全文获取类型
收费全文 | 1382篇 |
免费 | 275篇 |
国内免费 | 258篇 |
专业分类
化学 | 859篇 |
力学 | 65篇 |
综合类 | 79篇 |
数学 | 320篇 |
物理学 | 592篇 |
出版年
2023年 | 17篇 |
2022年 | 41篇 |
2021年 | 42篇 |
2020年 | 26篇 |
2019年 | 3篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 3篇 |
2015年 | 6篇 |
2014年 | 333篇 |
2013年 | 298篇 |
2012年 | 149篇 |
2011年 | 265篇 |
2010年 | 212篇 |
2009年 | 221篇 |
2008年 | 114篇 |
2007年 | 40篇 |
2006年 | 15篇 |
2005年 | 12篇 |
2004年 | 24篇 |
2003年 | 8篇 |
2002年 | 11篇 |
2001年 | 3篇 |
2000年 | 12篇 |
1999年 | 9篇 |
1998年 | 16篇 |
1997年 | 9篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1992年 | 2篇 |
1977年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有1915条查询结果,搜索用时 15 毫秒
1.
2.
对氧碘化学激光器的单重态氧发生器(SOG)进行了改进,采用横向射流方式,并对该横向射流式单重态氧发生器的性能进行了检测。实验中过氧化氢碱溶液温度控制在-16℃左右,氯气流量为530mmol/s,He与氯气的流量比为3;采用PS法测量单重态氧分子的产率,吸收法测量氯气的利用率和相对水含量。得出如下结论:在不使用冷阱和分离器的情况下,最高单重态氧分子产率达到58%, 氯气利用率在80%以上,相对水含量小于等于0.5;气体达到最大流量时,发生器仍然能稳定地工作。 相似文献
3.
Lai Chunhui 《东北数学》1997,(1)
SomePropertiesofQuasi┐keep┐rangeOperatorsandTheirApplicationsLaiChunhui(赖春晖)(DepartmentofMathematics,ZhangzhouTeachersColege,... 相似文献
4.
与q形变玻色算符逆算符相关的相干态及其量子统计性质 总被引:1,自引:1,他引:0
讨论了q形变玻色算符的广义逆算符作用于q-相干态所得到的两类量子态的数学及量子统计性质。结果表明,q-相干态的光子激发态不存在压缩但呈现反聚束效应,而q-相干态的光子湮灭态却存在压缩但不呈现反聚束效应。 相似文献
5.
In this paper, the authors deal with bifunctions defined on complete metric spaces and with values in locally convex spaces ordered by closed convex cones. The aim is to provide a vector version of Ekeland’s theorem related to equilibrium problems. To prove this principle, a weak notion of continuity of a vector-valued function is considered, and some of its properties are presented. Via the vector Ekeland’s principle, existence results for vector equilibria are proved in both compact and noncompact domains. 相似文献
6.
This paper proposes a method for estimation of a class of partially linear single-index models with randomly censored samples. The method provides a flexible way for modelling the association between a response and a set of predictor variables when the response variable is randomly censored. It presents a technique for “dimension reduction” in semiparametric censored regression models and generalizes the existing accelerated failure-time models for survival analysis. The estimation procedure involves three stages: first, transform the censored data into synthetic data or pseudo-responses unbiasedly; second, obtain quasi-likelihood estimates of the regression coefficients in both linear and single-index components by an iteratively algorithm; finally, estimate the unknown nonparametric regression function using techniques for univariate censored nonparametric regression. The estimators for the regression coefficients are shown to be jointly root-n consistent and asymptotically normal. In addition, the estimator for the unknown regression function is a local linear kernel regression estimator and can be estimated with the same efficiency as all the parameters are known. Monte Carlo simulations are conducted to illustrate the proposed methodology. 相似文献
7.
8.
Transition between layered and filamentary types of anisotropy in layered superconducting structures
D. A. Kuptsov 《Annalen der Physik》1992,504(4):296-301
A model of layered superconducting structure consisting of alternating anisotropic superconducting layers S1 and S2 with different transition temperatures is considered. It is shown that due to competition between two origins of anisotropy - effective-mass anisotropy of individual layers and proximity-induced anisotropy the effective anisotropy of the whole system signficiantly varies temperature. The components of the effective-mass tensor mc (along the anisotropy axis) and ma (perpendicular to the anisotropy axis) strongly depend upon temperature. This may lead to transition between layered (mc > ma) and quasi one-dimensional (mc < ma) types of anisotropy as well as to biaxial-type anisotropy which is also temperature dependent. The field distribution in a tilted vortex in a biaxial superconductor is calculated. The change in the properties of the vortex lattice with temperature in such systems is also investigated. The properties of YBa2Cu3Ox/PrBa2Cu3Oy multilayers are discussed in this connection. 相似文献
9.
A copper(Ⅱ) complex 1 of a novel macrocyclic polyamine ligand with hydroxylethyl pendant groups, 4,11-bis(hydroxylethyl)-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L) has been synthesized and characterized. Rate enhancement for hydrolysis of p-nitrophenyl picolinate (PNPP) catalyzed by 1 was studied kinetically under Brij35 micellar condition. For comparision, the catalytic activity of corresponding copper(Ⅱ) complex 2 of non-substituted macrocyclic polyamine ligand, 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraaza-cyclotetradecane (L') toward the hydrolysis of PNPP was also investigated. The results indicate that the macrocyclic polyamine copper(Ⅱ) complex 1 effectively catalyzed the hydrolysis of PNPP, and the pendant ligand hydroxyl group or deprotonated pendant ligand hydroxyl group can act as catalytically active species in the reaction. A ternary Complex kinetic model involving metal ion, ligand and substrate has been proposed, and the results confirmed the reasonability of such kinetic model. 相似文献
10.
1991年Decher等将带相反电荷的聚电解质 ,于水溶液中交替沉积在片基上 ,制备了多层超薄膜[1] ,这种制膜方法现称为静电自组装 .它操作简单 ,无需专用设备 ;一般在水体系进行 ,对环境友好 ;静电力比范德华力强 ,使它比LB膜稳定 ,所以近年来有很大发展[2 ] .现在自组装成膜驱动力已从静电力扩展到氢键力、电荷转移相互作用、疏水相互作用等 ,用于组装的组分也从聚电解质扩展到多官能团小分子、胶体粒子、无机纳米颗粒 ,DNA、蛋白质等生物大分子等[3~ 11] .虽然自组装膜比LB膜稳定 ,但它也不耐极性溶剂、电解质水溶液等侵蚀 .如… 相似文献