C_(60)离子束撞击固体表面的坍塌沉积(Ⅰ)共焦显微拉曼光谱研究

为了研究C60的结构特性，我们最近在实验中将加这后的C60离子束沉积在固体表面，对其沉积后的形态进行了共焦显微拉曼光谱的表征．在记录的光谱中已检测不出C60原有的特征谱问，说明C60离子在高速憧击固体表面后，已经完全失去了原有的球状构型．C60的t）［R实验在自制的串级飞     

Relationship between the radial dynamics and the chemical production of a harmonically driven spherical bubble

The sonochemical activity and the radial dynamics of a harmonically excited spherical bubble are investigated numerically. A detailed model is employed capable to calculate the chemical production inside the bubble placed in water that is saturated with oxygen. Parameter studies are performed with the control parameters of the pressure amplitude, the forcing frequency and the bubble size. Three different definitions of collapse strengths (extracted from the radius vs. time curves) are examined and compared with the chemical output of various species. A mathematical formula is established to estimate the chemical output as a function of the collapse strength; thus, the chemical activity can be predicted without taking into account the chemical kinetics into the bubble model. The calculations are carried out by an in-house code exploiting the high processing power of professional graphics cards (GPUs).The results shown that chemical activity can be approximated qualitatively from the values of relative expansion. This could be helpful in order to optimise chemical output of sonochemical reactors either from measurement data or simulations as well.     

C60离子束撞击固体表面的坍塌与沉积(II)扫描隧道显微研究

Mass-selected C60 beam produced by laser ablation was accelerated and bombarded the (0001) surface of highly oriented pyrolitic graphite and (111) surface of gold single crystal. The samples were characterized by STM. The STM images showed that, the deposited species collapsed and formed planar structure on the solid surface, but the collapsed species were not dissociated and well oriented on the surface. Both positive and negative C60 ions were observed in the desorption mass spectra, confirming that the species collapsed on the solid surface are still the C60 clusters.     

About collapse and revivals of two quantum oscillators in off-resonance interaction

The off-resonance effect and its influence on the reversibility between two quantum subsystems in interaction (single mode cavity field and a three-level atom in cascade configuration) are studied. The partial restoration condition is found at which these radiators can restore their diagonal moments, while the non-diagonal ones remain correlated after the interaction process.     

Effect of non-associated electrolyte solutions on the behaviour of poly(vinyl alcohol)-based hydrogels

The aim of this paper is to present the behaviour of the poly(vinyl alcohol) hydrogels [PVA-HG] in sodium and potassium chlorides aqueous solutions, due to their interactions. The tested [PVA-HG]-s have been obtained by repeated freezing and thawing cycles. White, heterogeneous hydrogels have been obtained. These hydrogels exhibit a mechanical active behaviour at their contact with electrolytes aqueous solutions, manifested by important changing in mass, volume and density of the hydrogel samples. These modifications could be explained by water elimination from the hydrogels that initially reached the equilibrium of swelling. The kinetic of the water desorption and the reversibility of this process, have been studied and some of the factors that influence this behaviour have been evidenced. The sensitivity of PVA hydrogels to electrolyte nature and concentration could be used in sensors design and also could explain some aspects of electrolytes diffusion through PVA membranes and targeted drugs delivery.     

Drug-loaded nano/microbubbles for combining ultrasonography and targeted chemotherapy

A new class of multifunctional nanoparticles that combine properties of polymeric drug carriers, ultrasound imaging contrast agents, and enhancers of ultrasound-mediated drug delivery has been developed. At room temperature, the developed systems comprise perfluorocarbon nanodroplets stabilized by the walls made of biodegradable block copolymers. Upon heating to physiological temperatures, the nanodroplets convert into nano/microbubbles. The phase state of the systems and bubble size may be controlled by the copolymer/perfluorocarbon volume ratio. Upon intravenous injections, a long-lasting, strong and selective ultrasound contrast is observed in the tumor volume indicating nanobubble extravasation through the defective tumor microvasculature, suggesting their coalescence into larger, highly echogenic microbubbles in the tumor tissue. Under the action of tumor-directed ultrasound, microbubbles cavitate and collapse resulting in a release of the encapsulated drug and dramatically enhanced intracellular drug uptake by the tumor cells. This effect is tumor-selective; no accumulation of echogenic microbubbles is observed in other organs. Effective chemotherapy of the MDA MB231 breast cancer tumors has been achieved using this technique.     

Visualisation and les simulation of cavitation cloud formation and collapse in an axisymmetric geometry

Visualisation and Large Eddy Simulations (LES) of cavitation inside the apparatus previously developed by Franc (2011) for surface erosion acceleration tests and material response monitoring are presented. The experimental flow configuration is a steady-state closed loop flow circuit where pressurised water, flowing through a cylindrical feed nozzle, is forced to turn 90° and then, move radially between two flat plates towards the exit of the device. High speed images show that cavitation is forming at the round exit of the feed nozzle. The cavitation cloud then grows in the radial direction until it reaches a maximum distance where it collapses. Due to the complexity of the flow field, direct observation of the flow structures was not possible, however vortex shedding is inferred from relevant simulations performed for the same conditions. Despite the axisymmetric geometry utilized, instantaneous pictures of cavitation indicate variations in the circumferential direction. Image post-processing has been used to characterize in more detail the phenomenon. In particular, the mean cavitation appearance and the cavity length have been estimated, showing good correlation with the erosion zone. This also coincides with the locations of the maximum values of the standard deviation of cavitation presence. The dominant frequency of the ‘large-scale’ cavitation clouds has been estimated through FFT. Cloud collapse frequencies vary almost linearly between 200 and 2000 Hz as function of the cavitation number and the downstream pressure. It seems that the increase of the Reynolds number leads to a reduction of the collapse frequency; it is believed that this effect is due to the agglomeration of vortex cavities, which causes a decrease of the apparent frequency. The results presented here can be utilized for validation of relevant cavitation erosion models which are currently under development.     

Numerical investigation of the effect of dual frequency sonication on stable bubble dynamics

A computational study aiming to simulate an oxygen single acoustic bubble oscillation under a dual-frequency sonication was presented in this paper. The non-linear response of the bubble to the superposition of two fields of ultrasonic waves was investigated through dynamics parameters, collapse ratios and average velocities. The main goal of this analyze is to link the properties of the wave resulting from the dual-frequency excitation to the dynamics behavior of the bubble. The obtained results prove that, in contrast with the mono-frequency, coupling a wave to lower frequencies enhances the collapse duration and raises the compression ratio in the case of 35 kHz, while associating any of the studied waves to a higher frequency elevates the number of bubble oscillations during a time interval as compared to mono-frequency. The total sonochemical production has been investigated in accordance with the dynamics results, as well as the proportions of the three predominant free radicals, that show a dependency on the value of the basic frequency.