Crystal Structures of Two Potential Tumor Imaging Agents and Therapeutic Agents Copper（Ⅱ） Ternary Complexes with Salicylidene-tyrosinato Schiff Base and Nitrogen-donor Chelating Lewis Base

The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents.     

Penta-Coordinate Phosphorus Intermediates Analysis on Phospho-related Proteins

In this paper, based on known crystal structures of square pyramid （SP） and trigonal bipyramid （TBP） penta coordinated phosphorus compounds containing amino acid side chains, such as amino, carboxyl, hydroxyl or thiol, a software for survey the P（5）-structure of phosphorylated proteins was derived. By this software, it was found that 382 of 398 phosphorus related kinases （96%） from current PDB could go through the penta-coordinated phosphorus transition state or intermediate.     

锥体棱镜的加工

本文简单地叙述了锥体棱镜两种加工工艺。重点介绍直接成型法加工中对角度误差~1″的控制。并提出了角度超差零件返修时的光胶方法。     

从入射面检测锥体棱镜直角误差的方法

介绍了一种应用激光平面干涉仪从入射面检测锥体棱镜直角误差的方法。棱镜被测角通过一个夹具被预置一个初始角,使射入棱镜内的测试平行光垂直于被测角棱,经被测直角的两个面反射后形成全反射光路,当射出的光与测试平行光重合时产生干涉,实现对锥体棱镜直角误差的测量。介绍了测量、干涉条纹图形分析和直角误差计算的方法,并与传统检测方法进行了比较。结果表明,该方法具有操作简单、测量准确、计算精度高等特点,适合于高精度锥体棱镜(α≤3″)的直角误差测量。     

碳量子点在八面双锥和纳米片TiO2上的光催化

依次用溶剂热法和水热法制备得到暴露(101)晶面的八面双锥体二氧化钛OBP-TiO2和不同碳负载量的N-CDs/OBP-TiO2复合催化剂,以及暴露(001)晶面的纳米片二氧化钛TNS和不同碳负载量的N-CDs/TNS复合催化剂。利用TEM、XRD、XPS等表征手段对这2类复合催化剂的形貌结构、化学成分等作了鉴定。系统研究了碳量子点负载量对可见光降解RhB的光催化性能影响。实验发现,由于N-CDs的加入,均能较大提高2类复合催化剂的光催化性能。(101)高裸露晶面N-CDs/OBP-TiO2比(001)高裸露晶面N-CDs/TNS的光催化活性高。     

基于Voronoi切割算法的碎冰区构造及离散元分析

离散元方法广泛应用于海冰,特别是碎冰区的动力过程及其对海洋结构作用过程的数值模拟。为构造碎冰区中的冰块几何特性,基于二维Voronoi图方法对计算域进行随机切割以生成碎冰区中冰块的几何形态,并采用球体单元对每个碎冰块单元进行填充,从而确定碎冰区的初始分布场。在采用Voronoi图进行碎冰区构造时,可对冰块尺寸、几何形态和密集度等海冰参数进行设定。为确定冰块的不同几何规则度,综合采用排斥法和扰动法以定量地控制碎冰块几何形态从完全随机分布到规则分布的连续变换。为分析不同几何规则度下碎冰块的几何特性概率分布规律,对计算域内冰块的面积和边数等参数进行统计分析,从而可更合理地参数化控制初始冰场中碎冰块的几何特性。在此基础上,本文基于粘接-破碎的球体离散元方法对不同冰况下锥体结构的冰荷载进行了数值计算,讨论分析了碎冰区的海冰密集度、冰块面积和几何规则度对冰载荷的影响。     

基于COMSOL软件下截锥体电阻的计算

本文应用Comsol软件讨论了截锥体内电势和电流的分布,并计算了截锥体的电阻.     

Associative Cones and Integrable Systems

Abstract We identify ℝ⁷ as the pure imaginary part of octonions. Then the multiplication in octonions gives a natural almost complex structure for the unit sphere S⁶. It is known that a cone over a surface M in S⁶ is an associative submanifold of ℝ⁷ if and only if M is almost complex in S⁶. In this paper, we show that the Gauss-Codazzi equation for almost complex curves in S⁶ are the equation for primitive maps associated to the 6-symmetric space G₂=T², and use this to explain some of the known results. Moreover, the equation for S¹-symmetric almost complex curves in S⁶ is the periodic Toda lattice, and a discussion of periodic solutions is given. (Dedicated to the memory of Shiing-Shen Chern) * Partially supported by NSF grant DMS-0529756.     

掺镱双包层光纤激光器的径向偏振振荡

通过在腔内放置汇聚型布儒斯特角轴锥体,并对增益光纤采用双端泵浦, 实验上实现了掺镱双包层光纤激光器的径向偏振模振荡.对增益光纤的末端做了斜角抛光,抑制了光纤端面间的寄生振荡,减小了在低泵浦功率下被放大的自发辐射光份额.该激光器的域值约为175 mW,斜率效率13.8%,激发波长约1085 nm.当泵浦功率达到最大值460 mW时,获得了39 mW的激光输出功率,其光束偏振纯度和圆柱形对称性有显著改善.     

胀锚型锚栓锚固破坏及承载力研究

混凝土基材锥体受拉破坏是后锚固锚栓受拉的基本破坏形式,采用混凝土破坏准则和弹性力学方法,推导了胀锚型锚栓基于混凝土基材破坏的抗拔极限承载力简化计算公式．通过对不同混凝土强度的极限状态数值分析,发现基材锚固破坏锥面底部直径R与有效锚固深度he为近似比值关系。与试验的对比结果表明,简化计算方法精度满足工程需要,和多种试验测试结果相当吻合。