problem has been shown to be strongly NP-hard for any fixed number (?2) of machines. This paper focuses on the design and analysis of efficient heuristics for the case without release dates. Occasionally, however, we extend our results to the case with release dates. The heuristics considered include some that have already been proposed in the literature as well as several new ones. They include various static and dynamic priority rules as well as two more sophisticated LP-based algorithms. We analyze the performance bounds of the priority rules and of the algorithms and present also an in-depth comparative analysis of the various rules and algorithms. The conclusions from this empirical analysis provide insights into the trade-offs with regard to solution quality, speed, and memory space. 相似文献
7.
The Efficient Determination Criterion (EDC) generalizes the AIC and BIC criteria and provides a class of consistent estimators
for the order of a Markov chain with finite state space. In this note, we derive rates of convergence for the EDC estimates.
*Partially supported by CNPq, CAPES/PROCAD, FAPDF/PRONEX, FINATEC and FUNPE/UnB.
**Partially supported by CAPES. 相似文献
8.
9.
On the properties of solutions to the Goursat-Darboux problem with boundary and distributed controls
N. I. Pogodaev 《Siberian Mathematical Journal》2007,48(5):897-912
We consider a control system described by the Goursat-Darboux equation. The system is controlled by distributed and boundary controls. The controls are subject to the constraints given as multivalued mappings with closed, possibly nonconvex, values depending on the phase variable. Alongside the initial constraints, we consider the convexified constraints and the constraints whose values are the extreme points of the convexified constraints. We study the questions of existence of solutions and establish connections between the solutions under various constraints. 相似文献
10.
H. Sakuma T. Taniyama K. Ishii Y. Kitamoto Y. Yamazaki 《Journal of magnetism and magnetic materials》2006,300(2):284-292
The order parameter S of Fe–Pt nanoparticles is estimated from X-ray diffraction (XRD) patterns. The total intensity of a diffraction peak is obtained by Rietveld analysis as well as simply integrating the intensity. The Rietveld analysis is found to provide a plausible value of S even for a sample showing an XRD pattern with broad and overlapped peaks. Another order parameter Q, which is obtained from Mössbauer spectra, is introduced, and it is confirmed that Q is equivalent to the probability of Fe atoms being in the L10-type atomic arrangement. The coercivity of Fe–Pt nanoparticles is directly proportional to Q, while it vanishes at S=0.4, indicating that the magnetic property of Fe–Pt nanoparticles has a closer relationship to Q than S. 相似文献