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1.
[Na(18-C-6)]2[Cu(i-mnt)2]的合成与结构分析 总被引:2,自引:2,他引:0
研究了18-冠-6与Na2[Cu(i-mnt)2][i-mnt=异丁二腈烯二硫醇阴离子,S2CC(CN)2-2]的反应,得到的配合物[Na(18-C-6)]2[Cu(i-mnt)2](1)通过元素分析、红外光谱、X射线单晶衍射进行了结构分析.配合物为单斜晶系,空间群P2(1)/c.晶体学结构数据a=1.2819(11),b=1.1793(10),c=1.4928(13)nm,β=99.121(16)°,V=2.228(3)nm3,Z=2,Dcaled.=1.369g/cm3,F(000)=958,R1=0.0521,wR2=0.1003.1中的[Cu(i-mnt)2]基团通过配体i-mnt的氮原子与两个[Na(18-C-6)]基团中的钠原子成键,形成稳定的中性配合物. 相似文献
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3.
A probe-corrected theory based on complex point sources is presented for computing the acoustic field of an arbitrary finite source from measurements of the near field on a cylindrical scanning surface. The complex point sources are used both as basis functions for the expansion of the field outside the scan cylinder and for the representation of the probe. The resulting probe-corrected formulas are considerably simpler than the standard probe-corrected formulas based on cylindrical waves. The new formulation makes simulations of near-field scanning systems much less computationally intensive than simulations based on standard theory. The complex point-source theory is validated through numerical examples involving a baffled circular piston transducer probe. 相似文献
4.
Luiza Amália Moraes Luis Romero Grados 《Journal of Mathematical Analysis and Applications》2003,281(2):575-586
Let Au(BG) be the Banach algebra of all complex valued functions defined on the closed unit ball BG of a complex Banach space G which are uniformly continuous on BG and holomorphic in the interior of BG, endowed with the sup norm. A characterization of the boundaries for Au(BG) is given in case G belongs to a class of Banach spaces that includes the pre-dual of a Lorentz sequence space studied by Gowers in Israel J. Math. 69 (1990) 129-151. The non-existence of the Shilov boundary for Au(BG) is also proved. 相似文献
5.
Mauno Rnkk 《Nonlinear Analysis: Hybrid Systems》2007,1(4):560-576
In this paper, we discuss modelling and analysis of hybrid systems with physical interaction dynamics. Such systems are typically considered complex and they are modelled using abstractions. Abstractions may, however, unintentionally exclude critical details, leading to partial or false results. Therefore, we study here use of a particle system in modelling and analysis. The novelty of the particle system is that it is designed to reveal interaction dynamics as emergent dynamics; thus, supporting analysis of complex and intricate interaction dynamics with acceptable modelling effort. As the main contribution, we formalize the particle system, and use it to model and analyze hybrid systems, both mechanical and biological, with nontrivial interaction dynamics. 相似文献
6.
本文得到复流形局部q-凸楔形上(r,s)型微分形式的带权的同伦公式和(r,s)型的方程的带权的连续解,并给出(r,s)型微分形式的不含边界积分的新的带权的同伦公式和(r,s)型的方程的新的带权的连续解.这些新的带权公式尤其适用于具有非光滑边界的局部q-凸楔形,这时不但可以避免边界积分的复杂估计,而且积分密度也不必在边界有定义,只要在区域上有定义就行.其次,引进权因子,带权的积分公式在应用上(比如在函数的插值方面)具有更大的灵活性. 相似文献
7.
Naoki Murabayashi 《Journal of Number Theory》2004,108(2):268-286
The purpose of this paper is to decide the conditions under which a CM elliptic curve is modular over its field of definition. 相似文献
8.
该文用顺磁离子对其近邻~(13)C核的NMR吸收增宽效应,系统地研究了抗坏血酸在不同溶剂中对金属离子Mn~(2+)、Gd~(3+)的配合行为.在水溶液中,抗坏血酸可通过两种配合方式与Mn~(2+)作用,但与Gd~(3+)的作用只有一种稳定的结构.在水中抗坏血酸对金属的配位活性部位分别是1位羟基氧,3位离解的羟基氧和6位羟基氧.在DMSO中,3位羟基由于H~+对该基团的静电遮蔽而变得对金属离子Mn~(2+)表现为配位惰性,同时6位羟基配位活性较大增强.对Gd~(3+)来说,此时没有优势配位活性部位存在.文章还讨论了抗坏血酸在H_2O-DMSO混合溶剂中的~(13)C NMR谱及在DMSO中NaOH对其~(13)C NMR谱及其与金属络合结构的影响. 相似文献
9.
J.-L. Garden 《Thermochimica Acta》2007,452(2):85-105
What is really measured in dynamic calorimetric experiments is still an open question. This paper is devoted to this question, which can be usefully envisaged by means of macroscopic non-equilibrium thermodynamics. From the pioneer work of De Donder on chemical reactions and with other authors along the 20th century, the question is tackled under an historical point of view. A special attention is paid about the notions of frequency dependent complex heat capacity and entropy production due to irreversible processes occurring during an experiment. This phenomenological approach based on thermodynamics, not widely spread in the literature of calorimetry, could open significant perspectives on the study of macro-systems undergoing physico-chemical transformations probed by dynamic calorimetry. 相似文献
10.
Manicka Dhanasekar Jianjun Han Qinghua Qin 《Finite Elements in Analysis and Design》2006,42(14-15):1314-1323
Much work on special elements that simplify geometrical modelling of structures containing holes, cracks and/ or inclusions has been reported extensively in the literature. This paper presents a hybrid-Trefftz element containing elliptic hole formulated using Hellinger–Reissner principle by employing trial functions based on the mapping technique and the Cauchy integral method. The element presented in this paper could be regarded as an improved formulation over Piltner [Special finite elements with holes and internal cracks, Int. J. Numer. Methods Eng. 21 (1985) 1471–1485] element because the chosen trail functions in this paper have provided relatively more stable solutions. The use of the element with other ordinary displacement-based finite elements has also yielded very accurate solutions even when very coarse meshes relative to the size of the elliptic hole have been used. 相似文献