全文获取类型
收费全文 | 5947篇 |
免费 | 1286篇 |
国内免费 | 538篇 |
专业分类
化学 | 1588篇 |
晶体学 | 26篇 |
力学 | 211篇 |
综合类 | 28篇 |
数学 | 450篇 |
物理学 | 5468篇 |
出版年
2024年 | 15篇 |
2023年 | 58篇 |
2022年 | 107篇 |
2021年 | 129篇 |
2020年 | 173篇 |
2019年 | 148篇 |
2018年 | 154篇 |
2017年 | 147篇 |
2016年 | 232篇 |
2015年 | 204篇 |
2014年 | 260篇 |
2013年 | 406篇 |
2012年 | 312篇 |
2011年 | 413篇 |
2010年 | 329篇 |
2009年 | 393篇 |
2008年 | 457篇 |
2007年 | 484篇 |
2006年 | 385篇 |
2005年 | 312篇 |
2004年 | 269篇 |
2003年 | 312篇 |
2002年 | 311篇 |
2001年 | 253篇 |
2000年 | 263篇 |
1999年 | 191篇 |
1998年 | 177篇 |
1997年 | 119篇 |
1996年 | 79篇 |
1995年 | 82篇 |
1994年 | 57篇 |
1993年 | 73篇 |
1992年 | 53篇 |
1991年 | 37篇 |
1990年 | 48篇 |
1989年 | 37篇 |
1988年 | 31篇 |
1987年 | 28篇 |
1986年 | 29篇 |
1985年 | 26篇 |
1984年 | 25篇 |
1983年 | 10篇 |
1982年 | 19篇 |
1981年 | 23篇 |
1980年 | 19篇 |
1979年 | 12篇 |
1978年 | 13篇 |
1977年 | 15篇 |
1976年 | 12篇 |
1974年 | 8篇 |
排序方式: 共有7771条查询结果,搜索用时 31 毫秒
1.
L. A. Utracki 《Journal of Polymer Science.Polymer Physics》2004,42(15):2909-2915
The Simha and Somcynsky (S–S) statistical thermodynamics theory was used to compute the solubility parameters as a function of temperature and pressure [δ = δ(T, P)], for a series of polymer melts. The characteristic scaling parameters required for this task, P*, T*, and V*, were extracted from the pressure–temperature–volume (PVT) data. To determine the potential polymer–polymer miscibility, the dependence of δ versus T (at ambient pressure) was computed for 17 polymers. Close proximity of the δ versus T curves for four miscible polymer pairs: PPE/PS, PS/PVME, and PC/PMMA signaled the usefulness of this approach. It is noteworthy, that the tabulated solubility parameters (derived from the solution data under ambient conditions) propounded the immiscibility of the PVC/PVAc pair. The computed values of δ also suggested miscibility for polymer pairs of unknown miscibility, namely PPE/PVC, PPE/PVAc, and PET/PSF. In recognizing the limitations of the solubility parameter approach (the omission of several thermodynamic contributions), these preliminary results are auspicious because they indicate a new route for estimating the miscibility of any polymeric material at a given temperature and pressure. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2909–2915, 2004 相似文献
2.
We have investigated the low-lying collective states and electromagnetic transitions in 94Mo within the framework of the interacting boson model. The influence of model parameters on the energy levels and electromagnetic properties has been investigated. The analysis of the obtained results and the parameter values predict that the 23+state is the lowest mixed symmetry state with pure F = Fmax - 1 in this nucleus. The calculated results predicate that the 25+ (two-Q-phonon) mixed symmetry state is closed to the J = 2+ at 2.870 MeV in the experimental data, and the 2.965 MeV state is the lowest mixed symmetry with J = 3+. 相似文献
3.
提出了一种利用简并Ⅴ型三能级原子与相干态光场(大失谐条件下)Raman相互作用实现类自旋的腔场Greenberger-Home-Zeilinger(即GHZ)态的新方案。 相似文献
4.
Two-dimensional Marangoni convection in binary mixtures is studied in periodic domains with large spatial period in the horizontal. For negative Soret coefficients convection may set in via growing oscillations which evolve into standing waves. With increasing amplitude these waves undergo a transition to traveling waves, and then to more complex waveforms. Out of this state emerge stable stationary spatially localized structures embedded in a background of small amplitude standing waves. The relation of these states to the time-independent spatially localized states that characterize the so-called pinning region is investigated by exploring the stability properties of the latter, and the associated instabilities are studied using direct numerical simulation in time. 相似文献
5.
A master equation is used to study transitions between the stable limit cycle and stable focus in the two-variable bistable system. The distribution function of the mean first passage time between these attractors and the relative dispersion of the mean first return time from the stable focus to itself as a function of the intensity of fluctuations are calculated and discussed. A coherence resonance is observed for the return time from the focus to itself. 相似文献
6.
Peter D. Dacre 《Theoretical chemistry accounts》1976,43(2):197-205
The direct CI method, which avoids explicit calculation of the Hamiltonian matrix, is presented in a new form. The method is linked with Davidson's algorithm for iterative evaluation of the ground state eigenvector. The viability of the method is indicated by the test calculations on water which are described. 相似文献
7.
Cabaleiro-Lago EM Rodríguez-Otero J García-López RM Peña-Gallego A Hermida-Ramón JM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(20):5966-5974
A comprehensive B3LYP/6-31+G* study on the electrocyclization of 1,2,4,6-heptatetraene analogues was conducted. Starting from the cyclization of (2Z)-2,4,5-hexatrienal, a pericyclic disrotatory process favored by the assistance of a electron lone pair, we incorporated small modifications in its molecular structure to obtain a truly pseudopericyclic process. To this purpose electronegative atoms (fluorine and nitrogen) were added to give a more electrophilic character on the carbon atom which is attacked by the electron lone pair of the oxygen atom. The complete pathway for each reaction was determined, and changes in magnetic properties were monitored with a view to estimating the aromatization associated with each process. This information, together with the energetic and structural results, allowed us to classify the reactions as pseudopericyclic or pericyclic. Among all studied reactions only one was a truly pseudopericyclic process and another was a borderline case. The features of this unequivocally pseudopericyclic case were analyzed in depth. 相似文献
8.
Hiltrud Breitenfelder-Manske Friedrich Kohler 《Monatshefte für Chemie / Chemical Monthly》1985,116(11):1247-1261
The second virial coefficients of homonuclear three-centerLennard-Jones molecules are calculated with various parameters of the isosceles triangle connecting the three sites. A special effort is made to establish the reducedBoyle temperaturesT
B and the values of the second virial coefficients atT/T
B=0.3 for the sake of comparison with one- and two-centerLennard-Jones molecules. It is shown that it is possible to find parameter values of the interaction potential of one- and two-centerLennard-Jones molecules which give very similar values of second virial coefficients forT/T
B0.3, and the equivalence conditions are established. These conditions might not only give a basis for a microscopic scaling of state variables, but also some restrictions for the validity of the group contribution concept.Presented in part at the DFG-Colloquium at Paderborn, 19th April 1982, and at the 5th Conference on Mixtures of Nonelectrolytes and Intermolecular Interactions, April 18–22, 1983, at Halle (GDR). 相似文献
9.
Emission and absorption polarization spectra as well as emission lifetimes between room temperature and 5 °K have been measured of [Cr urea6]X3 single crystals, where X stands for ClO
4
–
, J–, NO
3
–
, Br–, Cl–, F–, and X3 for JSO
4
3–
. The strong temperature dependence of the fluorescence/phosphorescence-ratios, and of the emission lifetimes is discussed. The differences between the spectra as well as the emission lifetimes of the various salts can be attributed to an anion dependent trigonal perturbation.
Die Autoren danken dem Verband der Chemischen Industrie für finanzielle Unterstützung dieser Arbeit. 相似文献
10.
David Tzach Robert Buschauer Gregory Benford 《International Journal of Infrared and Millimeter Waves》1981,2(1):71-82
After eliminating reflections from the walls of the plasma container, we observed polarization of the coherent synchrotron radiation from a relativistic electron beam rotating in a plasma. Several features of the polarization agree well with calculations based on the single particle synchrotron radiation theory. A particular polarization ratio (Fig. 3) does not, however. We deduce from this direct diffraction of the radiation by the beam electrons. This is strong evidence for beam-particle bunches of size cm. Also, there must be some absorption of the extraordinary wave to account for the observations. We suggest a way to apply these results to measure the pitch angle of the beam.Work supported by Army Research Office. 相似文献