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有机化学,特别是天然有机化学,是和医学科学密切相关的,有机化学的成就在许多方面促进了医学科学的进步,反过来医学科学中提出的课题也推动了有机化学的发展。本文以抗疟药等天然药物和廿碳酸类等生理活性物质为例讨论了这两门学科间的一些关系。 相似文献
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利用三氰基铁酸盐(Bu4N)[FeⅢ(Tp)(CN)3](Tp=氢化三(1-吡唑基)硼酸)与配体2,9-二吡唑基-1,10-菲咯啉(dpzpen)以及高氯酸镍反应合成了一例氰根桥联的FeⅢ4NiⅡ2六核配合物[Fe4Ni2(Tp)4(CN)12(dpzpen)2]·12H2O·3CH3OH(1)。结构研究表明配合物1具有近似菱形的FeⅢ2NiⅡ2骨架结构,另外2个Fe(Ⅲ)则通过氰根延伸在菱形的外侧。磁性研究表明在配合物1中氰根桥联的Fe(Ⅲ)和Ni(Ⅱ)表现出铁磁相互作用。更为重要的是,基于配合物1的结构模型,对它的变温磁化率数据进行拟合得到了不同Fe(Ⅲ)-Ni(Ⅱ)之间的磁耦合常数,得到的最佳磁耦合常数J3d (15.73 cm-1)>J2d (3.53 cm-1)≈J1d (3.50 cm-1)与Ni—N键的键长以及Ni—N≡C键角的变化趋势有关(J3d: 0.206 5 nm,169.8°; J2d: 0.206 2 nm,163.1°; J1d: 0.198 7 nm,161.6°)。以上结果表明Ni—N键长越短,Ni—N≡C键角越大,Fe(Ⅲ)与Ni(Ⅱ)之间的铁磁耦合越强。 相似文献
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关于可测函数列各种收敛性的几点注记 总被引:1,自引:0,他引:1
关于可测函数列的收敛性.除了众所周知的处处收敛、一致收敛、几乎处处收敛外,尚有依测度收敛、平均收敛和弱收敛等.本文将主要讨论它们之间的相互关系。 相似文献
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Entanglement in One-Dimensional Random XY Spin Chain with Dzyaloshinskii--Moriya Interaction 下载免费PDF全文
The impurities of exchange couplings, external magnetic fields and Dzyaloshinskii-Moriya (DM) interaction considered as Gaussian distribution, and the entanglement in one-dimensional random XY spin systems is investigated by the method of solving the different spin-spin correlation functions and the average magnetization per spin. The entanglement dynamics at central locations of ferromagnetic and antiferromagnetic chains have been studied by varying the three impurities and the strength of DM interaction. (i) For the ferromagnetic spin chain, the weak DM interaction can improve the amount of entanglement to a large value, and the impurities have the opposite effect on the entanglement below and above critical DM interaction. (ii) For the antiferromagnetic spin chain, DM interaction can enhance the entanglement to a steady value. Our results imply that DM interaction strength, the impurity and exchange couplings (or magnetic field) play competing roles in enhancing quantum entanglement. 相似文献
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本文用ABC体系理论分析了ABX体系各特定跃迁的位置与强度,弄清它们与耦合常数之大小及其符号的一般变化规律,从而沟通了实测谱图与能级关联图、能级简图及耦合常数符号之间的关系.提出了只对体系作出初略强度分析以及通过双共振方法可容易地判断体系的耦合常数的相对符号的方法. 相似文献
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We discuss the possibility of coexistence of d -wave superconductivity and ferromagnetism in a two-dimensional model on the assumption that the same electrons are responsible for both the pairing order and the ferromagnetic order,The calculated results indicate that the coexistence is difficult to be realized in a uniform system. 相似文献
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De Li LI Andrew ROSALSKY Andrei VOLODIN 《数学学报(英文版)》2007,23(4):599-612
For a sequence of i.i.d. Banach space-valued random variables {Xn; n ≥ 1} and a sequence of positive constants {an; n ≥ 1}, the relationship between the Baum-Katz-Spitzer complete convergence theorem and the law of the iterated logarithm is investigated. Sets of conditions are provided under which
(i) lim sup n→∞ ||Sn||/an〈∞ a.s.and
∞ ∑n=1(1/n)P(||Sn||/an ≥ε〈∞for all ε 〉 λ for some constant λ ∈ [0, ∞) are equivalent;
(ii) For all constants λ ∈ [0, ∞),
lim sup ||Sn||/an =λ a.s.and ^∞∑ n=1(1/n) P(||Sn||/an ≥ε){〈∞, if ε〉λ =∞,if ε〈λare equivalent. In general, no geometric conditions are imposed on the underlying Banach space. Corollaries are presented and new results are obtained even in the case of real-valued random variables. 相似文献
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Previous studies carried out in the early 1990s conjectured that the main compressible effects could be associated with the dilatational effects of velocity fluctuation. Later, it was shown that the main compressibility effect came from the reduced pressure-strain term due to reduced pressure fluctuations. Although better understanding of the compressible turbulence is generally achieved with the increased DNS and experimental research effort, there are still some discrepancies among these recent findings. Analysis of the DNS and experimental data suggests that some of the discrepancies are apparent if the compressible effect is related to the turbulent Mach number, Mt. From the comparison of two classes of compressible flow, homogenous shear flow and inhomogeneous shear flow (mixing layer), we found that the effect of compressibility on both classes of shear flow can be characterized in three categories corresponding to three regions of turbulent Mach numbers: the low-Mr, the moderate-Mr and high-Mr regions. In these three regions the effect of compressibility on the growth rate of the turbulent mixing layer thickness is rather different. A simple approach to the reduced pressure-strain effect may not necessarily reduce the mixing-layer growth rate, and may even cause an increase in the growth rate. The present work develops a new second-moment model for the compressible turbulence through the introduction of some blending functions of Mt to account for the compressibility effects on the flow. The model has been successfully applied to the compressible mixing layers. 相似文献
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电位法测量了碱金属离子由水相到TBP(磷酸三丁酯)-CH~3OH混合溶剂相的标准迁移自由能△G^0~t。研究了溶剂化作用同PVC膜对金属离子选择性的关系。碱金属离子的△G^0~t随着TBP在混合溶剂中含量的增加而增大。△G^0~t还随着离子半径的增大而增大, 这同TBP-PVC膜对碱金属离子的选择性次序相一致; 而与四苯硼酸盐-TBP-PVC膜对碱金属离子的选择性次序不完全相同。说明了TBP为溶剂的四苯硼酸盐膜对金属离子的选择性除了同溶剂化作用有关外, 还同膜相和水相中离子的交换反应常数等因素相关。 相似文献