全文获取类型
收费全文 | 3447篇 |
免费 | 385篇 |
国内免费 | 373篇 |
专业分类
化学 | 804篇 |
晶体学 | 18篇 |
力学 | 129篇 |
综合类 | 88篇 |
数学 | 2318篇 |
物理学 | 848篇 |
出版年
2024年 | 7篇 |
2023年 | 40篇 |
2022年 | 56篇 |
2021年 | 72篇 |
2020年 | 103篇 |
2019年 | 119篇 |
2018年 | 113篇 |
2017年 | 99篇 |
2016年 | 102篇 |
2015年 | 95篇 |
2014年 | 143篇 |
2013年 | 308篇 |
2012年 | 156篇 |
2011年 | 170篇 |
2010年 | 161篇 |
2009年 | 193篇 |
2008年 | 214篇 |
2007年 | 209篇 |
2006年 | 224篇 |
2005年 | 206篇 |
2004年 | 181篇 |
2003年 | 177篇 |
2002年 | 151篇 |
2001年 | 118篇 |
2000年 | 119篇 |
1999年 | 133篇 |
1998年 | 105篇 |
1997年 | 82篇 |
1996年 | 53篇 |
1995年 | 42篇 |
1994年 | 32篇 |
1993年 | 31篇 |
1992年 | 21篇 |
1991年 | 14篇 |
1990年 | 14篇 |
1989年 | 19篇 |
1988年 | 16篇 |
1987年 | 11篇 |
1986年 | 11篇 |
1985年 | 15篇 |
1984年 | 9篇 |
1983年 | 5篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 11篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 5篇 |
排序方式: 共有4205条查询结果,搜索用时 62 毫秒
1.
Recyclable and reusable Pd(OAc)2/PPh3/PEG‐2000 system for homocoupling reaction of arylboronic acids under air without base
下载免费PDF全文
![点击此处可从《应用有机金属化学》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A stable and efficient Pd(OAc)2/PPh3/PEG‐2000 catalytic system for homocoupling of arylboronic acids has been developed. In the presence of Pd(OAc)2 and PPh3, the homocoupling reaction of arylboronic acids was carried out smoothly in PEG‐2000 at 70 °C under air without base to afford a variety of symmetric biaryls in good to excellent yields. The isolation of the products was readily performed by extraction with diethyl ether, and the Pd(OAc)2/PPh3/PEG‐2000 system could be easily recycled and reused six times without significant loss of catalytic activity. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
2.
Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis
Dr. Damien Dambournet Dr. Karena W Chapman Dr. Mathieu Duttine Dr. Olaf Borkiewicz Dr. Peter J Chupas Dr. Henri Groult 《ChemistryOpen》2015,4(4):443-447
The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties. 相似文献
3.
G. Montero L. Gonzlez E. Flrez M. D. García A. Surez 《Numerical Linear Algebra with Applications》2002,9(3):239-247
Parallel preconditioners are presented for the solution of general linear systems of equations. The computation of these preconditioners is achieved by orthogonal projections related to the Frobenius inner product. So, minM∈??∥AM?I∥ F and matrix M0∈?? corresponding to this minimum (?? being any vectorial subspace of ??n(?)) are explicitly computed using accumulative formulae in order to reduce computational cost when subspace ?? is extended to another one containing it. Every step, the computation is carried out taking advantage of the previous one, what considerably reduces the amount of work. These general results are illustrated with the subspace of matrices M such that AM is symmetric. The main application is developed for the subspace of matrices with a given sparsity pattern which may be constructed iteratively by augmenting the set of non‐zero entries in each column. Finally, the effectiveness of the sparse preconditioners is illustrated with some numerical experiments. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
4.
Volker Elling. 《Mathematics of Computation》2006,75(256):1721-1733
A particular case of initial data for the two-dimensional Euler equations is studied numerically. The results show that the Godunov method does not always converge to the physical solution, at least not on feasible grids. Moreover, they suggest that entropy solutions (in the weak entropy inequality sense) are not well posed.
5.
P. Le Bars 《Journal of Combinatorial Theory, Series A》2006,113(8):1771-1782
The aggregate error locator is defined and a computation method is given. The aggregate error locator is then used in a type of Forney algorithm to compute the error values in the received words of a Ca,b algebraic geometry code. 相似文献
6.
Huafei Sun 《Geometriae Dedicata》2002,90(1):63-75
We study minimal submanifolds in the locally symmetric and conformally flat Riemannian manifold and generalize Yau's result obtained in J. Amer. Math. 97 (1975), 76–100. 相似文献
7.
S. K. Godunov V. T. Zhukov O. B. Feodoritova 《Computational Mathematics and Mathematical Physics》2006,46(6):971-982
An algorithm is constructed for calculating invariant subspaces of symmetric hyperbolic systems arising in electromagnetic, acoustic, and elasticity problems. Discrete approximations are calculated for subspaces that correspond to minimal eigenvalues and smooth eigenfunctions. Difficulties related to the presence of an infinite-dimensional kernel in the differential operator are successfully handled. The efficiency of the algorithm is demonstrated using acoustics equations. 相似文献
8.
9.
A new method is presented for the determination of Ricci Collineations (RC) and Matter Collineations (MC) of a given spacetime, in the cases where the Ricci tensor and the energy momentum tensor are non-degenerate and have a similar form with the metric. This method reduces the problem of finding the RCs and the MCs to that of determining the KVs whereas at the same time uses already known results on the motions of the metric. We employ this method to determine all hypersurface homogeneous locally rotationally symmetric spacetimes, which admit proper RCs and MCs. We also give the corresponding collineation vectors. These results conclude a long due open problem, which has been considered many times partially in the literature. 相似文献
10.
HUA Jianjun LIU Yanhong & ZHANG Zhihe . Institute of Physics Chinese Academy of Sciences Beijing China . College of Biomedical Engineering Capital University of Medical Sciences Beijing China Correspondence should be addressed to Hua Jianjun 《中国科学G辑(英文版)》2004,(1)
Adustyplasmacanbedefinedasacomplicatedplasmacontainingsmallsolidmattercalleddustgrainsordustparticles,whichareusuallychargednegatively,duetoelectronshighermobilitythanion,bycollectingelectronsandionsfromthebackgroundplasma.Theuniverseisfilledwithdustyplasmassuchasplanetaryrings,comettails,andnebulae.Also,inindustrialplasmaprocessing,particulatessuspendedinplasmaarethemajorcontaminationinsemiconductormanufacture.Studiesondustyplasmahavebeenextendedtofar-flungtopicssuchaswaves,instabilities,stro… 相似文献