一维聚合物{[Co(N3)2(dps)2]·0.5H2O}n的合成，结构和磁性质

A coordination polymer {[Co(N₃)₂(dps)₂]·0.5H₂O}_n (1) (dps=dipyridin-4-ylsulfane) with one dimensional chains has been synthesized and the structure and magnetic properties were characterized. Complex 1 crystallizes belongs to monoclinic system and has space group P2₁/c. The Co^Ⅱ ion is six-coordinated and located at a compressed octahedral environment due to the Jahn-Teller effect. The ligand of dps bridges between Co^Ⅱ ions producing the infinite chains of Co…Co along a direction and, interestingly, four pyridyl groups of dps ligands form a propeller-shaped coordination geometry around Co^Ⅱ ion with the same spiral within the chain. These 1D chains are further linked through the hydrogen bonds to generate a 3D supermolecular network. Magnetic studies indicated that complex 1 shows very weak antiferromagnetic coupling between Co^Ⅱ ions in low temperature. CCDC: 769596.     

史上最耀眼的数学巨星——挪威天才阿贝尔(下）

<正>2.学术研究大道,蜿蜒曲折的心路历程椭圆函数是从椭圆积分来的.早在18世纪,从研究物理、天文、几何学的许多问题中经常导出一些不能用初等函数表示的积分,这些积分与计算椭圆弧长的积分往往具有某种形式上的共同性,椭圆积分就是如此得名的.事实上,阿贝尔发现了一片广袤的沃土,他个人不可能在短时间内把这片沃土全部开垦完毕,用埃尔米特的话来说,"阿贝尔留下的后继工     

脊加载曲折波导行波管注波互作用的线性理论研究

提出了一类新型毫米波大功率微波器件——脊加载曲折波导行波管,推导出了引入电子注后的"热"色散方程.通过数值求解此方程,研究了加脊尺寸和电子注参数对小信号增益影响.计算结果表明:通过适当的尺寸设计和工作参数的选择,此结构在Kα波段具有18.51%的3 dB增益带宽和1.15 dB/周期的增益;相比于常规曲折波导结构,脊加载结构在保证一定带宽的情况下,具有更高的增益和电子效率;为了进一步提高增益,可以适当增加脊宽度和高度,也可在一定范围内增加电子注电流. 关键词： 毫米波 曲折波导 脊加载 小信号增益     

Ka波段曲折双脊波导行波管的研究

提出了一种曲折双脊波导慢波结构,理论分析了慢波结构的高频特性,并在此基础上设计了工作在Ka波段的曲折双脊波导行波管.利用三维粒子模拟软件MAGIC 3D建立了曲折双脊波导行波管模型,并对行波管中的注-波互作用进行了模拟分析.在相同工作条件下,分析比较了曲折双脊波导行波管和曲折波导行波管的各种性能参量,从中发现：在行波管增益峰值相近的情况下,曲折双脊波导行波管具有更好的带宽性能,其3 dB增益带宽为22％;同时具有更高的电子效率,其峰值接近9％.     

Directional Propagation Characteristics of Flexural Waves in Two-Dimensional Thin-Plate Phononic Crystals

The propagation characteristics of flexural waves in two-dimensional thin-plate phononic crystals （PCs） are analysed with the plane wave expansion （PWE） method to yield phase constant surfaces, which predict high directivity of flexural wave propagation for certain frequencies outside the band gap. The prediction is validated through the computation of the harmonic responses of a finite structure with 9 × 9 unit cells. The results indicate that directional propagation of flexural waves is an while specific effects of the directional propagation in inherent characteristic of two-dimensional thin-plate PCs a finite structure vary with the positions of excitations.     

马嘉鱼的启示

索马里海峡有一种马嘉鱼.马嘉鱼头小身大体圆,平时生活在深海中,春夏之交会溯流而上,随着海潮漂游到浅海去产卵,这正是渔民捕捉马嘉鱼的最佳时机.渔民捕捉马嘉鱼的方法很简单:用一张网眼粗疏的网,下端系上铁块,放入水中,用两只小船拖着网拦截鱼群.马嘉鱼的"个性"很强,遇到阻拦时不会转弯,越受阻越往前冲,所以一只只"前赴后继"陷入网眼中,网眼随之紧缩.网孔越紧,马嘉鱼越是愤怒,就越是更加拼命地往前冲,结果被网孔牢牢地卡死,被渔民捕获.     

磁场辅助毛细管电色谱

磁场辅助毛细管电色谱是液相色谱研究领域中出现的新技术．它利用外加磁场的引力将置于毛细管内的具有磁响应性的硅胶微球或四氧化三铁微球固定在管内任意位置．磁场固定微球聚集体既可用作填充柱,直接用于电色谱分离;也可用作柱筛,用于填装由商品色谱填料组成的色谱柱．这一技术的优势在于制备简便易行,柱管可以再生使用,适合于微流控芯片上柱筛或柱床的制作．本文简要评述磁场辅助毛细管电色谱的进展,包括磁性色谱填料的制备,磁场固定柱床电色谱,磁性柱筛电色谱及毛细管柱内柱结构参数的测定等方面．     

一维聚合物{[Co(N3)2(dps)2]·0.5H2O}n的合成,结构和磁性质

A coordination polymer {[Co(N3)2(dps)2]·0.5H2O}n (1) (dps=dipyridin-4-ylsulfane) with one dimensional chains has been synthesized and the structure and magnetic properties were characterized. Complex 1 crystallizes belongs to monoclinic system and has space group P21/c. The CoⅡ ion is six-coordinated and located at a compressed octahedral environment due to the Jahn-Teller effect. The ligand of dps bridges between Co Ⅱ ions producing the infinite chains of Co ? ? ? Co along a direction and, interestingly, four pyridy1 groups of dps ligands form a propeller-shaped coordination geometry around CoⅡ ion with the same spiral within the chain. These 1D chains are further linked through the hydrogen bonds to generate a 3D supermolecular network. Magnetic studies indicated that complex 1 shows very weak antiferromagnetic coupling between CoⅡ ions in low temperature.     

蜿蜒边界下平面流的线性流动稳定性

为便于数值分析,蜿蜒河流水动力和演变模型中一般隐性假设二次时均流-二次涡的关系与明渠流时均流-明渠湍流的关系相同,但由于高雷诺数下的DNS算力限制和实验尺度限制,这种隐含假设是否成立目前尚无相关湍流研究来支撑.文章试图通过分析明渠湍流和二次湍流发展初期的研究,侧面揭示其湍流结构的异同.通过对曲线正交坐标系下的平面二维NS方程使用双参数摄动的方法,建立了一种求解蜿蜒边界弱非线性层流的摄动解法,并推导得出一个适用于蜿蜒边界的EOS方程以及其特征值问题的解法.蜿蜒边界下弱非线性层流解为一系列蜿蜒谐波分量的叠加,其中线性部分使得两壁产生流速差,非线性部分随着雷诺数增大呈指数增长.水流的扰动增长率特征谱的第一模态与直道流相似,由3条曲线、4个波段合成,但其长波段和短波段的扰动流场与直道流不同,所有短波段的扰动流速近似于KH涡.蜿蜒边界对内部水流扰动有一定的选择性.偏角幅值越大扰动增长越快;蜿蜒波数的影响则为先增后减,有一个使扰动增长最快的蜿蜒波数.扰动流场由一个典型的TS波和一对波包形式的二次涡叠加而成,波包只有纵向流速分量,包络线由蜿蜒波数控制,波包内是与直道扰动波参数相同的TS波.